An Aqueous Supramolecular Side-Chain Polymer Designed for Molecular Loading

2010 ◽  
Vol 63 (4) ◽  
pp. 627 ◽  
Author(s):  
Jin Geng ◽  
Dezhi Jiao ◽  
Urs Rauwald ◽  
Oren A. Scherman
Keyword(s):  
Self Assembly ◽  
Chain Transfer ◽  
The Self ◽  
Side Chain ◽  
Side Chains ◽  
Chain Polymer ◽  
Reversible Addition ◽  
Recognition Motifs ◽  
Chain Transfer Polymerization

Hydrophilic copolymers containing recognition motifs based on 2-naphthol moieties in their side chains for the self-assembly with cucurbit[8]uril (CB[8]), have been prepared by reversible addition–fragmentation chain transfer polymerization. Self-assembly of the copolymer with both redox sensitive hydrophilic and hydrophobic viologen derivatives in the presence of CB[8] has been investigated.

scholarly journals Synthesis of aminated polystyrene and its self-assembly with nanoparticles at oil/water interface

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 317-327
Author(s):  
Chenliang Shi ◽  
Ling Lin ◽  
Yukun Yang ◽  
Wenjia Luo ◽  
Maoqing Deng ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Self Assembly ◽  
Carbon Dots ◽  
Chain Transfer ◽  
Functionalized Polymers ◽  
Amino Groups ◽  
One Dimensional ◽  
Reversible Addition ◽  
Oil Water ◽  
Chain Transfer Polymerization

AbstractThe influence of density of amino groups, nanoparticles dimension and pH on the interaction between end-functionalized polymers and nanoparticles was extensively investigated in this study. PS–NH2 and H2N–PS–NH2 were prepared using reversible addition–fragmentation chain transfer polymerization and atom transfer radical polymerization. Zero-dimensional carbon dots with sulfonate groups, one-dimensional cellulose nanocrystals with sulfate groups and two-dimensional graphene with sulfonate groups in the aqueous phase were added into the toluene phase containing the aminated PS. The results indicate that aminated PS exhibited the strongest interfacial activity after compounding with sulfonated nanoparticles at a pH of 3. PS ended with two amino groups performed better in reducing the water/toluene interfacial tension than PS ended with only one amino group. The dimension of sulfonated nanoparticles also contributed significantly to the reduction in the water/toluene interfacial tension. The minimal interfacial tension was 4.49 mN/m after compounding PS–NH2 with sulfonated zero-dimensional carbon dots.

Hierarchical superstructures of norbornene-based polymers depending on dendronized side-chains

2016 ◽  
Vol 7 (33) ◽  
pp. 5304-5311 ◽  
Author(s):  
Dae-Yoon Kim ◽  
Dong-Gue Kang ◽  
Suyong Shin ◽  
Tae-Lim Choi ◽  
Kwang-Un Jeong
Keyword(s):  
Self Assembly ◽  
Ring Opening ◽  
Main Chain ◽  
The Self ◽  
Side Chain ◽  
Side Chains ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Main Chain Polymers

For understanding the self-assembly behaviours of norbornene-based main-chain polymers depending on side-chain pendants, a series of polynorbornenes containing the programmed dendrons is newly designed and successfully synthesized via ring opening metathesis polymerization.

Influence of side-chain interactions on the self-assembly of discotic tricarboxyamides: a crystallographic insight

RSC Advances ◽  
2015 ◽  
Vol 5 (40) ◽  
pp. 31845-31851 ◽  
Author(s):  
Arpita Paikar ◽  
Apurba Pramanik ◽  
Debasish Haldar
Keyword(s):  
Self Assembly ◽  
The Self ◽  
Side Chain ◽  
Side Chains ◽  
Fiber Network

Side chains interactions promote the self-assembly of discotic tricarboxyamides to form an entangled fiber network and thermo responsive gel.

Brush macromolecules with thermo-sensitive coil backbones and pendant polypeptide side chains: synthesis, self-assembly and functionalization

2015 ◽  
Vol 6 (8) ◽  
pp. 1316-1324 ◽  
Author(s):  
Zheng Wei ◽  
Shuzhe Zhu ◽  
Hanying Zhao
Keyword(s):  
Self Assembly ◽  
Ring Opening ◽  
Chain Transfer ◽  
Ring Opening Polymerization ◽  
Side Chains ◽  
Reversible Addition

Macromolecular brushes with thermo-sensitive coil backbones and pendant poly(γ-benzyl-l-glutamate) side chains were synthesized by reversible addition–fragmentation chain transfer and ring-opening polymerization. Functionalization and self-assembly of the macromolecules were investigated.

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