Universal polymeric bipolar hosts for highly efficient solution-processable blue and green thermally activated delayed fluorescence OLEDs

2020 ◽  
Vol 8 (45) ◽  
pp. 16048-16056
Author(s):  
Jinhyo Hwang ◽  
Chae Yeong Kim ◽  
Hyunchul Kang ◽  
Ji-Eun Jeong ◽  
Han Young Woo ◽  
...  

Two novel polymeric host materials, P(NmCP) and P(mCP), were synthesized, and high-performing sky-blue and green thermally activated delayed fluorescence organic light-emitting diodes were achieved.




2020 ◽  
Vol 20 (11) ◽  
pp. 7191-7195
Author(s):  
JaMin Lee ◽  
Sae Won Lee ◽  
Young Sik Kim

Novel thermally activated delayed fluorescence (TADF) host materials for blue electrophosphores-cence were designed by combining the electron acceptor dibenzothiophene (DBT) unit and the electron donor acridine derivatives into a single molecular unit by density functional theory (DFT). Depending on the optimal charge transfer, DFT and time-dependent DFT (TD-DFT) calculations for the ground state were performed to obtain the energy of the singlet (S1) and triplet (T1) excited states of the TADF material for Hartree-Fock percentage of TD-DFT. The sufficiently large separation between the HOMO and LUMO resulted in a small difference in energy (ΔEST) between the S1 and T1 states using DFT and TD-DFT calculations. The host molecules retained high triplet energy and showed great potential for use in blue organic light-emitting diodes (OLED). The results showed that these molecules are a good TADF host materials because they have a low barrier to hole and electron injection with a balanced charge transporting property for both holes and electrons, and a small ΔEST.







Author(s):  
Yang Tang ◽  
Yuan Liu ◽  
Weimin Ning ◽  
Lisi Zhan ◽  
Junqiao Ding ◽  
...  

Solution-processed phosphorescent organic light-emitting diodes (PhOLEDs) have been known as promising alternatives to vacuum deposited counterparts due to the excellent cost-effectiveness. However, the solution-processed devices still suffered from low efficiencies...



2018 ◽  
Vol 6 (34) ◽  
pp. 9152-9157 ◽  
Author(s):  
Xing Li ◽  
Kai Wang ◽  
Yi-Zhong Shi ◽  
Ming Zhang ◽  
Gao-Le Dai ◽  
...  

A novel thermally activated delayed fluorescence (TADF) emitter was designed and synthesized for solution-processed red organic light-emitting diodes (OLEDs).



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