ZIF-8 calcination derived Cu2O-ZnO* material for enhanced visible-light photocatalytic performance

2021 ◽  
Author(s):  
YiLin Yin ◽  
Jingchao Liu ◽  
Zengnan Wu ◽  
Ting Zhang ◽  
Zenghe Li

As one of the most essential semiconductors, ZnO has been widely used for solar cells, photocatalysis, environmental remediation, etc. Doping and morphology control of ZnO can significantly improve the efficiency...

2015 ◽  
Vol 814 ◽  
pp. 31-38
Author(s):  
Xiao Yu Xu ◽  
Meng Wang ◽  
Lin Lin ◽  
Dan Nong He

Sensitized TiO2 nanospheres with uniform diameter of ca. 100 nm were successfully synthesized by a hydrothermal method using urea as templates and subsequently employed as robust visible-light photocatalysts. The photocatalytic activities of the sensitized TiO2 nanospheres evaluated by photodegrading methyl orange (MO) were recorded, giving the best photocatalytic performance for the sample synthesized at 110°C for 36 h. The photocatalytic mechanisms of the sensitized TiO2 nanospheres were attributed to the reduction of bandgap energies and the sensitizing effect of melon. The resultant melon acted as a sensitizer to absorb visible light and induced electrons which participated in the photodegradation of MO molecules. The new concept was helpful to guide the synthesis of robust photocatalysts, dye-sensitized solar cells, or hybrid solar cells, and the results suggested that the sensitized TiO2 nanospheres were very promising for enhancing the visible-light photocatalytic activity of TiO2 photocatalysts.


2019 ◽  
Vol 48 (35) ◽  
pp. 13353-13359 ◽  
Author(s):  
Hongfei Shi ◽  
Tingting Zhao ◽  
Yue Zhang ◽  
Huaqiao Tan ◽  
Wenhui Shen ◽  
...  

Pt/PMo12/TiO2 composite nanofibers have been prepared and exhibit a highly efficient visible-light photocatalytic performance for removing methyl orange, tetracycline, Bisphenol A and Cr(vi).


2020 ◽  
Vol 10 (9) ◽  
pp. 3238
Author(s):  
Min Liu ◽  
Guangxin Wang ◽  
Panpan Xu ◽  
Yanfeng Zhu ◽  
Wuhui Li

In this study, the Ag3PO4/SnO2 heterojunction on carbon cloth (Ag3PO4/SnO2/CC) was successfully fabricated via a facile two-step process. The results showed that the Ag3PO4/SnO2/CC heterojunction exhibited a remarkable photocatalytic performance for the degradation of Rhodamine B (RhB) and methylene blue (MB), under visible light irradiation. The calculated k values for the degradation of RhB and MB over Ag3PO4/SnO2/CC are 0.04716 min−1 and 0.04916 min−1, which are higher than those calculated for the reactions over Ag3PO4/SnO2, Ag3PO4/CC and SnO2/CC, respectively. The enhanced photocatalytic activity could mainly be attributed to the improved separation efficiency of photogenerated electron-hole pairs, after the formation of the Ag3PO4/SnO2/CC heterojunction. Moreover, carbon cloth with a large specific surface area and excellent conductivity was used as the substrate, which helped to increase the contact area of dye solution with photocatalysts and the rapid transfer of photogenerated electrons. Notably, when compared with the powder catalyst, the catalysts supported on carbon cloth are easier to quickly recycle from the pollutant solution, thereby reducing the probability of recontamination.


Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3948
Author(s):  
Lingfang Qiu ◽  
Zhiwei Zhou ◽  
Mengfan Ma ◽  
Ping Li ◽  
Jinyong Lu ◽  
...  

Novel visible-light responded aluminosilicophosphate-5 (SAPO-5)/g-C3N4 composite has been easily constructed by thermal polymerization for the mixture of SAPO-5, NH4Cl, and dicyandiamide. The photocatalytic activity of SAPO-5/g-C3N4 is evaluated by degrading RhB (30 mg/L) under visible light illumination (λ > 420 nm). The effects of SAPO-5 incorporation proportion and initial RhB concentration on the photocatalytic performance have been discussed in detail. The optimized SAPO-5/g-C3N4 composite shows promising degradation efficiency which is 40.6% higher than that of pure g-C3N4. The degradation rate improves from 0.007 min−1 to 0.022 min−1, which is a comparable photocatalytic performance compared with other g-C3N4-based heterojunctions for dye degradation. The migration of photo-induced electrons from g-C3N4 to the Al site of SAPO-5 should promote the photo-induced electron-hole pairs separation rate of g-C3N4 efficiently. Furthermore, the redox reactions for RhB degradation occur on the photo-induced holes in the g-C3N4 and Al sites in SAPO-5, respectively. This achievement not only improves the photocatalytic activity of g-C3N4 efficiently, but also broadens the application of SAPOs in the photocatalytic field.


2019 ◽  
Vol 43 (44) ◽  
pp. 17416-17422 ◽  
Author(s):  
Huaqiang Zhuang ◽  
Zhenping Cai ◽  
Wentao Xu ◽  
Mianli Huang ◽  
Xiaobin Liu

A WO3/g-C3N4 composite photocatalyst with 2D–2D heterostructure was designed and constructed by an in situ preparation strategy.


ChemCatChem ◽  
2019 ◽  
Vol 11 (15) ◽  
pp. 3490-3504 ◽  
Author(s):  
Shanshan Ding ◽  
Mengshu Han ◽  
Yuxuan Dai ◽  
Shaogui Yang ◽  
Danjun Mao ◽  
...  

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