Synthesis of Epihalohydrins by Dehydrohalogenation of Glycerol Dihalohydrins - Utilization of a Basic Ion-Exchange Resin
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Dehydrohalogenation of a mixture of glycerol 1,3- and 2,3-dihalohydrins by a strong basic ion-exchange resin (IRA 440 and A 26) at room temperature in an organic medium quantitatively leads to the corresponding epihalohydrin (1a; X = Cl), and (1b; X = Br) in a very short reaction time. Hydrolysis of the epihalohydrin does not occur under these conditions.
1990 ◽
Vol 23
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pp. 354-359
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2011 ◽
Vol 71
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pp. 139-145
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1955 ◽
Vol 77
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pp. 3360-3365
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2012 ◽
Vol 90
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pp. 1189-1196
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2013 ◽
Vol 36
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pp. 1715-1724
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1953 ◽
Vol 75
(9)
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pp. 2039-2041
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2012 ◽
Vol 51
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pp. 11653-11658
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2007 ◽
Vol 126
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pp. 111-118
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2019 ◽
Vol 495
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pp. 012050
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