Photo-induced elimination in some aporphinium salts
Ultraviolet irradiation of (+)-glaucine methiodide in methanol gave the elimination product 1-[2'-(N,N-dimethylaminoethyl)]-3,4,6,7- tetramethoxyphenanthrene in good yield. Analogous products were obtained from the ethiodide and benzylbromide salts of this aporphine alkaloid, and from quaternary salts of (+)-boldine and (-)-O,O'-dimethylapomorphine. This photoelimination reaction was also applied to the hydrochloride salts of (+)-glaucine and (+)-boldine.
1979 ◽
Vol 115
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pp. 1421-1423
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1998 ◽
Vol 3
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pp. 61-68
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2013 ◽
Vol 133
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pp. 13-19
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1970 ◽
2019 ◽