Internal Molecular Motions of Large Amplitude Illustrated by the Symmetrical Vibration of Ammonia

1948 ◽  
Vol 16 (4) ◽  
pp. 310-323 ◽  
Author(s):  
R. R. Newton ◽  
L. H. Thomas
1990 ◽  
Vol 45 (3-4) ◽  
pp. 343-348 ◽  
Author(s):  
Hiromitsu Terao ◽  
Tsutomu Okuda

Abstract The 81Br and 127I NQR spectra were recorded in CH3NH3 HgBr3 and CH3NH HgI3 , respectively. In addition to a phase transition at 338 K, successive phase transitions take place at 127 ± 1, 184±1 and 243±5 K in CH3NH3 HgBr3. On heating, the resonance lines of CH3NH3HgI3 disappear near a phase transition at 328 K and one line appears above this temperature. The temperature variations of the resonance frequencies of the terminal halogen atoms in both crystals are extraordinarily steep. This indicates the large amplitude molecular motions expected for the CH3NH3 cations which are linked to the terminal halogen atoms through N-H ··· X type H-bonding.


1985 ◽  
Vol 82 ◽  
pp. 293-303 ◽  
Author(s):  
A.H. Fuchs ◽  
J. Virlet ◽  
D. Andre ◽  
H. Szwarc

1966 ◽  
Vol 25 ◽  
pp. 197-222 ◽  
Author(s):  
P. J. Message

An analytical discussion of that case of motion in the restricted problem, in which the mean motions of the infinitesimal, and smaller-massed, bodies about the larger one are nearly in the ratio of two small integers displays the existence of a series of periodic solutions which, for commensurabilities of the typep+ 1:p, includes solutions of Poincaré'sdeuxième sortewhen the commensurability is very close, and of thepremière sortewhen it is less close. A linear treatment of the long-period variations of the elements, valid for motions in which the elements remain close to a particular periodic solution of this type, shows the continuity of near-commensurable motion with other motion, and some of the properties of long-period librations of small amplitude.To extend the investigation to other types of motion near commensurability, numerical integrations of the equations for the long-period variations of the elements were carried out for the 2:1 interior case (of which the planet 108 “Hecuba” is an example) to survey those motions in which the eccentricity takes values less than 0·1. An investigation of the effect of the large amplitude perturbations near commensurability on a distribution of minor planets, which is originally uniform over mean motion, shows a “draining off” effect from the vicinity of exact commensurability of a magnitude large enough to account for the observed gap in the distribution at the 2:1 commensurability.


Author(s):  
B. Roy Frieden

Despite the skill and determination of electro-optical system designers, the images acquired using their best designs often suffer from blur and noise. The aim of an “image enhancer” such as myself is to improve these poor images, usually by digital means, such that they better resemble the true, “optical object,” input to the system. This problem is notoriously “ill-posed,” i.e. any direct approach at inversion of the image data suffers strongly from the presence of even a small amount of noise in the data. In fact, the fluctuations engendered in neighboring output values tend to be strongly negative-correlated, so that the output spatially oscillates up and down, with large amplitude, about the true object. What can be done about this situation? As we shall see, various concepts taken from statistical communication theory have proven to be of real use in attacking this problem. We offer below a brief summary of these concepts.


1978 ◽  
Vol 126 (9) ◽  
pp. 67-99 ◽  
Author(s):  
N.N. Korst ◽  
L.I. Antsiferova

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