Heterocyclic-Functionalized Organic Dyes for Dye-Sensitized Solar Cells: Tuning Solar Cell Performance by Structural Modification

2012 ◽  
Vol 65 (9) ◽  
pp. 1203 ◽  
Author(s):  
Qianqian Li ◽  
Zhongxing Jiang ◽  
Jingui Qin ◽  
Zhen Li

Due to their high conversion efficiency and low cost of production, dye-sensitized solar cells based on organic dyes have attracted considerable attention. By utilizing various heterocycles as construction blocks for organic dyes, the performance of solar cells was optimized to exhibit good light-harvesting features and suppress interfacial recombinations. The aim of this review is to highlight recent progress in the molecular design of heterocyclic-functionalized organic dyes for efficient dye-sensitized solar cells, and special attention has been paid to the relationship between chemical structure and the photovoltaic performance of dye-sensitized solar cells based on these dyes.

2014 ◽  
Vol 14 (10) ◽  
pp. 7938-7942 ◽  
Author(s):  
Hyo Jeong Jo ◽  
Jung Eun Nam ◽  
Kyoseung Sim ◽  
Dae-Hwan Kim ◽  
Jae Hong Kim ◽  
...  

2020 ◽  
Vol 44 (30) ◽  
pp. 12909-12915
Author(s):  
Yi-Qiao Yan ◽  
Yi-Zhou Zhu ◽  
Pan-Pan Dai ◽  
Jun Han ◽  
Mao Yan ◽  
...  

Effects of hetero-donors on the photovoltaic performance of tetraphenylethylene-based organic dyes were systematically investigated.


2017 ◽  
Vol 2017 ◽  
pp. 1-10 ◽  
Author(s):  
Carolynne Zie Wei Sie ◽  
Zainab Ngaini

Sensitization of heavy metal free organic dyes onto TiO2 thin films has gained much attention in dye sensitized solar cells (DSSCs). A series of new kojic acid based organic dyes KA1–4 were synthesized via nucleophilic substitution of azobenzene bearing different vinyl chains A1–4 with kojyl chloride 4. Azo dyes KA1–4 were characterized for photophysical properties employing absorption spectrometry and photovoltaic characteristic in TiO2 thin film. The presence of vinyl chain in A1–4 improved the photovoltaic performance from 0.20 to 0.60%. The introduction of kojic acid obtained from sago waste further increases the efficiency to 0.82–1.54%. Based on photovoltaic performance, KA4 achieved the highest solar to electrical energy conversion efficiency (η = 1.54%) in the series.


2017 ◽  
Vol 2017 ◽  
pp. 1-8
Author(s):  
Saeid Vafaei ◽  
Kazuhiro Manseki ◽  
Soki Horita ◽  
Masaki Matsui ◽  
Takashi Sugiura

We present for the first time a synthetic method of obtaining 1D TiO2 nanorods with sintering methods using bundle-shaped 3D rutile TiO2 particles (3D BR-TiO2) with the dimensions of around 100 nm. The purpose of this research is (i) to control crystallization of the mixture of two kinds of TiO2 semiconductor nanocrystals, that is, 3D BR-TiO2 and spherical anatase TiO2 (SA-TiO2) on FTO substrate via sintering process and (ii) to establish a new method to create photoanodes in dye-sensitized solar cells (DSSCs). In addition, we focus on the preparation of low-cost and environmentally friendly titania electrode by adopting the “water-based” nanofluids. Our results provide useful guidance on how to improve the photovoltaic performance by reshaping the numerous 3D TiO2 particles to 1D TiO2-based electrodes with sintering technique.


2020 ◽  
Vol 10 (6) ◽  
pp. 2149
Author(s):  
Manuel Meneghetti ◽  
Aldo Talon ◽  
Elti Cattaruzza ◽  
Emilio Celotti ◽  
Elisabetta Bellantuono ◽  
...  

During the last two decades, Dye Sensitized Solar Cells (DSSCs) have received a great deal of attention as a promising, low-cost alternative to conventional silicon photovoltaic devices. Natural dye molecules can be used as a sensitizer for their low cost, good light absorbance, easy preparation process, and biodegradability. In this study, dyes were obtained from wine lees, the last by-product of winemaking process, supplied by a venetian winery (Italy). Polyphenols, like tannins and anthocyanins, which were extracted from winemaking lees, were adsorbed on a nanostructured ordered mesoporous titanium dioxide, previously treated at different temperatures (400–600 °C). Both dyes and titania semiconductor samples were studied with different techniques. The tests were carried out on prototypes to evaluate the cell power and the photocurrent generated under simulated solar light irradiation. The obtained solar energy conversion efficiencies are comparable to those that were reported in literature by using organic dyes extracted from vegetables, fruits, and plants. It is significant that these dyes are largely available and cost effective, since recovered from a waste otherwise to be disposed of, opening up a perspective of feasibility for inexpensive and environmentally friendly dye solar cells to generate green electricity and transforming agri-food waste into a resource.


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