Halogen Functionalization of Aluminium Fumarate Metal–Organic Framework via In Situ Hydrochlorination of Acetylenedicarboxylic Acid

2019 ◽  
Vol 72 (10) ◽  
pp. 835 ◽  
Author(s):  
Tobie J. Matemb Ma Ntep ◽  
Wei Wu ◽  
Hergen Breitzke ◽  
Carsten Schlüsener ◽  
Bastian Moll ◽  
...  
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Fold Increase ◽  
Aluminium Chloride ◽  
One Pot ◽  
Metal Organic ◽  
Acetylenedicarboxylic Acid ◽  
Adsorption Of Co2 ◽  
Organic Framework

The successful chloro-functionalization of aluminium fumarate (MIL-53-Fum) was achieved by in situ hydrochlorination of acetylenedicarboxylic acid on reaction with aluminium chloride resulting in the formation of the aluminium chlorofumarate metal–organic framework (MIL-53-Fum-Cl=[Al(OH)(Fum-Cl)]) in a one-pot reaction. The chloro functional groups decorating the pores enhance gas (CO2, CH4, and H2) sorption capacities and affinity compared with the non-functionalized MIL-53-Fum. The functionalization also results in a 2-fold increase in the selective adsorption of CO2 over CH4 compared with MIL-53-Fum.

scholarly journals Mechanochemical Approaches Towards the in Situ Confinement of 5-FU Anti-Cancer Drug Within MIL-100 (Fe) Metal-Organic Framework

2020 ◽  
Author(s):  
Barbara Souza ◽  
Jin-Chong Tan
Keyword(s):  
Drug Release ◽  
Metal Organic Framework ◽  
Cancer Drug ◽  
One Pot ◽  
Host Interactions ◽  
Anti Cancer ◽  
Metal Organic ◽  
Iron Based ◽  
Organic Framework

We report two solvent-free mechanochemical methods to achieve one‑pot encapsulation of anti-cancer drug 5‑Fluorouracil (5‑FU) in the iron-based MIL‑100 metal-organic framework (MOF). We compare the structural and physicochemical properties of drug@MIL‑100 systems derived from <i>in situ </i>manual and vortex grinding, where the former exhibits a slower drug release due to stronger guest-host interactions.

An unusual (3,6)-connected microporous metal–organic framework based on tetrahedral Zn4 clusters with selective adsorption of CO2

CrystEngComm ◽  
2011 ◽  
Vol 13 (15) ◽  
pp. 4823 ◽  
Author(s):  
Rong-Rong Zeng ◽  
Quan-Guo Zhai ◽  
Shu-Ni Li ◽  
Yu-Cheng Jiang ◽  
Man-Cheng Hu
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Adsorption Of Co2 ◽  
Organic Framework

A metal–organic framework based on cyclotriphosphazene-functionalized hexacarboxylate for selective adsorption of CO2 and C2H6 over CH4 at room temperature

CrystEngComm ◽  
2015 ◽  
Vol 17 (33) ◽  
pp. 6314-6319 ◽  
Author(s):  
Yajing Ling ◽  
Chengling Song ◽  
Yunlong Feng ◽  
Mingxing Zhang ◽  
Yabing He
Keyword(s):  
Room Temperature ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Adsorption Of Co ◽  
Adsorption Of Co2 ◽  
Organic Framework

A new MOF constructed from a flexible cyclotriphosphazene-functionalized hexacarboxylate exhibits selective adsorption of CO2 and C2H6 over CH4 at room temperature.

A Distorted [Mn2(COO)4N2] Cluster Based Metal–Organic Framework with (3,3,6) Topology and Selective Adsorption of CO2

2017 ◽  
Vol 17 (4) ◽  
pp. 2223-2227 ◽  
Author(s):  
Jingjing Jiang ◽  
Qian Wang ◽  
Mingxing Zhang ◽  
Junfeng Bai
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Adsorption Of Co2 ◽  
Organic Framework

A new porous 2D copper(II) metal–organic framework for selective adsorption of CO2 over N2

2013 ◽  
Vol 38 ◽  
pp. 104-107 ◽  
Author(s):  
Da-Shu Chen ◽  
Jia-Ming Cheng ◽  
Li-Bo Sun ◽  
Zhi-Qiang Liang ◽  
Kui-Zhan Shao ◽  
...  
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Adsorption Of Co2 ◽  
Organic Framework

A novel 3-fold interpenetration metal–organic framework with tunable luminescence and selective adsorption of CO2 properties

2015 ◽  
Vol 39 (12) ◽  
pp. 9075-9078 ◽  
Author(s):  
Rong-Guang Lin ◽  
Gao-Juan Cao ◽  
Jian-Di Lin ◽  
Yu-Lin Wang
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Luminescence Properties ◽  
Adsorption Behaviors ◽  
Metal Organic ◽  
Adsorption Of Co2 ◽  
Organic Framework

A novel acylamide metal–organic framework (MOF) with 3-fold interpenetration has been synthesized, which shows high selective adsorption behaviors of CO2 and tunable luminescence properties dependent on excitation wavelengths.

Ultramicroporous Metal–Organic Framework Qc-5-Cu for Highly Selective Adsorption of CO2 from C2H4 Stream

2020 ◽  
Vol 59 (7) ◽  
pp. 3153-3161
Author(s):  
Tengjiao He ◽  
Yonghou Xiao ◽  
Qidong Zhao ◽  
Mengxue Zhou ◽  
Gaohong He
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Adsorption Of Co2 ◽  
Organic Framework

Selective adsorption of CO2/CH4 and CO2/N2 within a charged metal–organic framework

2014 ◽  
Vol 2 (42) ◽  
pp. 17771-17778 ◽  
Author(s):  
Lidan Kong ◽  
Ruyi Zou ◽  
Wenzhu Bi ◽  
Ruiqin Zhong ◽  
Weijun Mu ◽  
...  
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Adsorption Of Co2 ◽  
Anionic Framework ◽  
Organic Framework

A new ultramicroporous metal–organic framework with an anionic framework and counter cations accommodated in the large channels is reported for CO2 capture.

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