scholarly journals Electron Transport Coefficients in Carbon Monoxide and Deuterium

1989 ◽  
Vol 42 (6) ◽  
pp. 609 ◽  
Author(s):  
ZLj Petrovic ◽  
RW Crompton
Keyword(s):  
Carbon Monoxide ◽  
Cross Sections ◽  
Vibrational Excitation ◽  
Transport Coefficients ◽  
Transverse Diffusion ◽  
Excitation Cross Sections ◽  
Electron Transport Coefficients ◽  
Gaseous Carbon Monoxide ◽  
Existing Data ◽  
Good Agreement

The drift velocity and the ratio of transverse diffusion coefficient to mobility have been measured for electrons in gaseous carbon monoxide and deuterium at 293 K. The measurements were made under conditions where vibrational excitation is the major energy loss in order to resolve some discrepancies that exist between published vibrational excitation cross sections for these gases. The results are in good agreement with the majority of the existing data where available, but the error bounds are reduced significantly in some cases.

EFFECTS OF ROTATIONAL AND VIBRATIONAL EXCITATION ON THE STEREODYNAMICS OF THE O (D-1) + HCl → OH + Cl REACTION

2009 ◽  
Vol 08 (06) ◽  
pp. 1177-1184 ◽  
Author(s):  
QIANG WEI ◽  
VICTOR WEI-KEH WU ◽  
BO ZHOU
Keyword(s):  
Cross Sections ◽  
Collision Energy ◽  
Energy Surface ◽  
Vibrational Excitation ◽  
Classical Trajectory ◽  
Rotational Excitation ◽  
Title Reaction ◽  
Vibrational Excitations ◽  
Product Vector ◽  
Good Agreement

The stereodynamics of the title reaction on the ground 1 1A′ potential energy surface (PES) has been studied using quasi-classical trajectory (QCT) method. Collision energy of 6.4 kcal/mol is considered, and vector properties including angular momentum alignment distributions and polarization-dependent differential cross-sections (PDDCS) of the product OH are presented. Furthermore, the influence of reagent rotational excitation and vibrational excitation on the product vector properties has also been studied in the present work. The results indicate that the distribution of the P(θr) and P(ϕr) are sensitively affected by the rotational and vibrational excitation. The rotational excitation decreases the degree of alignment and orientation, while vibrational excitation increases the degree of alignment and orientation. The PDDCS (2π/σ)(dσ20/dωt) and (2π/σ)(dσ22+/dωt) are sensitively influenced by rotational and vibrational excitations, while the PDDCS ((2π/σ)(dσ00/dωt)) and (2π/σ)(dσ21-/dωt) are not. The preference of forward scattering has been found from the results of PDDCS ((2π/σ)(dσ00/dωt)), which is in good agreement with the experimental results.

scholarly journals Drift Velocity and Longitudinal Diffusion Coefficient of Electrons in CO2?Ar Mixtures and Electron Collision Cross Sections for CO2 Molecules

1995 ◽  
Vol 48 (3) ◽  
pp. 357 ◽  
Author(s):  
Y Nakamura
Keyword(s):  
Diffusion Coefficient ◽  
Momentum Transfer ◽  
Cross Section ◽  
Drift Velocity ◽  
Cross Sections ◽  
Vibrational Excitation ◽  
Electron Collision ◽  
Longitudinal Diffusion ◽  
Excitation Cross Sections ◽  
Momentum Transfer Cross Section

The drift velocity and longitudinal diffusion coefficient of electrons in 0�2503% and 1� 97% C02-Ar mixtures were measured for 0�03 ~ E/N ~ 20 Td. The measured electron swarm parameters in the mixtures were used to derive a set of consistent vibrational excitation cross sections for the C02 molecule. Analysis of electron swarms in pure C02 using the present vibrational excitation cross sections was also carried out in order to determine a new momentum transfer cross section for the C02 molecule.

Measurement of absolute electron-impact excitation cross sections in Ar and N2 using H and H2 emissions as secondary standards

1988 ◽  
Vol 66 (4) ◽  
pp. 349-357 ◽  
Author(s):  
J. L. Forand ◽  
S. Wang ◽  
J. M. Woolsey ◽  
J. W. McConkey
Keyword(s):  
Electron Impact ◽  
Cross Section ◽  
Cross Sections ◽  
Emission Cross Section ◽  
Impact Excitation ◽  
Electron Impact Excitation ◽  
Dissociative Excitation ◽  
Excitation Cross Sections ◽  
Line Following ◽  
Good Agreement

A detailed description is given of a technique in which emissions from H and H2 are used to calibrate an apparatus used for electron-impact emission cross-section measurements in the wavelength range 90–130 nm. Absolute emission cross sections have been measured at 200 eV electron-impact energy for the 120 nm N I line following dissociative excitation of N2 and for the Ar and Ar+ lines at 104.8, 106.7, 92.0, and 93.8 nm respectively. Good agreement with earlier works is obtained in the case of the N I line when earlier data are renormalized to take into account the recent revision of the cross section for production of Lyman α from H2. Measurements of the 104.8 and 106.7 nm lines suggest a 40% cascade component for the latter line at energies of 200 eV and above.

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