270. The absorption spectrum of cobalt chloride in presence of magnesium chloride in aqueous solution

Author(s):  
O. Rhys Howell ◽  
Albert Jackson
Author(s):  
Owen Rhys Howell ◽  
Albert Jackson ◽  
Eric Keightley Rideal

The change in the absorption spectrum of cobalt chloride in aqueous solution with increasing concentration of hydrochloric acid at constant temperature (20° C) has already been investigated.* It was shown that with increasing concentration of acid up to 5N HCl, no blue constituent was formed. The cobalt atom, therefore, retains its six grouping over this range. The effect of increasing acid concentration is to replace two molecules of water by two atoms of chlorine: [Co(H 2 O) 6 ] → [Co(H 2 O) 4 Cl 2 ].


2020 ◽  
Vol 27 (9) ◽  
pp. 9582-9588 ◽  
Author(s):  
Jiaqi Zhang ◽  
Xiaolan Hu ◽  
Jinpeng Yan ◽  
Li Long ◽  
Yingwen Xue

1992 ◽  
Vol 272 ◽  
Author(s):  
M. Gutiérrez ◽  
A. Henglein

ABSTRACTA radiolysis method is described to prepare isolated cadmium particles in aqueous solution. The spectrum of these particles (narrow band at 260nm) agrees with the spectrum calculated from the optical data of cadmium. Clusters of particles absorb at longer wavelengths. Redox reactions of the particles with methyl viologen, nitrous oxide and carbon tetrachloride were also investigated. It is shown that the absorption spectrum of the particles changes during these reactions as de-clustering takes place.


2015 ◽  
Vol 36 (12) ◽  
pp. 1756-1761 ◽  
Author(s):  
Zhiyun Chen ◽  
Zilin Yang ◽  
Xianlong Du ◽  
Jihua Zhao ◽  
Weiguo Shen

2011 ◽  
Vol 18 (4) ◽  
pp. 557-563 ◽  
Author(s):  
Jana Padežnik Gomilšek ◽  
Alojz Kodre ◽  
Iztok Arčon ◽  
Simone de Panfilis ◽  
Darko Makovec

The approximate barium X-ray atomic absorption in the energy region ofL-edges is reconstructed from the absorption spectrum of an aqueous solution of BaCl2. The result is corroborated by comparison with pure atomic absorption spectra of neighbour elements Xe and Cs. The application of the atomic absorption signal as a proper EXAFS background is demonstrated and discussed in the analysis of Ba hexaferrite nanoparticles with a very weak structural signal. The essential gain is found in the decrease of uncertainty intervals of structural parameters and their correlations. A simple analytical model of the absorption background for the practical EXAFS analysis is demonstrated.


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