375. Complex-ion formation. Part II. The entropies of formation of some metal ammines

Author(s):  
W. S. Fyfe
Keyword(s):  
1930 ◽  
Vol 14 (2) ◽  
pp. 215-222 ◽  
Author(s):  
Kenneth V. Thimann

The effect of the addition of sodium chloride to gelatin solutions is shown from the Donnan relationship to increase the ionisation of the gelatin, the increase produced in acid solutions reaching a maximum at about 1/1000 molar salt concentration. This effect is attributed to the formation of complex ions. From the similar action of calcium and copper chlorides the effective combining power of gelatin for complex positive ion formation is deduced. The bearing of complex ion formation on the zwitter-ionic structure and solubility phenomena of proteins is pointed out.


1961 ◽  
Vol 65 (11) ◽  
pp. 1951-1954 ◽  
Author(s):  
R. A. Osteryoung ◽  
C. Kaplan ◽  
D. L. Hill

1996 ◽  
Vol 33 (8) ◽  
pp. 605-610 ◽  
Author(s):  
F Kirchhoff ◽  
J. M Holender ◽  
M. J Gillan
Keyword(s):  

1954 ◽  
Vol 32 (9) ◽  
pp. 864-866 ◽  
Author(s):  
S. Hill ◽  
F. E. W. Wetmore

Conductivity data have been combined with transport fractions to show that silver chloride in dilute solutions in silver nitrate can be regarded as being almost completely in the form of complex cation. The mobility of the complex ion is shown to be about one-half that of silver ion.


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