Solvation of ions. XXXI. Partial molal volumes of sodium, silver(I) and copper(I) ions in acetonitrile/water mixtures

The partial molal volumes of Na+, Ag+, Cu+, Ph4As+, BPh4-, Cl- and NO3- are reported for transfer from water to various acetonitrile/water (MeCN/H2O) mixtures by using the tatb assumption that ΔVt(Ph4As+) = ΔVt(BPh4-). The results, which show a complex dependence of ionic partial molal volumes on MeCN/H2O solvent composition, are discussed in terms of ion-solvent and solvent-solvent interactions. This study complements earlier work on the energetics of transfer (tatb assumption) of these ions from water to aqueous acetonitrile solutions.

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Solvation of ions. XXV. Partial molal volumes of single ions in protic and dipolar aprotic solvents

Australian Journal of Chemistry ◽

10.1071/ch9750955 ◽

1975 ◽

Vol 28 (5) ◽

pp. 955 ◽

Cited By ~ 74

Author(s):

MRJ Dack ◽

KJ Bird ◽

AJ Parker

Keyword(s):

Propylene Carbonate ◽

Dimethyl Sulphoxide ◽

Aprotic Solvents ◽

Solvent Interactions ◽

Partial Molal Volumes ◽

Steric Crowding ◽

Solvation Of Ions ◽

Molal Volumes ◽

Solvent Molecules ◽

Dipolar Aprotic Solvents

Partial molal volumes at 25� are reported for some 1 : 1 electrolytes, and for triphenylmethane, in dimethyl sulphoxide, N,N- dimethylformamide, acetonitrile, propylene carbonate, formamide and hexamethylphosphoramide. The assumption that ΔV�tr(Ph4As+) = ΔV�tr(BPh4-) was used to obtain ionic partial molal volumes of transfer from water to the non-aqueous solvents. Solvent compressibility appears to determine the partial molal volumes of non-electrolytes and large hydrophobic ions in solution. Values of ΔV�tr for cations and anions are discussed in terms of ion-solvent interactions, solvent-solvent interactions and steric crowding of large solvent molecules around the ions.

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Solute-solvent interactions in water-tert-butyl alcohol mixtures. X. Partial molal volumes of alkali and halide lons

Journal of Solution Chemistry ◽

10.1007/bf00667996 ◽

1980 ◽

Vol 9 (11) ◽

pp. 827-840 ◽

Cited By ~ 9

Author(s):

M. Dollet ◽

J. Juillard ◽

R. Zana

Keyword(s):

Butyl Alcohol ◽

Solvent Interactions ◽

Tert Butyl ◽

Partial Molal Volumes ◽

Tert Butyl Alcohol ◽

Alcohol Mixtures ◽

Molal Volumes

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Ion-solvent interactions. VII. Apparent and partial molal volumes of some symmetrical tetraalkylammonium halides in anhydrous methanol solutions

The Journal of Physical Chemistry ◽

10.1021/j100866a022 ◽

1967 ◽

Vol 71 (7) ◽

pp. 2112-2116 ◽

Cited By ~ 31

Author(s):

Jacob Padova ◽

I. Abrahamer

Keyword(s):

Anhydrous Methanol ◽

Solvent Interactions ◽

Methanol Solutions ◽

Partial Molal Volumes ◽

Molal Volumes ◽

Tetraalkylammonium Halides

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Partial molal volume behavior of tetraalkylammonium chlorides in aqueous acetone and aqueous dimethylsulfoxide

Canadian Journal of Chemistry ◽

10.1139/v70-404 ◽

1970 ◽

Vol 48 (15) ◽

pp. 2416-2422 ◽

Cited By ~ 16

Author(s):

Digby D. Macdonald ◽

J. B. Hyne

Keyword(s):

Molecular Weight ◽

Aqueous Acetone ◽

Solvent Composition ◽

Partial Molal Volume ◽

Volume Data ◽

Molal Volume ◽

Partial Molal Volumes ◽

Molal Volumes ◽

Aqueous Dimethylsulfoxide ◽

Linear Expression

The partial molal volumes of a series of tetraalkylammonium chlorides in aqueous acetone and aqueous dimethylsulfoxide at 25.000 °C are reported as a function of solvent composition. It is shown that for each solvent composition the partial molal volume data are better represented by a quadratic in solute molecular weight than by the linear expression previously employed in similar studies. Extrapolation of molecular partial molal volumes to zero cation molecular weight has permitted evaluation of the partial molal volumes of the ions R4N+ and Cl−. The variation of molecular and ionic partial molal volume as a function of solvent composition is discussed.

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ON ION-SOLVENT INTERACTIONS. PART I. PARTIAL MOLAL VOLUMES OF IONS IN AQUEOUS SOLUTION1,2

The Journal of Physical Chemistry ◽

10.1021/j100823a009 ◽

1961 ◽

Vol 65 (5) ◽

pp. 740-744 ◽

Cited By ~ 96

Author(s):

Pasupati Mukerjee

Keyword(s):

Solvent Interactions ◽

Partial Molal Volumes ◽

Molal Volumes

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A Comparative Study of Bu4NBr, NaBPh4, Ph4PCl, and Ph4AsCl in Water and Methanol at 25 °C: Partial Molal Volumes, Heat Capacities, and Viscosities

Canadian Journal of Chemistry ◽

10.1139/v72-506 ◽

1972 ◽

Vol 50 (19) ◽

pp. 3167-3178 ◽

Cited By ~ 56

Author(s):

C. Jolicoeur ◽

P. R. Philip ◽

G. Perron ◽

P. A. Leduc ◽

J. E. Desnoyers

Keyword(s):

Comparative Study ◽

Transfer Functions ◽

Heat Capacities ◽

Solvent Interactions ◽

Apparent Molal Volumes ◽

Partial Molal Volumes ◽

Molal Volumes

The apparent molal volumes [Formula: see text] and heat capacities [Formula: see text] of Bu4NBr, NaBPh4, Ph4PCl, and Ph4AsCl have been measured in water and methanol at 25 °C in the concentration range 0.01–0.2 M. The viscosity of aqueous NaBPh4 and Ph4AsCl have also been measured at 25 °C and in the same concentration range. Individual ionic values have been estimated for most of these properties. A comparison of these values for the quaternary ions BU4N+, [Formula: see text], Ph4P+, Ph4As+ illustrates sizable differences in the solute–solvent interactions of alkyl and aryl substituted ions. Some specificity is also suggested in the solvation of the tetraphenyl ions, as shown by a comparison of the properties which should reflect directly the size of the ions [Formula: see text]and also in (H2O → CH3OH) transfer functions.

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