Robust three-dimensional carbon conductive network in a NaVPO4F cathode used for superior high-rate and ultralong-lifespan sodium-ion full batteries

2020 ◽  
Vol 8 (34) ◽  
pp. 17454-17462 ◽  
Author(s):  
Chen-De Zhao ◽  
Jin-Zhi Guo ◽  
Zhen-Yi Gu ◽  
Xin-Xin Zhao ◽  
Wen-Hao Li ◽  
...  

The NaVPO4F cathode material coated with a robust 3D rGO carbon network exhibits an excellent electrochemical performance for sodium-ion batteries.

2019 ◽  
Vol 6 (8) ◽  
pp. 1977-1985 ◽  
Author(s):  
Bing Yan ◽  
Lijiang Wang ◽  
Weiwei Huang ◽  
Shibing Zheng ◽  
Pandeng Hu ◽  
...  

SWCNTs formed a three-dimensional conductive network between C4Q/CMK-3 nanocomposites, significantly improving the electrochemical performance of C4Q-SIBs.


2019 ◽  
Vol 11 (1) ◽  
Author(s):  
Linqu Luo ◽  
Jianjun Song ◽  
Longfei Song ◽  
Hongchao Zhang ◽  
Yicheng Bi ◽  
...  

Abstract Metallic Sn has provoked tremendous progress as an anode material for sodium-ion batteries (SIBs). However, Sn anodes suffer from a dramatic capacity fading, owing to pulverization induced by drastic volume expansion during cycling. Herein, a flexible three-dimensional (3D) hierarchical conductive network electrode is designed by constructing Sn quantum dots (QDs) encapsulated in one-dimensional N,S co-doped carbon nanofibers (NS-CNFs) sheathed within two-dimensional (2D) reduced graphene oxide (rGO) scrolls. In this ingenious strategy, 1D NS-CNFs are regarded as building blocks to prevent the aggregation and pulverization of Sn QDs during sodiation/desodiation, 2D rGO acts as electrical roads and “bridges” among NS-CNFs to improve the conductivity of the electrode and enlarge the contact area with electrolyte. Because of the unique structural merits, the flexible 3D hierarchical conductive network was directly used as binder- and current collector-free anode for SIBs, exhibiting ultra-long cycling life (373 mAh g−1 after 5000 cycles at 1 A g−1), and excellent high-rate capability (189 mAh g−1 at 10 A g−1). This work provides a facile and efficient engineering method to construct 3D hierarchical conductive electrodes for other flexible energy storage devices.


Nano Research ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 6197-6205 ◽  
Author(s):  
Xiaobo Zhu ◽  
Takashi Mochiku ◽  
Hiroki Fujii ◽  
Kaibin Tang ◽  
Yuxiang Hu ◽  
...  

RSC Advances ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 6568-6575 ◽  
Author(s):  
Mengmeng Liu ◽  
Xiaohang Zhu ◽  
Tianye Ma ◽  
Congcong Zhang ◽  
Xiang Chen ◽  
...  

GA–TiO2 composites as a cathode material realize an excellent electrochemical performance in Li–S batteries.


RSC Advances ◽  
2015 ◽  
Vol 5 (88) ◽  
pp. 71644-71651 ◽  
Author(s):  
Qian Zhou ◽  
Li Liu ◽  
Guoxiong Guo ◽  
Zichao Yan ◽  
Jinli Tan ◽  
...  

A sandwich-like CoS/rGO composite as the anode material for sodium ion batteries.


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