Reactions of ferrous and ferric ions with hydrogen peroxide. Part I.—The ferrous ion reaction

1951 ◽  
Vol 47 (0) ◽  
pp. 462-500 ◽  
Author(s):  
W. G. Barb ◽  
J. H. Baxendale ◽  
P. George ◽  
K. R. Hargrave
Keyword(s):  
Hydrogen Peroxide ◽  
Ferrous Ion ◽  
Ferric Ions

Reactions of ferrous and ferric ions with hydrogen peroxide. Part II.—The ferric ion reaction

1951 ◽  
Vol 47 (0) ◽  
pp. 591-616 ◽  
Author(s):  
W. G. Barb ◽  
J. H. Baxendale ◽  
P. George ◽  
K. R. Hargrave
Keyword(s):  
Hydrogen Peroxide ◽  
Ferric Ion ◽  
Ferric Ions

scholarly journals THE RATE CONSTANT OF THE REACTION BETWEEN FERROUS IONS AND HYDROGEN PEROXIDE IN ACID SOLUTION

1957 ◽  
Vol 35 (5) ◽  
pp. 428-436 ◽  
Author(s):  
T. J. Hardwick
Keyword(s):  
Hydrogen Peroxide ◽  
Acid Solution ◽  
Sulphuric Acid ◽  
Acid Concentration ◽  
Rate Constant ◽  
Perchloric Acid ◽  
Ferrous Ion ◽  
Ferrous Ions ◽  
Bimolecular Rate Constant

Identical values of the bimolecular rate constant of the ferrous ion – hydrogen peroxide reaction were obtained from intercomparisons of the methods previously used in following this reaction. In perchloric acid the bimolecular rate constant is unaffected by acid concentration; in sulphuric acid it increases slightly in acid concentrations above 10−2N. The results agree with and explain the differences between those obtained by Baxendale and by Dainton, but are only in marginal agreement with those recently reported by Weiss.

Homogeneous oxidation of phenols in aqueous solution with hydrogen peroxide and ferric ions

1997 ◽  
Vol 36 (2-3) ◽  
pp. 151-154 ◽  
Author(s):  
H. Grigoropoulou ◽  
C. Philippopoulos
Keyword(s):  
Hydrogen Peroxide ◽  
Ferrous Sulphate ◽  
Ph Control ◽  
Chemical Oxidation ◽  
Ferric Ions ◽  
Experimental Conditions ◽  
Oxidation Rates ◽  
Homogeneous Oxidation ◽  
Oxidation Of Phenol ◽  
Ferrous Ammonium

The chemical oxidation of phenol and chlorophenols with hydrogen peroxide in the presence of soluble iron can be economically attractive at low oxidant consumption, leading then to intermediates that are more easily biodegradable. The homogeneous oxidation of phenol and chlorophenols in aqueous solutions with hydrogen peroxide is studied at oxidant : phenol ratio of about 4:1 and 16:1 (mol/mol) at various catalyst concentrations, at ambient temperature without pH control. Ferric chloride, ferric and ferrous sulphate and ferrous ammonium sulphate are used as oxidation catalysts. Ferric salts induce higher oxidation rates than ferrous ones and the nature of the anions present does not affect reaction rate. 4-Chlorophenol is found to be most resistant to oxidation and 2,4,6-Trichlorophenol is not attacked by hydrogen peroxide in the presence of ferric ions at the experimental conditions studied.

Regioselective degradation of [beta] 1,3 glucan by ferrous ion and hydrogen peroxide (Fenton oxidation)

2020 ◽  
Vol 497 ◽  
pp. 108124
Author(s):  
Rafael Ovalle ◽  
Lijie Chen ◽  
Clifford E. Soll ◽  
Carol Wood Moore ◽  
Peter N. Lipke
Keyword(s):  
Hydrogen Peroxide ◽  
Fenton Oxidation ◽  
Ferrous Ion

scholarly journals Reactions of Ferrous and Ferric Ions with Hydrogen Peroxide

Nature ◽  
1949 ◽  
Vol 163 (4148) ◽  
pp. 692-694 ◽  
Author(s):  
W. G. BARB ◽  
J. H. BAXENDALE ◽  
PHILIP GEORGE ◽  
K. R. HARGRAVE
Keyword(s):  
Hydrogen Peroxide ◽  
Ferric Ions
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