Ferroelectricity and Switching Polarization on the C-H…π Bond in Pure Organic Molecular Crystal – 1,3,5-Trimethylnitrobenzene

CrystEngComm ◽  
2021 ◽  
Author(s):  
Przemyslaw Szklarz ◽  
Vasyl Kinzhybalo ◽  
Grazyna Bator
Keyword(s):  
Single Crystal ◽  
Molecular Crystal ◽  
Single Component ◽  
The Novel ◽  
Temperature Dependent ◽  
Organic Molecular Crystal ◽  
Ferroelectric Single Crystal ◽  
Three Phases

The novel single component molecular ferroelectric single crystal of 1,3,5-trimethylnitrobenzene (TMNB) has been inves-tigated in terms of its temperature dependent polar properties. Three phases have been found in the solid...

Time‐Dependent Afterglow Color in a Single‐Component Organic Molecular Crystal

2020 ◽  
Vol 132 (25) ◽  
pp. 10118-10122 ◽  
Author(s):  
Jian‐Xin Wang ◽  
Ye‐Guang Fang ◽  
Chun‐Xiang Li ◽  
Li‐Ya Niu ◽  
Wei‐Hai Fang ◽  
...  
Keyword(s):  
Molecular Crystal ◽  
Single Component ◽  
Time Dependent ◽  
Organic Molecular Crystal

Time‐Dependent Afterglow Color in a Single‐Component Organic Molecular Crystal

2020 ◽  
Vol 59 (25) ◽  
pp. 10032-10036 ◽  
Author(s):  
Jian‐Xin Wang ◽  
Ye‐Guang Fang ◽  
Chun‐Xiang Li ◽  
Li‐Ya Niu ◽  
Wei‐Hai Fang ◽  
...  
Keyword(s):  
Molecular Crystal ◽  
Single Component ◽  
Time Dependent ◽  
Organic Molecular Crystal

Advancing the use of Voronoi–Dirichlet polyhedra to describe interactions in organic molecular crystal structures by the example of galunisertib polymorphs

CrystEngComm ◽  
2021 ◽  
Author(s):  
Viktor N. Serezhkin ◽  
Anton V. Savchenkov
Keyword(s):  
Crystal Structures ◽  
Molecular Crystal ◽  
Noncovalent Interactions ◽  
Organic Molecular Crystal ◽  
Universal Approach ◽  
Structure Properties

The universal approach for studying structure/properties relationships shows that every polymorph of galunisertib is characterized with unique noncovalent interactions.

Ternary Antimonides RE4T7Sb6 (RE=Gd–Lu; T =Ru, Rh) with Cubic U4Re7Si6-type Structure

2013 ◽  
Vol 68 (9) ◽  
pp. 971-978 ◽  
Author(s):  
Inga Schellenberg ◽  
Ute Ch. Rodewald ◽  
Christian Schwickert ◽  
Matthias Eul ◽  
Rainer Pöttgen
Keyword(s):  
Magnetic Susceptibility ◽  
Single Crystal ◽  
Magnetic Moment ◽  
Induction Furnace ◽  
X Ray Diffraction ◽  
Temperature Dependent ◽  
X Ray ◽  
Antiferromagnetic Ordering ◽  
Arc Melting ◽  
Intermediate Valent

The ternary antimonides RE4T7Sb6 (RE=Gd-Lu; T =Ru, Rh) have been synthesized from the elements by arc-melting and subsequent annealing in an induction furnace. The samples have been characterized by powder X-ray diffraction. Four structures were refined on the basis of single-crystal X-ray diffractometer data: U4Re7Si6 type, space group Im3m with a=862.9(2) pm, wR2=0.0296, 163 F2 values for Er4Ru7Sb6; a=864.1(1) pm, wR2=0.1423, 153 F2 values for Yb4Ru7Sb6; a=872.0(2) pm, wR2=0.0427, 172 F2 values for Tb4Rh7Sb6; and a=868.0(2) pm, wR2=0.0529, 154 F2 values for Er4Rh7Sb6, with 10 variables per refinement. The structures have T1@Sb6 octahedra and slightly distorted RE@T26Sb6 cuboctahedra as building units. The distorted cuboctahedra are condensed via all trapezoidal faces, and this network leaves octahedral voids for the T1 atoms. The ruthenium-based series of compounds was studied by temperature-dependent magnetic susceptibility measurements. Lu4Ru7Sb6 is Pauli-paramagnetic. The antimonides RE4Ru7Sb6 with RE=Dy, Ho, Er, and Tm show Curie-Weiss paramagnetism. Antiferromagnetic ordering occurs at 10.0(5), 5.1(5) and 4.0(5) K for Dy4Ru7Sb6, Ho4Ru7Sb6 and Er4Ru7Sb6, respectively, while Tm4Ru7Sb6 remains paramagnetic. Yb4Ru7Sb6 is an intermediate-valent compound with a reduced magnetic moment of 3.71(1) μB per Yb as compared to 4.54 μB for a free Yb3+ ion

A Novel Technique for Growth of Lithium-free ZnO Single Crystals

2013 ◽  
Vol 1538 ◽  
pp. 405-410
Author(s):  
Shaoping Wang ◽  
Aneta Kopec ◽  
Andrew G. Timmerman
Keyword(s):  
Single Crystal ◽  
The Novel ◽  
Uv Laser ◽  
Uv Detectors ◽  
Growth Technique ◽  
Light Emitting ◽  
Alkaline Metals ◽  
Novel Technique ◽  
Solar Blind ◽  
Zno Single Crystal

ABSTRACTA ZnO single crystal is a native substrate for epitaxial growth of high-quality thin films of ZnO-based Group II-oxides (e.g. ZnO, ZnMgO, ZnCdO) for variety of devices, such as UV and visible-light emitting diodes (LEDs), UV laser diodes and solar-blind UV detectors. Currently, commercially available ZnO single crystal wafers are produced using a hydrothermal technique. The main drawback of hydrothermal growth technique is that the ZnO crystals contain large amounts of alkaline metals, such as Li and K. These alkaline metals are electrically active and hence can be detrimental to device performances. In this paper, results from a recently developed novel growth technique for ZnO single crystal boules are presented. Lithium-free ZnO single crystal boules of up to 1 inch in diameter was demonstrated using the novel technique. Results from crystal growth and materials characterization will be discussed.

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