Facile synthesis of organic/inorganic hybrid 2D structure tincone film by molecular layer deposition

2022 ◽  
Author(s):  
GeonHo Beak ◽  
Seung-Hwan Lee ◽  
Hye-mi Kim ◽  
Su-Hwan Choi ◽  
Jin-Seong Park

Organic/inorganic hybrid tincone films were deposited by molecular layer deposition (MLD) using N,N′-tert-butyl-1,1-dimethylethylenediamine stannylene(II) as a precursor and hydroquinone (HQ) as organic reactants. As a result of previous studies it...

Author(s):  
Seung-Hwan Lee ◽  
Hyun-Jun Jeong ◽  
Ki-Lim Han ◽  
GeonHo Beak ◽  
Jin-Seong Park

Indium oxide and indicone hybrid films consisting of indium oxide and organic aromatic linker are grown by molecular layer deposition (MLD) using bis(trimethylsilyl)amido-diethyl Indium (INCA-1) as the indium precursor, hydrogen...


2017 ◽  
Vol 5 (35) ◽  
pp. 18326-18378 ◽  
Author(s):  
Xiangbo Meng

This review makes a comprehensive summary on the processes of molecular layer deposition (MLD) for organic and organic–inorganic hybrid materials, and on their applications.


2019 ◽  
Vol 10 ◽  
pp. 399-411 ◽  
Author(s):  
Leva Momtazi ◽  
Henrik H Sønsteby ◽  
Ola Nilsen

We have constructed thin films of organic–inorganic hybrid character by combining titanium tetra-isopropoxide (TTIP) and the nucleobases thymine, uracil or adenine using the molecular layer deposition (MLD) approach. Such materials have potential as bioactive coatings, and the bioactivity of these films is described in our recent work [Momtazi, L.; Dartt, D. A.; Nilsen, O.; Eidet, J. R. J. Biomed. Mater. Res., Part A 2018, 106, 3090–3098. doi:10.1002/jbm.a.36499]. The growth was followed by in situ quartz crystal microbalance (QCM) measurements and all systems exhibited atomic layer deposition (ALD) type of growth. The adenine system has an ALD temperature window between 250 and 300 °C, while an overall reduction in growth rate with increasing temperature was observed for the uracil and thymine systems. The bonding modes of the films have been further characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and X-ray diffraction, confirming the hybrid nature of the as-deposited films with an amorphous structure where partial inclusion of the TTIP molecule occurs during growth. The films are highly hydrophilic, while the nucleobases do leach in water providing an amorphous structure mainly of TiO2 with reduced density and index of refraction.


2020 ◽  
Vol 8 (42) ◽  
pp. 22100-22110
Author(s):  
Huibing He ◽  
Jian Liu

A novel organic–inorganic hybrid coating (alucone) by molecular layer deposition was developed to construct stable, dendrite-free, and deeply rechargeable Zn anodes for aqueous zinc-ion batteries.


ACS Nano ◽  
2012 ◽  
Vol 6 (8) ◽  
pp. 7263-7269 ◽  
Author(s):  
Sergey Ishchuk ◽  
Dereje Hailu Taffa ◽  
Ori Hazut ◽  
Niv Kaynan ◽  
Roie Yerushalmi

2021 ◽  
Vol 50 (37) ◽  
pp. 12896-12905
Author(s):  
Melania Rogowska ◽  
Per-Anders Hansen ◽  
Henrik Hovde Sønsteby ◽  
Joanna Dziadkowiec ◽  
Håkon Valen ◽  
...  

A series of organic–inorganic hybrid thin films with different d0-metals (Y, Ti, Zr and Hf) and 2,6-naphthalenedicarboxylic acid were prepared by molecular layer deposition (MLD) and their optical properties were explored.


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