Polyrhodamine: A redox stable conducting polyelectrolyte

2021 ◽  
Author(s):  
Ranganath Wahalathantrige Don ◽  
Timothy J Dowell ◽  
Briana L. Simms ◽  
Davita Watkins ◽  
David Wipf ◽  
...  

Rhodamine dyes are known for their excellent photoluminescence properties but not commonly known for their electrical conductivity or redox stability. They are usually found as pendants (sidechains) attached to a...


2015 ◽  
Vol 40 (35) ◽  
pp. 12003-12008 ◽  
Author(s):  
Jae-ha Myung ◽  
Tae Ho Shin ◽  
Xiubing Huang ◽  
George Carins ◽  
John T.S. Irvine


RSC Advances ◽  
2017 ◽  
Vol 7 (37) ◽  
pp. 22649-22661 ◽  
Author(s):  
Guohui Dong ◽  
Chunyang Yang ◽  
Fei He ◽  
Yanmei Jiang ◽  
Chunlei Ren ◽  
...  

PrBaFe1.9Sn0.1O5+δ shows excellent redox stability, high electrical conductivity, and ASR of a symmetrical cell as low as of 0.095–0.285 Ω cm2 from 850–750 °C in wet hydrogen, better than or comparable to the best of ceramic anodes in the open literature.



2021 ◽  
pp. 096739112110482
Author(s):  
Oğuz Yunus Sarıbıyık ◽  
İlyas Gönül ◽  
Burak Ay ◽  
Serkan Karaca

In this work, an insoluble three dimensional (3D) porous polymeric structure and their metal complexes were synthesised by the condensation reactions of meta(m)-phenylenediamine, para(p)-phenylenediamine and glutaraldehyde. The morphological and spectral features of the porous polymeric structures were determined using different analytical and spectroscopic methods, including field emission scanning electron microscopy, four-point probe electrical conductivity, photoluminescence spectroscopy, Fourier-transform infrared spectroscopy, surface area Brunauer–Emmett–Teller and magnetic and thermal behaviours. According to the obtained data, the shape, size and photoluminescence properties of the compounds, especially the conductivity, were clearly changed after the metalation processes.



2014 ◽  
Vol 34 (10) ◽  
pp. 2339-2350 ◽  
Author(s):  
N.M. Ferreira ◽  
A.V. Kovalevsky ◽  
E.N. Naumovich ◽  
A.A. Yaremchenko ◽  
K.V. Zakharchuk ◽  
...  


2005 ◽  
Vol 50 (22) ◽  
pp. 4385-4395 ◽  
Author(s):  
D. Marrero-López ◽  
J. Canales-Vázquez ◽  
J.C. Ruiz-Morales ◽  
J.T.S. Irvine ◽  
P. Núñez


2013 ◽  
Vol 33 (7) ◽  
pp. 1307-1315 ◽  
Author(s):  
E.M. Domingues ◽  
E.V. Tsipis ◽  
A.A. Yaremchenko ◽  
F.M. Figueiredo ◽  
J.C. Waerenborgh ◽  
...  


2013 ◽  
Vol 33 (13-14) ◽  
pp. 2751-2760 ◽  
Author(s):  
A.V. Kovalevsky ◽  
A.A. Yaremchenko ◽  
E.N. Naumovich ◽  
N.M. Ferreira ◽  
S.M. Mikhalev ◽  
...  


Author(s):  
John C. Russ ◽  
Nicholas C. Barbi

The rapid growth of interest in attaching energy-dispersive x-ray analysis systems to transmission electron microscopes has centered largely on microanalysis of biological specimens. These are frequently either embedded in plastic or supported by an organic film, which is of great importance as regards stability under the beam since it provides thermal and electrical conductivity from the specimen to the grid.Unfortunately, the supporting medium also produces continuum x-radiation or Bremsstrahlung, which is added to the x-ray spectrum from the sample. It is not difficult to separate the characteristic peaks from the elements in the specimen from the total continuum background, but sometimes it is also necessary to separate the continuum due to the sample from that due to the support. For instance, it is possible to compute relative elemental concentrations in the sample, without standards, based on the relative net characteristic elemental intensities without regard to background; but to calculate absolute concentration, it is necessary to use the background signal itself as a measure of the total excited specimen mass.



Author(s):  
Klaus-Ruediger Peters ◽  
Samuel A. Green

High magnification imaging of macromolecules on metal coated biological specimens is limited only by wet preparation procedures since recently obtained instrumental resolution allows visualization of topographic structures as smal l as 1-2 nm. Details of such dimensions may be visualized if continuous metal films with a thickness of 2 nm or less are applied. Such thin films give sufficient contrast in TEM as well as in SEM (SE-I image mode). The requisite increase in electrical conductivity for SEM of biological specimens is achieved through the use of ligand mediated wet osmiuum impregnation of the specimen before critical point (CP) drying. A commonly used ligand is thiocarbohvdrazide (TCH), first introduced to TEM for en block staining of lipids and glvcomacromolecules with osmium black. Now TCH is also used for SEM. However, after ligand mediated osinification nonspecific osmium black precipitates were often found obscuring surface details with large diffuse aggregates or with dense particular deposits, 2-20 nm in size. Thus, only low magnification work was considered possible after TCH appl ication.



1991 ◽  
Vol 18 (3) ◽  
pp. 611-627 ◽  
Author(s):  
Marta L. Fiorotto ◽  
William J. Klish


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