Influence of synthetic pathway, molecular weight and side chains on properties of indacenodithiophene-benzothiadiazole copolymers made by direct arylation polycondensation

Desiree Adamczak; Andrea Perinot; Hartmut Komber; Anna Illy; Sandra Hultmark; Bianca Passarella; Wen Liang Tan; Sebastian Hutsch; David Becker-Koch; Charlotte Rapley; Alberto D. Scaccabarozzi; Martin Heeney; Yana Vaynzof; Frank Ortmann; Christopher R. McNeill; Christian Müller; Mario Caironi; Michael Sommer

doi:10.1039/d1tc00043h

Influence of synthetic pathway, molecular weight and side chains on properties of indacenodithiophene-benzothiadiazole copolymers made by direct arylation polycondensation

Journal of Materials Chemistry C ◽

10.1039/d1tc00043h ◽

2021 ◽

Vol 9 (13) ◽

pp. 4597-4606

Author(s):

Desiree Adamczak ◽

Andrea Perinot ◽

Hartmut Komber ◽

Anna Illy ◽

Sandra Hultmark ◽

...

Keyword(s):

Molecular Weight ◽

Side Chains ◽

Direct Arylation ◽

Synthetic Pathway ◽

Direct Arylation Polycondensation

Poly(indacenodithiophene-alt-benzothiadiazole) with different side chains and molecular weight is made using two different pathways in which all C–C coupling steps are achieved by C–H activation, and the products are comprehensively investigated.

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High Mobility Ambipolar Diketopyrrolopyrrole-Based Conjugated Polymers Synthesized via Direct Arylation Polycondensation: Influence of Thiophene Moieties and Side Chains

Macromolecules ◽

10.1021/acs.macromol.8b01112 ◽

2018 ◽

Vol 51 (21) ◽

pp. 8752-8760 ◽

Cited By ~ 20

Author(s):

Yao Gao ◽

Junhua Bai ◽

Ying Sui ◽

Yang Han ◽

Yunfeng Deng ◽

...

Keyword(s):

Conjugated Polymers ◽

High Mobility ◽

Side Chains ◽

Direct Arylation ◽

Direct Arylation Polycondensation

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Dimethylacetamide-promoted Direct Arylation Polycondensation of 6,6′-Dibromo-7,7′-diazaisoindigo and (E)-1,2-bis(3,4-difluorothien-2-yl)ethene toward High Molecular Weight n-Type Conjugated Polymers

Chinese Journal of Polymer Science ◽

10.1007/s10118-019-2277-1 ◽

2019 ◽

Vol 37 (11) ◽

pp. 1099-1104 ◽

Cited By ~ 2

Author(s):

Kai Guo ◽

Yu Jiang ◽

Ying Sui ◽

Yun-Feng Deng ◽

Yan-Hou Geng

Keyword(s):

Molecular Weight ◽

Conjugated Polymers ◽

High Molecular Weight ◽

Direct Arylation ◽

Direct Arylation Polycondensation

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Direct Arylation Polycondensation: A Promising Method for the Synthesis of Highly Pure, High-Molecular-Weight Conjugated Polymers Needed for Improving the Performance of Organic Photovoltaics

Advanced Functional Materials ◽

10.1002/adfm.201302851 ◽

2014 ◽

Vol 24 (21) ◽

pp. 3226-3233 ◽

Cited By ~ 102

Author(s):

Junpei Kuwabara ◽

Takeshi Yasuda ◽

Seong Jib Choi ◽

Wei Lu ◽

Koutarou Yamazaki ◽

...

Keyword(s):

Molecular Weight ◽

Conjugated Polymers ◽

High Molecular Weight ◽

Organic Photovoltaics ◽

Promising Method ◽

Direct Arylation ◽

Direct Arylation Polycondensation

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Direct Arylation Polycondensation towards Water/Alcohol-Soluble Conjugated Polymers as Electron Transporting Layers for Organic Solar Cells

Chemical Communications ◽

10.1039/d1cc01128f ◽

2021 ◽

Author(s):

Kaiwen Lin ◽

Qingwu Yin ◽

Zhenfeng Wang ◽

Boming Xie ◽

Chunhui Duan ◽

...

Keyword(s):

Solar Cells ◽

Conjugated Polymers ◽

Organic Solar Cells ◽

Direct Arylation ◽

Direct Arylation Polycondensation ◽

Water Alcohol

Two water/alcohol soluble conjugated polymers (WSCPs), based on naphthalenediimide and amino-functionalized 3,4-(propylenedioxy)thiophene were synthesized via direct arylation polycondensation (DArP). The polymers worked well as electron transporting layers (ETLs) for fullerene-based...

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