A metal–organic framework based on cyclotriphosphazene-functionalized hexacarboxylate for selective adsorption of CO2 and C2H6 over CH4 at room temperature

CrystEngComm ◽  
2015 ◽  
Vol 17 (33) ◽  
pp. 6314-6319 ◽  
Author(s):  
Yajing Ling ◽  
Chengling Song ◽  
Yunlong Feng ◽  
Mingxing Zhang ◽  
Yabing He
Keyword(s):  
Room Temperature ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Adsorption Of Co ◽  
Adsorption Of Co2 ◽  
Organic Framework

A new MOF constructed from a flexible cyclotriphosphazene-functionalized hexacarboxylate exhibits selective adsorption of CO2 and C2H6 over CH4 at room temperature.

A highly robust metal–organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of CO2 over CH4

2015 ◽  
Vol 51 (46) ◽  
pp. 9463-9466 ◽  
Author(s):  
Hongming He ◽  
Yang Song ◽  
Chuanqi Zhang ◽  
Fuxing Sun ◽  
Rongrong Yuan ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Adsorption Of Co ◽  
Adsorption Of Co2 ◽  
Organic Framework

A stable microporous anionic MOF based on a dendritic aromatic 12-carboxyl ligand was synthesized, which demonstrates high Qst for CO2 and highly selective gas adsorption of CO2 over CH4.

Revealing an unusual temperature-dependent CO2 adsorption trend and selective CO2 uptake over water vapors in a polyamine-appended metal–organic framework

2019 ◽  
Vol 3 (12) ◽  
pp. 2759-2767 ◽  
Author(s):  
Jong Hyeak Choe ◽  
Dong Won Kang ◽  
Minjung Kang ◽  
Hyojin Kim ◽  
Jeoung Ryul Park ◽  
...  
Keyword(s):  
Co2 Adsorption ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Co2 Uptake ◽  
Temperature Dependent ◽  
Water Vapors ◽  
Metal Organic ◽  
Adsorption Of Co ◽  
Unusual Increase ◽  
Organic Framework

Heavily tetraethylenepentamine (tepa)-functionalized Mg2(dobpdc) showed an unusual increase in CO2 uptake on increasing the temperature and selective adsorption of CO2 over water vapors.

An unusual (3,6)-connected microporous metal–organic framework based on tetrahedral Zn4 clusters with selective adsorption of CO2

CrystEngComm ◽  
2011 ◽  
Vol 13 (15) ◽  
pp. 4823 ◽  
Author(s):  
Rong-Rong Zeng ◽  
Quan-Guo Zhai ◽  
Shu-Ni Li ◽  
Yu-Cheng Jiang ◽  
Man-Cheng Hu
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Adsorption Of Co2 ◽  
Organic Framework

A hydrothermally stable Zn(ii)-based metal–organic framework: structural modulation and gas adsorption

2015 ◽  
Vol 44 (35) ◽  
pp. 15697-15702 ◽  
Author(s):  
Xiuling Zhang ◽  
Yong-Zheng Zhang ◽  
Da-Shuai Zhang ◽  
Baoyong Zhu ◽  
Jian-Rong Li
Keyword(s):  
Gas Adsorption ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Structural Modulation ◽  
Adsorption Of Co ◽  
Organic Framework

A hydrothermally stable MOF, [Zn2(tcpt)OH]·solvents (1·solvents), was synthesized, in which an unusual paddlewheel SBU, Zn2(COO)3, was found. Furthermore, 1 can adsorb considerable amounts of H2 and displays high selective adsorption of CO2 over N2.

A Distorted [Mn2(COO)4N2] Cluster Based Metal–Organic Framework with (3,3,6) Topology and Selective Adsorption of CO2

2017 ◽  
Vol 17 (4) ◽  
pp. 2223-2227 ◽  
Author(s):  
Jingjing Jiang ◽  
Qian Wang ◽  
Mingxing Zhang ◽  
Junfeng Bai
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Adsorption Of Co2 ◽  
Organic Framework

A stable luminescent anionic porous metal–organic framework for moderate adsorption of CO2 and selective detection of nitro explosives

2015 ◽  
Vol 3 (14) ◽  
pp. 7224-7228 ◽  
Author(s):  
En-Long Zhou ◽  
Peng Huang ◽  
Chao Qin ◽  
Kui-Zhan Shao ◽  
Zhong-Min Su
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Selective Detection ◽  
Nitro Explosives ◽  
Metal Organic ◽  
Adsorption Of Co ◽  
Adsorption Of Co2 ◽  
Organic Framework

A new stable pillared-layer metal–organic framework was constructed, which showed moderate adsorption of CO2 and selective sensing of TNP.

A new porous 2D copper(II) metal–organic framework for selective adsorption of CO2 over N2

2013 ◽  
Vol 38 ◽  
pp. 104-107 ◽  
Author(s):  
Da-Shu Chen ◽  
Jia-Ming Cheng ◽  
Li-Bo Sun ◽  
Zhi-Qiang Liang ◽  
Kui-Zhan Shao ◽  
...  
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Adsorption Of Co2 ◽  
Organic Framework

Halogen Functionalization of Aluminium Fumarate Metal–Organic Framework via In Situ Hydrochlorination of Acetylenedicarboxylic Acid

2019 ◽  
Vol 72 (10) ◽  
pp. 835 ◽  
Author(s):  
Tobie J. Matemb Ma Ntep ◽  
Wei Wu ◽  
Hergen Breitzke ◽  
Carsten Schlüsener ◽  
Bastian Moll ◽  
...  
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Fold Increase ◽  
Aluminium Chloride ◽  
One Pot ◽  
Metal Organic ◽  
Acetylenedicarboxylic Acid ◽  
Adsorption Of Co2 ◽  
Organic Framework

The successful chloro-functionalization of aluminium fumarate (MIL-53-Fum) was achieved by in situ hydrochlorination of acetylenedicarboxylic acid on reaction with aluminium chloride resulting in the formation of the aluminium chlorofumarate metal–organic framework (MIL-53-Fum-Cl=[Al(OH)(Fum-Cl)]) in a one-pot reaction. The chloro functional groups decorating the pores enhance gas (CO2, CH4, and H2) sorption capacities and affinity compared with the non-functionalized MIL-53-Fum. The functionalization also results in a 2-fold increase in the selective adsorption of CO2 over CH4 compared with MIL-53-Fum.

A novel 3-fold interpenetration metal–organic framework with tunable luminescence and selective adsorption of CO2 properties

2015 ◽  
Vol 39 (12) ◽  
pp. 9075-9078 ◽  
Author(s):  
Rong-Guang Lin ◽  
Gao-Juan Cao ◽  
Jian-Di Lin ◽  
Yu-Lin Wang
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Luminescence Properties ◽  
Adsorption Behaviors ◽  
Metal Organic ◽  
Adsorption Of Co2 ◽  
Organic Framework

A novel acylamide metal–organic framework (MOF) with 3-fold interpenetration has been synthesized, which shows high selective adsorption behaviors of CO2 and tunable luminescence properties dependent on excitation wavelengths.

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