Doped transport layers are essential for achieving high efficiency in organic light emitting diodes (OLEDs). We have studied the effect of doping the electron transport layer (ETL), tris-(8-hydroxyquinoline) aluminum (Alq3) with different percentages of lithium fluoride (LiF). We have also studied the effect of different electron blocking layers (EBLs) such as Tris (4-carbazoyl-9-ylphenyl)amine (TCTA), N,N'-Bis (naphthalen-1-yl)-N,N'-bis(phenyl)-benzidine(NPB), and Di-[4-(N,N-di-p-tolyl-amino)-phenyl]cyclohexane (TAPC) in an Alq3:2,3,6,7-Tetrahydro-1,1,7,7,-tetramethyl-1H, 5H, 11H −10-(2-benzothiazolyl)quinolizino[9,9a, 1gh] coumarin (C545T) based organic light emitting diode (OLED) with optimized ETL doping. TCTA was found to effectively block the electrons and influence the recombination region in the process. At a brightness of 1000 cd/m2, an improvement of 27.8% was observed in external quantum efficiency (EQE) for the device with TCTA as the EBL and doped Alq3 as the ETL, compared to the one with just NPB as both EBL and HTL.