scholarly journals Molecular mechanism of direct electron transfer in the robust cytochrome-functionalised graphene nanosystem

RSC Advances ◽  
2021 ◽  
Vol 11 (31) ◽  
pp. 18860-18869
Author(s):  
Margot Jacquet ◽  
Małgorzata Kiliszek ◽  
Silvio Osella ◽  
Miriam Izzo ◽  
Jarosław Sar ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Molecular Mechanism ◽  
Opposite Effect ◽  
Direct Electron Transfer ◽  
Cathodic Current ◽  
Electron Hopping

Molecular mechanism of DET between graphene and cytochrome c depends on the metal in the bio-organic interface: Co enhances the cathodic current via electron hopping from graphene to haem, whereas Ni exerts the opposite effect via tunnelling.

Removal of acetaminophen through direct electron transfer by reactive Mn2O3: Efficiency, mechanism and pathway

2020 ◽  
pp. 144377
Author(s):  
Weihua Tan ◽  
Yahui Ma ◽  
Wei Ren ◽  
Yuanrou Fan ◽  
Xiang Liu ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Direct Electron Transfer

scholarly journals Amperometric Biosensors Based on Direct Electron Transfer Enzymes

Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4525
Author(s):  
Franziska Schachinger ◽  
Hucheng Chang ◽  
Stefan Scheiblbrandner ◽  
Roland Ludwig
Keyword(s):  
Electron Transfer ◽  
Electrode Materials ◽  
Direct Electron Transfer ◽  
Accurate Determination ◽  
Direct Electrochemistry ◽  
Product Analysis ◽  
Amperometric Biosensors ◽  
Chemical Surface ◽  
Fusion Enzymes ◽  
Cost Efficient

The accurate determination of analyte concentrations with selective, fast, and robust methods is the key for process control, product analysis, environmental compliance, and medical applications. Enzyme-based biosensors meet these requirements to a high degree and can be operated with simple, cost efficient, and easy to use devices. This review focuses on enzymes capable of direct electron transfer (DET) to electrodes and also the electrode materials which can enable or enhance the DET type bioelectrocatalysis. It presents amperometric biosensors for the quantification of important medical, technical, and environmental analytes and it carves out the requirements for enzymes and electrode materials in DET-based third generation biosensors. This review critically surveys enzymes and biosensors for which DET has been reported. Single- or multi-cofactor enzymes featuring copper centers, hemes, FAD, FMN, or PQQ as prosthetic groups as well as fusion enzymes are presented. Nanomaterials, nanostructured electrodes, chemical surface modifications, and protein immobilization strategies are reviewed for their ability to support direct electrochemistry of enzymes. The combination of both biosensor elements—enzymes and electrodes—is evaluated by comparison of substrate specificity, current density, sensitivity, and the range of detection.

scholarly journals Enhancement of Direct Electron Transfer in Graphene Bioelectrodes Containing Novel Cytochrome c Variants with Optimized Heme Orientation

2021 ◽  
pp. 107818
Author(s):  
Miriam Izzo ◽  
Silvio Osella ◽  
Margot Jacquet ◽  
Małgorzata Kiliszek ◽  
Ersan Harputlu ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Cytochrome C ◽  
Direct Electron Transfer

scholarly journals Third-Generation Biosensors Based on the Direct Electron Transfer of Proteins

2004 ◽  
Vol 20 (4) ◽  
pp. 603-609 ◽  
Author(s):  
Wenjun ZHANG ◽  
Genxi LI
Keyword(s):  
Electron Transfer ◽  
Direct Electron Transfer ◽  
Third Generation

Direct electron transfer in immobilized flavoenzyme chemically modified graphite electrodes

1982 ◽  
Vol 141 ◽  
pp. 23-32 ◽  
Author(s):  
Robert M. Ianniello ◽  
Thomas J. Lindsay ◽  
Alexander M. Yacynych
Keyword(s):  
Electron Transfer ◽  
Direct Electron Transfer ◽  
Graphite Electrodes ◽  
Chemically Modified

Direct electron transfer reaction of glucose oxidase at bare silver electrodes and its application in analysis

1997 ◽  
Vol 9 (8) ◽  
pp. 641-644 ◽  
Author(s):  
Zhihui Wen ◽  
Baoxian Ye ◽  
Xingyao Zhou
Keyword(s):  
Electron Transfer ◽  
Glucose Oxidase ◽  
Transfer Reaction ◽  
Direct Electron Transfer ◽  
Electron Transfer Reaction ◽  
Silver Electrodes
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