Transition metal complexes of diethyl Cyclopentanone-2,5-diglyoxylate
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Diethyl cyclopentanone-2,5-diglyoxylate (ecgH2; IV) forms complexes of the type M(ecg)Bn with divalent transition metals, where M = Mn, Fe, Co, Ni, Cu, Zn; B = H2O or a heterocyclic base, and n = 1 (when M = Cu) or n = 2 (M = others). All complexes have the high-spin configuration. Infrared spectra show the presence of chelate β-diketone rings and free carbonyl groups. Visible and near-infrared spectra support octahedral stereochemistry for the nickel(II) and cobalt(II) complexes. Molecular weights show the complexes to be dimeric. These results are consistent with an oxygen-bridged structure, M2L2B2n, in which base molecules are added above and below a planar M2L2 unit (VI).
1989 ◽
Vol 213
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pp. 133-144
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1975 ◽
Vol 25
(2)
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pp. 438-441
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1993 ◽
Vol 4
(3)
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pp. 309-319
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