MOF-derived Carbon Host Associated with Fe and Co Single atoms for Li-Se Batteries

Author(s):  
Yuqing Cao ◽  
Feifei Lei ◽  
Yunliang Li ◽  
Shilun Qiu ◽  
Yan Wang ◽  
...  

Lithium-selenium (Li-Se) batteries is considered as a promising energy storage material due to high electronic conductivity and volume capacity. However, the performance of Li-Se batteries is far away from commercial...

2015 ◽  
Vol 11 ◽  
pp. 368-375 ◽  
Author(s):  
M. Shashikanth ◽  
Binod Khadka ◽  
Yennam Lekhana ◽  
P. Mohan Sai Kiran ◽  
Nikhila Alaparthi ◽  
...  

2020 ◽  
Vol 185 ◽  
pp. 04023
Author(s):  
Liqiong Han ◽  
Yifan Liu ◽  
Rongyu Li

In order to improve the electro-conductibility of new energy storage material-manganese carbonate(MnCO3) and the properties apply to supercapacitors, we produce MnCO3/CB composite at room temperature by using a simple and mild liquid phase deposition method. Using dilute HNO3 to purify and activate the CB(carbon black), then put the handled CB into NH4HCO3/MnSO4 mixed solution for liquid deposition. Observed through infrared and XPS methods, we found that - after purified by dilute HNO3, the negatively charged groups(carboxyl & quinonyl) on CB surface increase, which makes CB uneasy to reunite in water and benefits the producing of a homogeneous compound. Observed the compound under SEM:40nm diameter CB granules wrap the Lotus-shaped MnCO3 granule, and form a porous structure between MnCO3 granules. The result of electro-chemical properties indicated by galvanostatic charge-discharge tests shows that the specific capacity of MnCO3/CB composite electrode material is twice of the pure MnCO3 electrode material, while the MnCO3/CB composite has a good cycle capacitive retention ratio. As a newly discovered energy storage material, MnCO3 provides a new direction to make composite material for supercapacitor electrodes.


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