Disilane-Bridged Architectures with High Optical Transparency for Optical Limiting

Author(s):  
Hongjie Feng ◽  
Zhikuan Zhou ◽  
Aviwe May ◽  
Jiaying Chen ◽  
John Mack ◽  
...  

A novel tetraphenylethylene (TPE) architecture that makes use of a disilane bridge was developed to successfully prepare organic optical power limiting (OPL) materials with high transparency. The σ-bridged TPE derivatives...

2017 ◽  
Vol 5 (45) ◽  
pp. 11672-11682 ◽  
Author(s):  
C. Yao ◽  
Z. Tian ◽  
D. Jin ◽  
F. Zhao ◽  
Y. Sun ◽  
...  

Two series of Pt(ii) acetylide complexes containing dimesitylborane and phenyl terminal groups with star- and V-shaped configurations were synthesized.


2016 ◽  
Vol 40 (10) ◽  
pp. 8262-8270 ◽  
Author(s):  
Alexander Yu. Tolbin ◽  
Alexander V. Dzuban ◽  
Evgeny V. Shulishov ◽  
Larisa G. Tomilova ◽  
Nikolay S. Zefirov

Phthalocyanine J-type dimers show unusual spectral properties and self-assembly in the solid phase. The optical power limiting effect was theoretically investigated.


2019 ◽  
Vol 48 (40) ◽  
pp. 15105-15113 ◽  
Author(s):  
Senqiang Zhu ◽  
Hao Liu ◽  
Kunyan Wang ◽  
Qian Cheng ◽  
Zhenxing Ma ◽  
...  

Pt(ii) complexes that exhibit long-lived triplet excited state lifetimes are promising for optical power limiting materials.


2000 ◽  
Vol 09 (04) ◽  
pp. 523-530 ◽  
Author(s):  
P. FENEYROU

We report experimental results on a tin phthalocyanine: the nanosecond transient spectroscopy shows a reverse saturable absorption between 490–530 nm and 550–700 nm and the nonlinear transmission provides a better optical power limiting efficiency from 570 nm to 700 nm compared to C 60. This molecule is then combined in a tandem filter with a multiphoton absorber and a mixture of reverse saturable absorbers to achieve neutral-color broadband protection against ns pulses: the transmitted energy is clamped below 2 μ J throughout the visible.


2014 ◽  
Vol 28 (10) ◽  
pp. 1450079 ◽  
Author(s):  
Qusay Mohammed Ali Hassan

The synthesis and the linear and optical limiting properties of a 2-(2-methoxybenzyllideneamino)-5-methylphenylmercuric chloride-doped poly(methylmethacrylate) (PMMA) film are described. The sample exhibits strong optical power limiting under continuous wave (cw) laser at the experimental wavelength. The mechanisms for the optical limiting were discussed on the basis of the two-photon absorption involved in the process. The nonlinear absorption coefficient β of the sample is estimated and its value is found to be 67 × 10-2 cm/W. Our study indicated that the investigated compound-doped PMMA film is a potential candidate for optical limiting applications in low power cw regime.


2015 ◽  
Vol 44 (29) ◽  
pp. 13163-13172 ◽  
Author(s):  
David Recatalá ◽  
Rosa Llusar ◽  
Adam Barlow ◽  
Genmiao Wang ◽  
Marek Samoc ◽  
...  

A series of mixed-ligand diimine–halide and diimine–dithiolene clusters based on the Mo3S7 core have been synthesized. Their optical limiting behavior was assessed by Z-scan techniques, and compared to that of a dithiolene Mo2O2S2-based cluster.


2003 ◽  
Vol 196 (1) ◽  
pp. 289-300 ◽  
Author(s):  
Jacky Wing Yip Lam ◽  
Junwu Chen ◽  
Charles Chi Wang Law ◽  
Han Peng ◽  
Zhiliang Xie ◽  
...  

1994 ◽  
Vol 64 (21) ◽  
pp. 2785-2787 ◽  
Author(s):  
J. E. Wray ◽  
K. C. Liu ◽  
C. H. Chen ◽  
W. R. Garrett ◽  
M. G. Payne ◽  
...  

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