Electronic and steric impact of bis-NHC ligands on reactions of Pt3S2 cores in trinuclear complexes bearing bis-NHC ligands with various lengths of alkylene bridges
A silver(i) ion attacks the sulfide ligand of a triplatinum complex bearing ethylene-bridged bis-NHC ligands to afford a heptanuclear complex with two Ag–S bonds due to the steric hindrance of the ligands covering the Pt–Pt bonds.
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1987 ◽
Vol 52
(10)
◽
pp. 2482-2491
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