The synthesis of cyclic olefin copolymers (COCs) by ethylene copolymerisations with cyclooctene, cycloheptene, and with tricyclo[6.2.1.0(2,7)]undeca-4-ene: the effects of cyclic monomer structures on thermal properties

The synthesis of amorphous ethylene copolymers with cycloheptene, cis-cyclooctene, or tricyclo[6.2.1.0(2,7)]undeca-4-ene using half-titanocene catalysts and the effects of ring size and structure on the thermal properties have been demonstrated.

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Effect of the number of arms on the mechanical properties of a star-shaped cyclic olefin copolymer

Polymer Chemistry ◽

10.1039/c9py01186b ◽

2019 ◽

Vol 10 (41) ◽

pp. 5578-5583 ◽

Cited By ~ 1

Author(s):

Takumitsu Kida ◽

Ryo Tanaka ◽

Koh-hei Nitta ◽

Takeshi Shiono

Keyword(s):

Mechanical Properties ◽

Thermal Properties ◽

Physical Properties ◽

Secondary Amine ◽

Aggregation Number ◽

Drastic Change ◽

Cyclic Olefin Copolymer ◽

Cyclic Olefin

The increase of aggregation number in a star-shaped cyclic olefin copolymer was succeeded by using a triazine-based secondary amine, which caused a drastic change in physical properties without changing the thermal properties.

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Infinite-Dilution Activity Coefficients of Volatile Organic Compounds in Cyclic Olefin Copolymers

Journal of Chemical & Engineering Data ◽

10.1021/je101120j ◽

2011 ◽

Vol 56 (4) ◽

pp. 1255-1260

Author(s):

P. Alessi ◽

A. Cortesi ◽

I. Kikic ◽

D. Solinas ◽

N. De Zordi ◽

...

Keyword(s):

Volatile Organic Compounds ◽

Organic Compounds ◽

Activity Coefficients ◽

Infinite Dilution ◽

Cyclic Olefin ◽

Infinite Dilution Activity Coefficients ◽

Volatile Organic ◽

Cyclic Olefin Copolymers

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In situ observation of optically and thermally induced charge depletion in chromophore-doped cyclic olefin copolymers

The 17th Annual Meeting of the IEEE Lasers and Electro-Optics Society, 2004. LEOS 2004. ◽

10.1109/ceidp.2004.1364296 ◽

2004 ◽

Cited By ~ 1

Author(s):

A. Mellinger ◽

R. Singh ◽

F.C. Gonzalez ◽

Z. Szamel ◽

I. Glowacki

Keyword(s):

In Situ Observation ◽

Thermally Induced ◽

Cyclic Olefin ◽

Induced Charge ◽

Cyclic Olefin Copolymers ◽

Charge Depletion

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Design of Efficient Molecular Catalysts for Synthesis of Cyclic Olefin Copolymers (COC) by Copolymerization of Ethylene and α-Olefins with Norbornene or Tetracyclododecene

Catalysts ◽

10.3390/catal6110175 ◽

2016 ◽

Vol 6 (11) ◽

pp. 175 ◽

Cited By ~ 13

Author(s):

Weizhen Zhao ◽

Kotohiro Nomura

Keyword(s):

Cyclic Olefin ◽

Molecular Catalysts ◽

Cyclic Olefin Copolymers

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Electrophysical Properties of Iodine Doped Acetylene/Ethylene Copolymers

MRS Proceedings ◽

10.1557/proc-328-273 ◽

1993 ◽

Vol 328 ◽

Author(s):

A. N. Aleshin ◽

E. G. Guk ◽

V. A. Marikhin ◽

L. P. Myasnikova ◽

D. G. Belov

Keyword(s):

Thermal Properties ◽

Charge Carrier ◽

Carrier Transport ◽

Room Temperature ◽

Dc Conductivity ◽

Charge Carrier Transport ◽

Electrophysical Properties ◽

Ethylene Copolymers ◽

Hopping Mechanism ◽

A Charge

ABSTRACTA new oxydative-resistant, fusible and processible ethylene/acetylene copolymer has been synthesized. The content of rigid (acetylene) and flexible (ethylene) fragments has been widely varied. The structure of the nascent powders and the films compressed at room temperature have been investigated by SEM and WAXS. DSC has been used for studying the thermal properties. DC conductivity of the iodine doped samples has been measured as a function of temperature. It is shown that the doping leads to arising conductivity in the samples even at 10 Mol % acetylene fragments in copolymer. The conductivity up to 10−3 S/cm is reached for the samples with acetylene fragment concentration about 20 Mol %. It is found that a charge carrier transport in investigated copolymers is caused by doped polyacetylene fragments and described by the hopping Mechanism.

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