Nickel(ii) monobenzoporphyrins and chlorins: synthesis, electrochemistry and anion sensing properties

2021 ◽  
Author(s):  
Sandeep Kumar ◽  
Nivedita Chaudhri ◽  
W. Ryan Osterloh ◽  
Karl M. Kadish ◽  
Muniappan Sankar

New NiII monobenzoporphyrins and chlorins were synthesized. One compound was used as a chemodosimeter for naked-eye detection of cyanide in nonaqueous media giving a new π-extended porphyrin product with NIR absorptions and a 1.47 V HOMO–LUMO gap.

2020 ◽  
Vol 12 (47) ◽  
pp. 5699-5708
Author(s):  
Saswati Ghosh Roy ◽  
Subhendu Mondal ◽  
Kumaresh Ghosh

Two polymers, linear P1 and cross-linked P2, are employed in anion sensing. P1 exhibits fluorescence sensing of HPPi with a detection limit of about 1.63 ppm in aqueous DMSO. P2 exhibits selective naked-eye detection of PPi/HPPi via an indicator displacement assay (IDA).


2021 ◽  
Author(s):  
Hyungwook Kim ◽  
Young Jae Jung ◽  
Jungkyu K. Lee

We developed a novel strategy for signal amplification strategy using a visible light-induced photopolymerization, initiated by a selective turn-on photoredox catalyst. As photoredox catalysts, fluorescein derivatives are able to initiate...


2021 ◽  
Vol 328 ◽  
pp. 112776
Author(s):  
Yogendra Singh Solanki ◽  
Priya Yadav ◽  
Madhu Agarwal ◽  
Ragini Gupta ◽  
Sanjeev Gupta ◽  
...  

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