scholarly journals Millimeter- and submillimeter-wave spectroscopy of thioformamide and interstellar search toward Sgr B2(N)

2020 ◽  
Vol 642 ◽  
pp. A29 ◽  
Author(s):  
R. A. Motiyenko ◽  
A. Belloche ◽  
R. T. Garrod ◽  
L. Margulès ◽  
H. S. P. Müller ◽  
...  
Keyword(s):  
Interstellar Medium ◽  
Rotational Transition ◽  
High Mass ◽  
Mass Star ◽  
Rotational Spectrum ◽  
Star Forming ◽  
Preferential Formation ◽  
Upper Limits ◽  
Interesting Candidate ◽  
Centrifugal Distortion Constants

Context. Thioformamide NH2CHS is a sulfur-bearing analog of formamide NH2CHO. The latter was detected in the interstellar medium back in the 1970s. Most of the sulfur-containing molecules detected in the interstellar medium are analogs of corresponding oxygen-containing compounds. Therefore, thioformamide is an interesting candidate for a search in the interstellar medium. Aims. A previous study of the rotational spectrum of thioformamide was limited to frequencies below 70 GHz and to transitions with J ≤ 3. The aim of this study is to provide accurate spectroscopic parameters and rotational transition frequencies for thioformamide to enable astronomical searches for this molecule using radio telescope arrays at millimeter wavelengths. Methods. The rotational spectrum of thioformamide was measured and analyzed in the frequency range 150−660 GHz using the Lille spectrometer. We searched for thioformamide toward the high-mass star-forming region Sagittarius (Sgr) B2(N) using the ReMoCA spectral line survey carried out with the Atacama Large Millimeter/submillimeter Array. Results. Accurate rigid rotor and centrifugal distortion constants were obtained from the analysis of the ground state of parent, 34S, 13C, and 15N singly substituted isotopic species of thioformamide. In addition, for the parent isotopolog, the lowest two excited vibrational states, v12 = 1 and v9 = 1, were analyzed using a model that takes Coriolis coupling into account. Thioformamide was not detected toward the hot cores Sgr B2(N1S) and Sgr B2(N2). The sensitive upper limits indicate that thioformamide is nearly three orders of magnitude at least less abundant than formamide. This is markedly different from methanethiol, which is only about two orders of magnitude less abundant than methanol in both sources. Conclusions. The different behavior shown by methanethiol versus thioformamide may be caused by the preferential formation of the latter (on grains) at late times and low temperatures, when CS abundances are depressed. This reduces the thioformamide-to-formamide ratio, because the HCS radical is not as readily available under these conditions.

scholarly journals Millimeter wave spectra of ethyl isocyanate and searches for it in Orion KL and Sagittarius B2

2018 ◽  
Vol 616 ◽  
pp. A173 ◽  
Author(s):  
L. Kolesniková ◽  
E. R. Alonso ◽  
B. Tercero ◽  
J. Cernicharo ◽  
J. L. Alonso
Keyword(s):  
Millimeter Wave ◽  
High Mass ◽  
Mass Star ◽  
Rotational Spectrum ◽  
Torsional Mode ◽  
Star Forming ◽  
Star Forming Regions ◽  
Ethyl Isocyanate ◽  
Wave Region ◽  
Centrifugal Distortion Constants

Context. Relatively high abundances of methyl isocyanate (CH3NCO), a methyl derivative of isocyanic acid (HNCO), found in the Orion KL and Sgr B2 molecular clouds suggest that its ethyl derivative, ethyl isocyanate (CH3CH2NCO), may also be present. Aims. The aim of this work is to provide accurate experimental frequencies of ethyl isocyanate in its ground and excited vibrational states in the millimeter wave region to support searches for it in the interstellar medium. Methods. The rotational spectrum of ethyl isocyanate was recorded at room temperature from 80 to 340 GHz using the millimeter wave spectrometer in Valladolid. Assigned rotational transitions were analyzed using the S -reduced semirigid-rotor Hamiltonian. Results. More than 1100 distinct frequency lines were analyzed for the ground vibrational state of the cis conformer as well as for three vibrational satellites corresponding to successive excitation of the lowest-frequency C–N torsional mode. Newly determined rotational and centrifugal distortion constants were used for searches of spectral features of ethyl isocyanate in Orion KL and Sgr B2 clouds. Upper limits to CH3CH2NCO in these high-mass star-forming regions were obtained.

scholarly journals Nitrogen and hydrogen fractionation in high-mass star-forming cores from observations of HCN and HNC

2018 ◽  
Vol 609 ◽  
pp. A129 ◽  
Author(s):  
L. Colzi ◽  
F. Fontani ◽  
P. Caselli ◽  
C. Ceccarelli ◽  
P. Hily-Blant ◽  
...  
Keyword(s):  
Solar System ◽  
Solar Nebula ◽  
Rotational Transition ◽  
High Mass ◽  
Evolutionary Stage ◽  
Mass Star ◽  
Stellar Cluster ◽  
Star Forming ◽  
Star Forming Regions ◽  
Dense Cores

The ratio between the two stable isotopes of nitrogen, 14N and 15N, is well measured in the terrestrial atmosphere (~272), and for the pre-solar nebula (~441, deduced from the solar wind). Interestingly, some pristine solar system materials show enrichments in 15N with respect to the pre-solar nebula value. However, it is not yet clear if and how these enrichments are linked to the past chemical history because we have only a limited number of measurements in dense star-forming regions. In this respect, dense cores, which are believed to be the precursors of clusters and also contain intermediate- and high-mass stars, are important targets because the solar system was probably born within a rich stellar cluster, and such clusters are formed in high-mass star-forming regions. The number of observations in such high-mass dense cores has remained limited so far. In this work, we show the results of IRAM-30 m observations of the J = 1−0 rotational transition of the molecules HCN and HNC and their 15N-bearing counterparts towards 27 intermediate- and high-mass dense cores that are divided almost equally into three evolutionary categories: high-mass starless cores, high-mass protostellar objects, and ultra-compact Hii regions. We have also observed the DNC(2–1) rotational transition in order to search for a relation between the isotopic ratios D/H and 14N/15N. We derive average 14N/15N ratios of 359 ± 16 in HCN and of 438 ± 21 in HNC, with a dispersion of about 150–200. We find no trend of the 14N/15N ratio with evolutionary stage. This result agrees with what has been found for N2H+ and its isotopologues in the same sources, although the 14N/15N ratios from N2H+ show a higher dispersion than in HCN/HNC, and on average, their uncertainties are larger as well. Moreover, we have found no correlation between D/H and 14N/15N in HNC. These findings indicate that (1) the chemical evolution does not seem to play a role in the fractionation of nitrogen, and that (2) the fractionation of hydrogen and nitrogen in these objects is not related.

scholarly journals D 2 O and HDS in the coma of 67P/Churyumov–Gerasimenko

2017 ◽  
Vol 375 (2097) ◽  
pp. 20160253 ◽  
Author(s):  
K. Altwegg ◽  
H. Balsiger ◽  
J. J. Berthelier ◽  
A. Bieler ◽  
U. Calmonte ◽  
...  
Keyword(s):  
High Ratio ◽  
High Mass ◽  
Mass Star ◽  
Deuterated Water ◽  
Star Forming ◽  
Star Forming Regions ◽  
Upper Limits ◽  
Rosetta Mission ◽  
Low Mass ◽  
Grain Surface

The European Rosetta mission has been following comet 67P/Churyumov–Gerasimenko for 2 years, studying the nucleus and coma in great detail. For most of these 2 years the Rosetta Orbiter Sensor for Ion and Neutral Analysis (ROSINA) has analysed the volatile part of the coma. With its high mass resolution and sensitivity it was able to not only detect deuterated water HDO, but also doubly deuterated water, D 2 O and deuterated hydrogen sulfide HDS. The ratios for [HDO]/[H 2 O], [D 2 O]/[HDO] and [HDS]/[H 2 S] derived from our measurements are (1.05 ± 0.14) × 10 −3 , (1.80 ± 0.9) × 10 −2 and (1.2 ± 0.3) × 10 −3 , respectively. These results yield a very high ratio of 17 for [D 2 O]/[HDO] relative to [HDO]/[H 2 O]. Statistically one would expect just 1/4. Such a high value can be explained by cometary water coming unprocessed from the presolar cloud, where water is formed on grains, leading to high deuterium fractionation. The high [HDS]/[H 2 S] ratio is compatible with upper limits determined in low-mass star-forming regions and also points to a direct correlation of cometary H 2 S with presolar grain surface chemistry. This article is part of the themed issue ‘Cometary science after Rosetta’.

scholarly journals The millimeter-wave spectrum of methyl ketene and the astronomical search for it

2018 ◽  
Vol 619 ◽  
pp. A92 ◽  
Author(s):  
C. Bermúdez ◽  
B. Tercero ◽  
R. A. Motiyenko ◽  
L. Margulès ◽  
J. Cernicharo ◽  
...  
Keyword(s):  
Excited State ◽  
Millimeter Wave ◽  
Ground State ◽  
Wave Spectrum ◽  
High Mass ◽  
Mass Star ◽  
Rotational Spectrum ◽  
Star Forming ◽  
Dark Clouds ◽  
Star Forming Regions

Context. The analysis of isomeric species of a compound observed in the interstellar medium (ISM) is a useful tool to understand the chemistry of complex organic molecules. It could, likewise, assist in the detection of new species. Aims. Our goal consists in analyzing one of the two most stable species of the C3H4O family, methyl ketene, whose actual rotational parameters are not precise enough to allow its detection in the ISM. The obtained parameters will be used to search for it in the high-mass star-forming regions Orion KL and Sagittarius B2, as well as in the cold dark clouds TMC-1 in the Taurus Molecular Cloud and Barnard 1 (B1–b). Methods. A millimeter-wave room-temperature rotational spectrum of methyl ketene was recorded from 50 to 330 GHz. The internal rotation analysis of its ground state and first torsional excited state was performed with the rho-axis method employing the RAM36 program. Results. More than 3000 transitions of the rotational spectrum of the ground state (Kamax = 18) and first torsional excited state (Kamax = 13) of methyl ketene were fitted using a Hamiltonian that contains 41 parameters with a root mean square of 44 kHz. Column density limits were calculated but no lines were detected in the ISM belonging to methyl ketene.

scholarly journals Laboratory rotational spectrum and astronomical search for methoxyacetaldehyde

2018 ◽  
Vol 619 ◽  
pp. A67 ◽  
Author(s):  
L. Kolesniková ◽  
I. Peña ◽  
E. R. Alonso ◽  
B. Tercero ◽  
J. Cernicharo ◽  
...  
Keyword(s):  
Millimeter Wave ◽  
Ethyl Formate ◽  
High Mass ◽  
Spectroscopic Constants ◽  
Mass Star ◽  
Rotational Spectrum ◽  
Stable Conformer ◽  
Dark Cloud ◽  
Star Forming ◽  
Star Forming Regions

Context. Methoxyacetaldehyde belongs to a group of structural isomers with the general formula C3H6O2, of which methyl acetate and ethyl formate are known interstellar molecules. Rotational data available for methoxyacetaldehyde are limited to 40 GHz, which makes predictions at higher frequencies rather uncertain.Aims. The aim of this work is to provide accurate experimental frequencies of methoxyacetaldehyde in the millimeter-wave region to support its detection in the interstellar medium.Methods. The rotational spectrum of methoxyacetaldehyde was recorded at room-temperature from 75 to 120 GHz and from 170 to 310 GHz using the millimeter-wave spectrometer in Valladolid. Additional measurements were also performed at conditions of supersonic expansion from 6 to 18 GHz. The assigned rotational transitions were analyzed using theS-reduced semirigid-rotor Hamiltonian.Results. We newly assigned over 1000 lines for the most stable conformer of methoxyacetaldehyde in its ground state and five lowest excited vibrational states, and precise sets of spectroscopic constants were obtained. We searched for spectral features of methoxyacetaldehyde in the high-mass star-forming regions Orion KL and Sagittarius B2, as well as in the cold dark cloud Barnard 1 (B1-b). No lines belonging to methoxyacetaldehyde were detected above the detection limit of our data. We provide upper limits to the methoxyacetaldehyde colum density in these sources.

scholarly journals Molecular complexity in the interstellar medium

2019 ◽  
Vol 15 (S350) ◽  
pp. 96-99
Author(s):  
Arnaud Belloche
Keyword(s):  
Interstellar Medium ◽  
High Mass ◽  
High Angular Resolution ◽  
Mass Star ◽  
Star Forming ◽  
Rotational Spectra ◽  
Increased Sensitivity ◽  
Molecular Complexity ◽  
Complex Organic ◽  
Made In

AbstractThe search for complex organic molecules in the interstellar medium (ISM) has revealed species of ever greater complexity. This search relies on the progress made in the laboratory to characterize their rotational spectra. Our understanding of the processes that lead to molecular complexity in the ISM builds on numerical simulations that use chemical networks fed by laboratory and theoretical studies. The advent of ALMA and NOEMA has opened a new door to explore molecular complexity in the ISM. Their high angular resolution reduces the spectral confusion of star-forming cores and their increased sensitivity allows the detection of low-abundance molecules that could not be probed before. The complexity of the recently-detected molecules manifests itself not only in terms of number of atoms but also in their molecular structure. We discuss these developments and report on ReMoCA, a new spectral line survey performed with ALMA toward the high-mass star-forming region Sgr B2(N).

scholarly journals First detection of 13CH in the interstellar medium

2020 ◽  
Vol 640 ◽  
pp. A125 ◽  
Author(s):  
Arshia M. Jacob ◽  
Karl M. Menten ◽  
Helmut Wiesemeyer ◽  
Rolf Güsten ◽  
Friedrich Wyrowski ◽  
...  
Keyword(s):  
Interstellar Medium ◽  
Isotopic Ratio ◽  
Far Infrared ◽  
High Spectral Resolution ◽  
High Mass ◽  
Chemical Fractionation ◽  
Mass Star ◽  
Galactocentric Distance ◽  
Star Forming ◽  
Star Forming Regions

In recent years, a plethora of observations with high spectral resolution of sub-millimetre and far-infrared transitions of methylidene (CH), conducted with Herschel and SOFIA, have demonstrated this radical to be a valuable proxy for molecular hydrogen that can be used for characterising molecular gas within the interstellar medium on a Galactic scale, including the CO-dark component. We report the discovery of the 13CH isotopologue in the interstellar medium using the upGREAT receiver on board SOFIA. We have detected the three hyperfine structure components of the ≈2 THz frequency transition from its X2Π1∕2 ground-state towards the high-mass star-forming regions Sgr B2(M), G34.26+0.15, W49(N), and W51E and determined 13CH column densities. The ubiquity of molecules containing carbon in the interstellar medium has turned the determination of the ratio between the abundances of the two stable isotopes of carbon, 12C/13C, into a cornerstone for Galactic chemical evolution studies. Whilst displaying a rising gradient with galactocentric distance, this ratio, when measured using observations of different molecules (CO, H2CO, and others), shows systematic variations depending on the tracer used. These observed inconsistencies may arise from optical depth effects, chemical fractionation, or isotope-selective photo-dissociation. Formed from C+ either through UV-driven or turbulence-driven chemistry, CH reflects the fractionation of C+, and does not show any significant fractionation effects, unlike other molecules that were previously used to determine the 12C/13C isotopic ratio. This makes it an ideal tracer for the 12C/13C ratio throughout the Galaxy. By comparing the derived column densities of 13CH with previously obtained SOFIA data of the corresponding transitions of the main isotopologue 12CH, we therefore derive 12C/13C isotopic ratios toward Sgr B2(M), G34.26+0.15, W49(N) and W51E. Adding our values derived from 12∕13CH to previous calculations of the Galactic isotopic gradient, we derive a revised value of 12C/13C = 5.87(0.45)RGC + 13.25(2.94).

scholarly journals GASTON: Galactic Star Formation with NIKA2. Evidence for the mass growth of star-forming clumps

2021 ◽  
Author(s):  
A J Rigby ◽  
N Peretto ◽  
R Adam ◽  
P Ade ◽  
M Anderson ◽  
...  
Keyword(s):  
Star Formation ◽  
Large Scale ◽  
Galactic Plane ◽  
High Sensitivity ◽  
High Mass ◽  
Evolutionary Stage ◽  
Mass Star ◽  
Mass Growth ◽  
Star Forming ◽  
Compact Source

Abstract Determining the mechanism by which high-mass stars are formed is essential for our understanding of the energy budget and chemical evolution of galaxies. By using the New IRAM KIDs Array 2 (NIKA2) camera on the Institut de Radio Astronomie Millimétrique (IRAM) 30-m telescope, we have conducted high-sensitivity and large-scale mapping of a fraction of the Galactic plane in order to search for signatures of the transition between the high- and low-mass star-forming modes. Here, we present the first results from the Galactic Star Formation with NIKA2 (GASTON) project, a Large Programme at the IRAM 30-m telescope which is mapping ≈2 deg2 of the inner Galactic plane (GP), centred on ℓ = 23${_{.}^{\circ}}$9, b = 0${_{.}^{\circ}}$05, as well as targets in Taurus and Ophiuchus in 1.15 and 2.00 mm continuum wavebands. In this paper we present the first of the GASTON GP data taken, and present initial science results. We conduct an extraction of structures from the 1.15 mm maps using a dendrogram analysis and, by comparison to the compact source catalogues from Herschel survey data, we identify a population of 321 previously-undetected clumps. Approximately 80 per cent of these new clumps are 70 μm-quiet, and may be considered as starless candidates. We find that this new population of clumps are less massive and cooler, on average, than clumps that have already been identified. Further, by classifying the full sample of clumps based upon their infrared-bright fraction – an indicator of evolutionary stage – we find evidence for clump mass growth, supporting models of clump-fed high-mass star formation.

scholarly journals The prospects for observing [O iii] 52 micron emission from galaxies during the Epoch of Reionization

2021 ◽  
Vol 504 (1) ◽  
pp. 723-730
Author(s):  
Shengqi Yang ◽  
Adam Lidz ◽  
Gergö Popping
Keyword(s):  
Fine Structure ◽  
Interstellar Medium ◽  
Emission Line ◽  
Parameter Space ◽  
Gas Density ◽  
Star Forming ◽  
Upper Limits ◽  
Redshift Galaxies

ABSTRACT The [O iii] 88 $\mu$m fine-structure emission line has been detected into the Epoch of Reionization (EoR) from star-forming galaxies at redshifts 6 < z ≲ 9 with ALMA. These measurements provide valuable information regarding the properties of the interstellar medium (ISM) in the highest redshift galaxies discovered thus far. The [O iii] 88 $\mu$m line observations leave, however, a degeneracy between the gas density and metallicity in these systems. Here, we quantify the prospects for breaking this degeneracy using future ALMA observations of the [O iii] 52 $\mu$m line. Among the current set of 10 [O iii] 88 $\mu$m emitters at 6 < z ≲ 9, we forecast 52 $\mu$m detections (at 6σ) in SXDF-NB1006-2, B14-6566, J0217-0208, and J1211-0118 within on-source observing times of 2–10 h, provided their gas densities are larger than about nH ≳ 102–103 cm−3. Other targets generally require much longer integration times for a 6σ detection. Either successful detections of the 52 $\mu$m line or reliable upper limits will lead to significantly tighter constraints on ISM parameters. The forecasted improvements are as large as ∼3 dex in gas density and ∼1 dex in metallicity for some regions of parameter space. We suggest SXDF-NB1006-2 as a promising first target for 52 $\mu$m line measurements. We discuss how such measurements will help in understanding the mass–metallicity relationship during the EoR.

scholarly journals Looking for outflow and infall signatures in high-mass star-forming regions

2012 ◽  
Vol 538 ◽  
pp. A140 ◽  
Author(s):  
P. D. Klaassen ◽  
L. Testi ◽  
H. Beuther
Keyword(s):  
High Mass ◽  
Mass Star ◽  
Star Forming ◽  
Star Forming Regions
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