Efficiently luminescent mononuclear copper iodide complexes with sterically hindered iminephosphine chelating ligands

2021 ◽  
Author(s):  
Bin Zhang ◽  
Jie Zhang ◽  
Ahui Sun ◽  
Chunmei Liu ◽  
Mengsi Gu ◽  
...  
Keyword(s):  
Solid State ◽  
Chelating Ligands ◽  
Copper Iodide ◽  
Intense Emission ◽  
Sterically Hindered ◽  
Uv Excitation

Phosphorescent four-coordinate Cu(I) complexes (1-3) of type [CuI(PPh3)(N^P)], N^P = 4-(diphenylphosphanyl)-1,2-diphenylbenzimidazole derivatives, have been synthesized and characterized. Under UV excitation, the titled complexes in the solid-state exhibit intense emission with...

scholarly journals Switching-On Fluorescence by Copper (II) and Basic Anions: A Case Study with a Pyrene-Functionalized Squaramide

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1301
Author(s):  
Giacomo Picci ◽  
Jessica Milia ◽  
Maria Carla Aragoni ◽  
Massimiliano Arca ◽  
Simon J. Coles ◽  
...  
Keyword(s):  
Solid State ◽  
Copper Complex ◽  
Receptor Complex ◽  
Emission Properties ◽  
Naked Eye ◽  
Intense Emission ◽  
Uv Lamp

The new symmetric acyclic N,N’-bis(1-pyrenyl) squaramide (H2L) functionalized with the pyrene moiety as a fluorogenic fragment has been designed and its ability to selectively detect specific anions and metals investigated. H2L selectively binds Cl− both in solution (DMSO 0.5% H2O and MeCN) and in the solid state, and allows to selectively detect Cu2+ in MeCN with the formation of a 2:1 metal-receptor complex, with a green intense emission appreciable by naked eye under the UV lamp. The H2L copper complex preserves its emission properties in the presence of Cl−. The addition of basic anions (OH−, CN−, and F−) up to 10 equivalents caused the deprotonation of the squaramide NHs and a dramatic change of the emission properties of the H2L copper complex.

Benzothiazole–pyrimidine-based BODIPY analogues: promising luminophores with fluorescence sensing and imaging ability and asymmetrization-induced solid-state emission

2016 ◽  
Vol 45 (43) ◽  
pp. 17274-17280 ◽  
Author(s):  
Xiaoqing Wang ◽  
Qingsong Liu ◽  
Fen Qi ◽  
Lin Li ◽  
Hai-Dong Yu ◽  
...  
Keyword(s):  
Solid State ◽  
Fluorescence Sensing ◽  
Intense Emission ◽  
Boron Difluoride

A series of boron difluoride dyes were demonstrated to possess intense emission both in solution and solid-state. Their fluorogenic sensing and imaging abilities were also investigated.

scholarly journals Rational ligand choice extends the SABRE substrate scope

2020 ◽  
Vol 56 (65) ◽  
pp. 9336-9339 ◽  
Author(s):  
Johannes F. P. Colell ◽  
Angus W. J. Logan ◽  
Zijian Zhou ◽  
Jacob R. Lindale ◽  
Raul Laasner ◽  
...  
Keyword(s):  
Signal Amplification ◽  
Chelating Ligands ◽  
Sterically Hindered

Here we report on chelating ligands for Signal Amplification By Reversible Exchange (SABRE) catalysts that permit hyperpolarisation on otherwise sterically hindered substrates.

Reactions of a pincer proligand with copper iodide: bridging instead of C–H metalation

2020 ◽  
Vol 98 (9) ◽  
pp. 524-530
Author(s):  
Taghrid Chahrour ◽  
Annie Castonguay ◽  
Paul O. Oguadinma ◽  
Frank Schaper ◽  
Davit Zargarian
Keyword(s):  
Solid State ◽  
The Other ◽  
Strong Preference ◽  
Pincer Complexes ◽  
Divalent Copper ◽  
Copper Iodide ◽  
Tetrahedral Geometry ◽  
Central Carbon ◽  
Copper Center ◽  
Solid State Structures

Various precursors of divalent copper have been treated with the meta-disubstituted phenylene-based proligand POC(H)OP (1,3-(i-Pr2PO)2C6H4) with the objective of preparing classical pincer complexes (POCOP)CuX. However, in no case was such species obtained, presumably owing to the difficult C–H metallation step. Analogous reactions of monovalent precursors were also unsuccessful, whereas reaction of POC(H)OP with CuI under different conditions gave the non-metallated adducts {(μ, κP, [Formula: see text]-POC(H)OP)Cu(μ-Ι)}2, 1, {(μ, κP, [Formula: see text]-POC(H)OP)Cu2(μ-Ι)2(DMAP)2}, 2 (DMAP = 4-dimethylaminopyridine), and {(μ, κP, [Formula: see text]-POC(H)OP)Cu2(μ3-Ι)2}2, 3. Treating 1 with DMAP gave the adduct 2, whereas 3 could be obtained by treating 1 with BuLi or by sublimation of 1. The solid state structures of these complexes revealed the tetrahedral geometry that might be anticipated for the d10 Cu(I) centers, in addition to fairly close I–H distances; on the other hand, no C–H interaction (agostic or otherwise) was observed with the Cu centers in any of these structures. The unsuccessful metallation of the C(2)–H moiety is thought to be a result of the strong preference of monovalent copper center to form bridging interactions with iodide and the POC(H)OP ligand; this appears to prevent the approach of the central carbon of the ligand to the Cu centers.

Synthesis and solid-state structures of some sterically hindered cyclopropenylsilanes

1989 ◽  
Vol 8 (3) ◽  
pp. 770-777 ◽  
Author(s):  
Dhananjay B. Puranik ◽  
M. Pontier. Johnson ◽  
Mark J. Fink
Keyword(s):  
Solid State ◽  
Sterically Hindered ◽  
Solid State Structures

Effect of Sterically Hindered Ligands on the Solid-State Structures of Organosilanediols Containing Si−N Bonds§

2001 ◽  
Vol 40 (5) ◽  
pp. 940-945 ◽  
Author(s):  
Vadapalli Chandrasekhar ◽  
Selvarajan Nagendran ◽  
Ramamoorthy Boomishankar ◽  
Raymond J. Butcher
Keyword(s):  
Solid State ◽  
Sterically Hindered ◽  
Solid State Structures

Photoluminescence properties of single-component white-emitting Ca9Bi(PO4)7:Ce3+,Tb3+,Mn2+phosphors for UV LEDs

2015 ◽  
Vol 3 (27) ◽  
pp. 7096-7104 ◽  
Author(s):  
Kai Li ◽  
Mengmeng Shang ◽  
Yang Zhang ◽  
Jian Fan ◽  
Hongzhou Lian ◽  
...  
Keyword(s):  
High Temperature ◽  
Solid State ◽  
White Light ◽  
Solid State Reaction Method ◽  
Photoluminescence Properties ◽  
Light Emitting ◽  
Reaction Method ◽  
White Light Emitting Diodes ◽  
Uv Leds ◽  
Uv Excitation

A series of Ca9Bi(PO4)7:Ce3+,Tb3+,Mn2+phosphors synthesizedviathe high-temperature solid-state reaction method can emit intense tunable color from purple-blue to red including white under UV excitation, which shows their potential application in UV-pumped white-light-emitting diodes.

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