scholarly journals Acetone Complexes for High-Performance Perovskite Photovoltaics with Reduced Nonradiative Recombination

2022 ◽  
Author(s):  
Zhen Wang ◽  
Chenguang Yang ◽  
Yuying Cui ◽  
Li Xie ◽  
Feng Hao

Solvent engineering has been widely employed in the preparation of high-quality perovskite films for emerging halide perovskite solar cells (PSCs). However, the heavy use of toxic solvents (such as N-methyl-2-pyrrolidone...

Author(s):  
Jing Ren ◽  
Shurong Wang ◽  
Jianxing Xia ◽  
Chengbo Li ◽  
Lisha Xie ◽  
...  

Defects, inevitably produced in the solution-processed halide perovskite films, can act as charge carrier recombination centers to induce severe energy loss in perovskite solar cells (PSCs). Suppressing these trap states...


Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3398
Author(s):  
Yi Long ◽  
Kun Liu ◽  
Yongli Zhang ◽  
Wenzhe Li

Inorganic cesium lead halide perovskites, as alternative light absorbers for organic–inorganic hybrid perovskite solar cells, have attracted more and more attention due to their superb thermal stability for photovoltaic applications. However, the humid air instability of CsPbI2Br perovskite solar cells (PSCs) hinders their further development. The optoelectronic properties of CsPbI2Br films are closely related to the quality of films, so preparing high-quality perovskite films is crucial for fabricating high-performance PSCs. For the first time, we demonstrate that the regulation of ambient temperature of the dry air in the glovebox is able to control the growth of CsPbI2Br crystals and further optimize the morphology of CsPbI2Br film. Through controlling the ambient air temperature assisted crystallization, high-quality CsPbI2Br films are obtained, with advantages such as larger crystalline grains, negligible crystal boundaries, absence of pinholes, lower defect density, and faster carrier mobility. Accordingly, the PSCs based on as-prepared CsPbI2Br film achieve a power conversion efficiency of 15.5% (the maximum stabilized power output of 15.02%). Moreover, the optimized CsPbI2Br films show excellent robustness against moisture and oxygen and maintain the photovoltaic dark phase after 3 h aging in an air atmosphere at room temperature and 35% relative humidity (R.H.). In comparison, the pristine films are completely converted to the yellow phase in 1.5 h.


2019 ◽  
Vol 34 (14) ◽  
pp. 2416-2424 ◽  
Author(s):  
Jian Li ◽  
Ruihan Yang ◽  
Longcheng Que ◽  
Yafei Wang ◽  
Feng Wang ◽  
...  

Abstract


2020 ◽  
Vol 4 (9) ◽  
pp. 4506-4515
Author(s):  
Zeyang Zhang ◽  
Fengqin He ◽  
Weidong Zhu ◽  
Dandan Chen ◽  
Wenming Chai ◽  
...  

High-quality CsPbIBr2 films with a much lower self-doping level are obtained by the use of a CsI-rich precursor, which enables the fabrication of an all-inorganic, carbon-based solar cell with a superior efficiency of 10.48%.


2018 ◽  
Vol 2 (11) ◽  
pp. 2435-2441 ◽  
Author(s):  
Changlei Wang ◽  
Zhaoning Song ◽  
Yue Yu ◽  
Dewei Zhao ◽  
Rasha A. Awni ◽  
...  

The combination of Pb(SCN)2 and CsPbI3 results in high quality perovskite films, leading to high performance PVSCs with a stable power output.


2020 ◽  
Vol 13 (7) ◽  
pp. 1971-1996 ◽  
Author(s):  
Weijie Chen ◽  
Xinqi Li ◽  
Yaowen Li ◽  
Yongfang Li

The key factors for high-quality all-inorganic perovskite crystal growth.


Solar RRL ◽  
2020 ◽  
Vol 4 (9) ◽  
pp. 2000213 ◽  
Author(s):  
Qiong Wang ◽  
Joel A. Smith ◽  
Dieter Skroblin ◽  
Julian A. Steele ◽  
Christian M. Wolff ◽  
...  

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