Carbon-rich Conjugated Framework PTEB Modified Cu Nanowires for Stabilizing Lithium Metal Anode

2021 ◽  
Author(s):  
Shan Yang ◽  
Ru Xiao ◽  
Tongwei Zhang ◽  
Yuan Li ◽  
Benhe Zhong ◽  
...  
Keyword(s):  
Energy Density ◽  
Dendritic Growth ◽  
Coulombic Efficiency ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Cu Nanowires ◽  
Lithium Metal Anode

Lithium metal anode provides a direction for the development of high-energy-density lithium ion batteries. In order to solve lithium dendritic growth and low Coulombic efficiency in lithium plating/stripping process, designing...

Stable liquid-solid interface of lithium metal anode enabled by micro-region meshing

Nanoscale ◽  
2021 ◽  
Author(s):  
Jianzong Man ◽  
Kun Liu ◽  
Yehong Du ◽  
Xinyu Wang ◽  
Song Li ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Battery Lifetime ◽  
Lithium Metal Anode ◽  
Solid Liquid Interface ◽  
Solid Liquid

Although lithium metal is regarded as the most promising anode for high energy density lithium ion batteries, the unstable solid-liquid interface during cycling severely shortens the battery lifetime. The Li...

Slow surface diffusion on Cu substrates in Li metal batteries

2021 ◽  
Author(s):  
Ingeborg Treu Røe ◽  
Sondre K. Schnell
Keyword(s):  
Crystal Structure ◽  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anode ◽  
Slow Surface ◽  
Cu Substrates

Dendrite growth on the lithium metal anode still obstructs a widespread commercialization of high energy density lithium metal batteries. In this work, we investigate how the crystal structure of the...

scholarly journals Recent Advances in Lithiophilic Porous Framework toward Dendrite-Free Lithium Metal Anode

2020 ◽  
Vol 10 (12) ◽  
pp. 4185 ◽  
Author(s):  
Rajesh Pathak ◽  
Yue Zhou ◽  
Qiquan Qiao
Keyword(s):  
Rational Design ◽  
Safety Concern ◽  
Coulombic Efficiency ◽  
High Surface ◽  
High Energy ◽  
High Energy Density ◽  
Research Progress ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

Rechargeable lithium metal anode (LMA) based batteries have attracted great attention as next-generation high-energy-density storage systems to fuel the extensive practical applications in portable electronics and electric vehicles. However, the formation of unstable solid-electrolyte- interphase (SEI) and growth of lithium dendrite during plating/stripping cycles stimulate safety concern, poor coulombic efficiency (CE), and short lifespan of the lithium metal batteries (LMBs). To address these issues, the rational design of micro/nanostructured Li hosts are widely adopted in LMBs. The high surface area of the interconnected conductive framework can homogenize the Li-ion flux distribution, lower the effective current density, and provides sufficient space for Li accommodation. However, the poor lithiophilicity of the micro/nanostructure host cannot govern the initial lithium nucleation, which leads to the non-uniform/dendritic Li deposition and unstable SEI formation. As a result, the nucleation overpotential and voltage hysteresis increases, which eventually leads to poor battery cycling performance. Thus, it is imperative to decorate a micro/nanostructured Li host with lithiophilic coatings or seeds for serving as a homogeneous nucleation site to guide the uniform lithium deposition. In this review, we summarize research progress on porous metal and non-metal based lithiophilic micro/nanostructured Li hosts. We present the synthesis, structural properties, and the significance of lithiophilic decorated micro/nanostructured Li host in the LMBs. Finally, the perspectives and critical challenges needed to address for the further improvement of LMBs are concluded.

scholarly journals An ultrastable lithium metal anode enabled by designed metal fluoride spansules

2020 ◽  
Vol 6 (10) ◽  
pp. eaaz3112 ◽  
Author(s):  
Huadong Yuan ◽  
Jianwei Nai ◽  
He Tian ◽  
Zhijin Ju ◽  
Wenkui Zhang ◽  
...  
Keyword(s):  
Metal Layer ◽  
Coulombic Efficiency ◽  
High Energy ◽  
High Energy Density ◽  
Metal Fluoride ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
The Matrix ◽  
Lithium Dendrites

The lithium metal anode (LMA) is considered as a promising star for next-generation high-energy density batteries but is still hampered by the severe growth of uncontrollable lithium dendrites. Here, we design “spansules” made of NaMg(Mn)F3@C core@shell microstructures as the matrix for the LMA, which can offer a long-lasting release of functional ions into the electrolyte. By the assistance of cryogenic transmission electron microscopy, we reveal that an in situ–formed metal layer and a unique LiF-involved bilayer structure on the Li/electrolyte interface would be beneficial for effectively suppressing the growth of lithium dendrites. As a result, the spansule-modified anode affords a high Coulombic efficiency of 98% for over 1000 cycles at a current density of 2 mA cm−2, which is the most stable LMA reported so far. When coupling this anode with the Li[Ni0.8Co0.1Mn0.1]O2 cathode, the practical full cell further exhibits highly improved capacity retention after 500 cycles.

scholarly journals Engineering and characterization of interphases for Lithium metal anode 

2021 ◽  
Author(s):  
Zulipiya Shadike ◽  
Sha Tan ◽  
Ruoqian Lin ◽  
Xia Cao ◽  
Enyuan Hu ◽  
...  
Keyword(s):  
Energy Density ◽  
Specific Capacity ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Battery Systems ◽  
Theoretical Specific Capacity

Lithium metal is a very promising anode material in achieving high energy density for next generation battery systems due to its low redox potential and high theoretical specific capacity of...

Iron oxyfluorides as lithium-free cathode materials for solid-state Li metal batteries

2017 ◽  
Vol 5 (35) ◽  
pp. 18464-18468 ◽  
Author(s):  
Li-Ping Wang ◽  
Tai-Shan Wang ◽  
Xu-Dong Zhang ◽  
Jia-Yan Liang ◽  
Li Jiang ◽  
...  
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Cathode Materials ◽  
Storage Systems ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

High energy density storage systems can be achieved by utilizing a lithium metal anode in solid-state Li secondary batteries.

scholarly journals High-capacity, low-tortuosity, and channel-guided lithium metal anode

2017 ◽  
Vol 114 (14) ◽  
pp. 3584-3589 ◽  
Author(s):  
Ying Zhang ◽  
Wei Luo ◽  
Chengwei Wang ◽  
Yiju Li ◽  
Chaoji Chen ◽  
...  
Keyword(s):  
Volume Change ◽  
Coulombic Efficiency ◽  
Solid Electrolyte Interphase ◽  
High Capacity ◽  
High Energy ◽  
High Energy Density ◽  
Future Application ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

Lithium metal anode with the highest capacity and lowest anode potential is extremely attractive to battery technologies, but infinite volume change during the Li stripping/plating process results in cracks and fractures of the solid electrolyte interphase, low Coulombic efficiency, and dendritic growth of Li. Here, we use a carbonized wood (C-wood) as a 3D, highly porous (73% porosity) conductive framework with well-aligned channels as Li host material. We discovered that molten Li metal can infuse into the straight channels of C-wood to form a Li/C-wood electrode after surface treatment. The C-wood channels function as excellent guides in which the Li stripping/plating process can take place and effectively confine the volume change that occurs. Moreover, the local current density can be minimized due to the 3D C-wood framework. Therefore, in symmetric cells, the as-prepared Li/C-wood electrode presents a lower overpotential (90 mV at 3 mA⋅cm−2), more-stable stripping/plating profiles, and better cycling performance (∼150 h at 3 mA⋅cm−2) compared with bare Li metal electrode. Our findings may open up a solution for fabricating stable Li metal anode, which further facilitates future application of high-energy-density Li metal batteries.

Lithium phosphide/lithium chloride coating on lithium for advanced lithium metal anode

2018 ◽  
Vol 6 (32) ◽  
pp. 15859-15867 ◽  
Author(s):  
Liangdong Lin ◽  
Feng Liang ◽  
Kaiyuan Zhang ◽  
Hongzhi Mao ◽  
Jian Yang ◽  
...  
Keyword(s):  
Energy Density ◽  
Anode Material ◽  
Lithium Chloride ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Chloride Coating

Lithium metal has been regarded as an ideal anode material for high-energy-density batteries.

Sign in / Sign up

Export Citation Format

Share Document