Rhombohedral-to-tetragonal phase transformation and thermal depolarization in relaxor-based ferroelectric single crystal

2008 ◽  
Vol 93 (8) ◽  
pp. 082903 ◽  
Author(s):  
W. S. Chang ◽  
L. C. Lim ◽  
P. Yang ◽  
C.-S. Tu
Keyword(s):  
Phase Transformation ◽  
Single Crystal ◽  
Tetragonal Phase ◽  
Ferroelectric Single Crystal

Phase transformation in relaxor-ferroelectric single crystal [Pb(Sc1/2Nb1/2)O3]0.58–[PbTiO3]0.42

2014 ◽  
Vol 29 (9) ◽  
pp. 1054-1061 ◽  
Author(s):  
Shanmugam Velu Rajasekaran ◽  
Srungarpu Nagabhusan Achary ◽  
Sadequa J. Patwe ◽  
Ramasamy Jayavel ◽  
Garamilla Mangamma ◽  
...  
Keyword(s):  
Phase Transformation ◽  
Single Crystal ◽  
Relaxor Ferroelectric ◽  
Ferroelectric Single Crystal ◽  
Image Position

Abstract

Ferroelectric Domain Structure of Pb(Zr.52Ti.48)03

1980 ◽  
Vol 38 ◽  
pp. 214-215
Author(s):  
E.K. Goo ◽  
R.K. Mishra
Keyword(s):  
Phase Transformation ◽  
Domain Structure ◽  
Tetragonal Phase ◽  
Ferroelectric Domain ◽  
Cubic Phase ◽  
Ion Milling ◽  
Thin Foils ◽  
Ferroelectric Domain Structure ◽  
Ferroelectric Domains

Ferroelectric domains are twins that are formed when PZT undergoes a phase transformation from a non-ferroelectric cubic phase to a ferroelectric tetragonal phase upon cooling below ∼375°C.,1 The tetragonal phase is spontaneously polarized in the direction of c-axis, making each twin a ferroelectric domain. Thin foils of polycrystalline Pb (Zr.52Ti.48)03 were made by ion milling and observed in the Philips EM301 with a double tilt stage.

Phase transformation and preferred orientation in carboxylate derived ZrO2 thin films on silicon substates

1992 ◽  
Vol 7 (11) ◽  
pp. 3065-3071 ◽  
Author(s):  
Peir-Yung Chu ◽  
Isabelle Campion ◽  
Relva C. Buchanan
Keyword(s):  
Thin Films ◽  
Heat Treatment ◽  
Phase Transformation ◽  
Heating Rate ◽  
Tetragonal Phase ◽  
Monoclinic Phase ◽  
Preferred Orientation ◽  
Si Substrate ◽  
Interfacial Diffusion ◽  
Deposited Films

Phase transformation and preferred orientation in ZrO2 thin films, deposited on Si(111) and Si(100) substrates, and prepared by heat treatment from carboxylate solution precursors were investigated. The deposited films were amorphous below 450 °C, transforming gradually to the tetragonal and monoclinic phases on heating. The monoclinic phase developed from the tetragonal phase displacively, and exhibited a strong (111) preferred orientation at temperature as low as 550 °C. The degree of preferred orientation and the tetragonal-to-monoclinic phase transformation were controlled by heating rate, soak temperature, and time. Interfacial diffusion into the film from the Si substrate was negligible at 700 °C and became significant only at 900 °C, but for films thicker than 0.5 μm, overall preferred orientation exceeded 90%.

scholarly journals Nucleation barriers at corners for a cubic-to-tetragonal phase transformation

2015 ◽  
Vol 145 (4) ◽  
pp. 715-724 ◽  
Author(s):  
Peter Bella ◽  
Michael Goldman
Keyword(s):  
Phase Transformation ◽  
Tetragonal Phase ◽  
Scaling Law ◽  
Energetic Cost ◽  
Minimal Energy ◽  
Physical Experiments ◽  
Domain With A Corner ◽  
Appl Math ◽  
Good Agreement

We are interested in the energetic cost of a martensitic inclusion of volume V in austenite for the cubic-to-tetragonal phase transformation. In contrast with the work of Knüpfer, Kohn and Otto (Commun. Pure Appl. Math.66 (2013), 867–904), we consider a domain with a corner and obtain a better scaling law for the minimal energy (Emin ∼ min(V2/3, V7/9)). Our predictions are in good agreement with physical experiments where nucleation of martensite is usually observed near the corners of the specimen.

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