Studies of Lithium Hydride Systems. III. Solid—Liquid Equilibrium in the Lithium Bromide—Lithium Hydride and Lithium Iodide—Lithium Hydride Systems

1966 ◽  
Vol 44 (3) ◽  
pp. 884-889 ◽  
Author(s):  
Carl E. Johnson ◽  
Scott E. Wood ◽  
Carl E. Crouthamel
Keyword(s):  
Lithium Bromide ◽  
Lithium Hydride ◽  
Lithium Iodide ◽  
Liquid Equilibrium ◽  
Solid Liquid

Studies of Lithium Hydride Systems. I. Solid-Liquid Equilibrium in the Lithium Chloride-Lithium Hydride System

1964 ◽  
Vol 3 (11) ◽  
pp. 1487-1491 ◽  
Author(s):  
Carl E. Johnson ◽  
Scott E. Wood ◽  
Carl E. Crouthamel
Keyword(s):  
Lithium Chloride ◽  
Lithium Hydride ◽  
Liquid Equilibrium ◽  
Solid Liquid

Solid–Liquid Equilibrium in the Lithium Lithium Hydride System

1958 ◽  
Vol 62 (2) ◽  
pp. 220-222 ◽  
Author(s):  
Charles E. Messer ◽  
Edwin B. Damon ◽  
P. Calvin Maybury ◽  
John Mellor ◽  
Regina A. Seales
Keyword(s):  
Lithium Hydride ◽  
Liquid Equilibrium ◽  
Solid Liquid

Higher hydrates of lithium chloride, lithium bromide and lithium iodide

2018 ◽  
Vol 74 (2) ◽  
pp. 194-202 ◽  
Author(s):  
Julia Sohr ◽  
Horst Schmidt ◽  
Wolfgang Voigt
Keyword(s):  
Hydrogen Bond ◽  
Crystal Structures ◽  
Lithium Chloride ◽  
Lithium Bromide ◽  
Structure Type ◽  
Lithium Cation ◽  
Formula Unit ◽  
Lithium Iodide ◽  
Hydrogen Bond Networks ◽  
Solid Liquid

For lithium halides, LiX (X = Cl, Br and I), hydrates with a water content of 1, 2, 3 and 5 moles of water per formula unit are known as phases in aqueous solid–liquid equilibria. The crystal structures of the monohydrates of LiCl and LiBr are known, but no crystal structures have been reported so far for the higher hydrates, apart from LiI·3H2O. In this study, the crystal structures of the di- and trihydrates of lithium chloride, lithium bromide and lithium iodide, and the pentahydrates of lithium chloride and lithium bromide have been determined. In each hydrate, the lithium cation is coordinated octahedrally. The dihydrates crystallize in the NaCl·2H2O or NaI·2H2O type structure. Surprisingly, in the tri- and pentahydrates of LiCl and LiBr, one water molecule per Li+ ion remains uncoordinated. For LiI·3H2O, the LiClO4·3H2O structure type was confirmed and the H-atom positions have been fixed. The hydrogen-bond networks in the various structures are discussed in detail. Contrary to the monohydrates, the structures of the higher hydrates show no disorder.

Measurement and Correlation of Solubility of LiBr in Binary Solvents Formed by Acetone and Water Using LIFAC Model

2012 ◽  
Vol 455-456 ◽  
pp. 911-918 ◽  
Author(s):  
Bo Jiang ◽  
Li Sheng Wang ◽  
Mi Yi Li
Keyword(s):  
Experimental Data ◽  
Analytical Method ◽  
Mixed Solvents ◽  
Lithium Bromide ◽  
Binary Solvents ◽  
Interaction Parameters ◽  
Liquid Equilibrium ◽  
Acetone Water ◽  
Solid Liquid ◽  
Mixed Water

The solubility of lithium bromide in mixed solvents formed by acetone and water was determined in the temperature range between (293.15 and 323.15) K using a static analytical method. The solubilities of LiBr in mixed water-acetone solutions are predicted with the LIFAC model and its original interaction parameters. The average absolute deviations of the calculated values from the experimental data and mean relative deviations for this system were 0.0742 and 0.7349, respectively .The results show that the LIFAC model can be used to predict solid-liquid equilibrium of Acetone + water + Lithium Bromide.

Study on the solid-liquid equilibrium of l-malic acid in binary solvents

2021 ◽  
Vol 325 ◽  
pp. 115113
Author(s):  
Zhicheng Gao ◽  
Ying Li ◽  
Xunqiu Wang
Keyword(s):  
Malic Acid ◽  
Binary Solvents ◽  
Liquid Equilibrium ◽  
Solid Liquid
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