Selective desolvation in two-step nucleation mechanism steers crystal structure formation

Nanoscale ◽  
2022 ◽  
Author(s):  
Anish V. Dighe ◽  
Paria Coliaie ◽  
Prem K. R. Podupu ◽  
Meenesh R. Singh
Keyword(s):  
Crystal Structure ◽  
Structure Formation ◽  
Nucleation Mechanism ◽  
Crystalline Solids ◽  
Nucleation Process ◽  
Liquid Clusters ◽  
Crystal Structure Formation ◽  
Dense Liquid

Illustrated is a two-step nucleation process, where solute molecules in the solution are first partially desolvated to form locally dense liquid clusters followed by selective desolvation to yield crystalline solids.

Crystalline magnesium chloride–electron donor complexes: new support materials for Ziegler–Natta catalysts

2017 ◽  
Vol 46 (13) ◽  
pp. 4452-4460 ◽  
Author(s):  
V. H. Nissinen ◽  
I. O. Koshevoy ◽  
T. T. Pakkanen
Keyword(s):  
Crystal Structure ◽  
Structure Formation ◽  
Magnesium Chloride ◽  
Donor Ligands ◽  
Nitrogen Donor Ligands ◽  
Support Materials ◽  
Polymerization Catalyst ◽  
Nitrogen Donor ◽  
Crystal Structure Formation ◽  
Ziegler Natta Catalysts

Chelating oxygen and nitrogen donor ligands (1,2-dimethoxyethane, 1,3-dimethoxypropane, and N,N′-diethylethylenediamine) are found to dictate the crystal structure formation of MgCl2, the important support component of a polymerization catalyst.

scholarly journals Crystal Structure Formation of CH3NH3PbI3-xClx Perovskite

Materials ◽  
2016 ◽  
Vol 9 (3) ◽  
pp. 123 ◽  
Author(s):  
Shiqiang Luo ◽  
Walid Daoud
Keyword(s):  
Crystal Structure ◽  
Structure Formation ◽  
Crystal Structure Formation

Crystal structure formation of hemihydrate calcium sulfate whiskers (HH-CSWs) prepared using FGD gypsum

Polyhedron ◽  
2019 ◽  
Vol 173 ◽  
pp. 114140 ◽  
Author(s):  
Xiaoting Zhang ◽  
Xiao Wang ◽  
Biao Jin ◽  
Xueping Liu ◽  
Liushuan Yang
Keyword(s):  
Crystal Structure ◽  
Structure Formation ◽  
Calcium Sulfate ◽  
Fgd Gypsum ◽  
Calcium Sulfate Whiskers ◽  
Crystal Structure Formation

Intermolecular interactions in crystals of benzene and its mono- and dinitro derivatives: study from the energetic viewpoint

CrystEngComm ◽  
2019 ◽  
Vol 21 (18) ◽  
pp. 2908-2919 ◽  
Author(s):  
Irina S. Konovalova ◽  
Svitlana V. Shishkina ◽  
G. Bani-Khaled ◽  
Ekaterina N. Muzyka ◽  
Alexander N. Boyko
Keyword(s):  
Crystal Structure ◽  
Structure Formation ◽  
Quantum Chemical Calculations ◽  
Intermolecular Interactions ◽  
Quantum Chemical ◽  
Weak Intermolecular Interactions ◽  
Crystal Structure Formation

The weak intermolecular interactions and their role in mono- and dinitrobenzene crystal structure formation have been studied using quantum-chemical calculations.

Influence of fluorine side-group substitution on the crystal structure formation of benzene-1,3,5-trisamides

CrystEngComm ◽  
2014 ◽  
Vol 16 (39) ◽  
pp. 9273-9283 ◽  
Author(s):  
Christoph Zehe ◽  
Marko Schmidt ◽  
Renée Siegel ◽  
Klaus Kreger ◽  
Venita Daebel ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Structure Formation ◽  
Solid State Nmr ◽  
Quantum Chemical ◽  
Side Group ◽  
X Ray Diffraction ◽  
X Ray ◽  
Crystal Structure Formation

The crystal structure of 1,3,5-tris(2-fluoro-2-methylpropionylamino)benzene was solved by combining powder X-ray diffraction, solid-state NMR spectroscopy and quantum chemical calculations.

scholarly journals Dynamics of Crystal Structure Formation in Spin-Coated Colloidal Films

2010 ◽  
Vol 1 (9) ◽  
pp. 1481-1486 ◽  
Author(s):  
Maximiliano Giuliani ◽  
Wenceslao González-Viñas ◽  
Kristin M. Poduska ◽  
Anand Yethiraj
Keyword(s):  
Crystal Structure ◽  
Structure Formation ◽  
Colloidal Films ◽  
Crystal Structure Formation
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