Exploring pedogenesis via nuclide-based soil production rates and OSL-based bioturbation rates

Soil Research ◽  
2005 ◽  
Vol 43 (6) ◽  
pp. 767 ◽  
Author(s):  
Marshall T. Wilkinson ◽  
Geoff S. Humphreys

New dating techniques are available for soil scientists to test fundamental pedogenic ideas. Recent developments in applications of terrestrial in situ cosmogenic nuclides (TCN) from bedrock and saprolite allow the derivation of soil production rates, at scales ranging from local (sub-hillslope) to catchment wide, generally averaged over timescales of 104–105 years. Where soil depths are relatively constant over time, soil production rates equal transport rates and are thus essential to establishing sustainable erosion rates. TCN also allow the form of the soil production function to be compared to theoretical models—a difficult task previously. Furthermore, parameterised soil production functions can now be incorporated into numerical surface process models to test landscape evolution ideas. Bedrock and saprolite conversion to soil is demonstrably dependent on the overlying soil depth, and there is general agreement that weathering declines exponentially beyond maximum soil production, consistent with theory. Whether maximum soil production occurs under a finite or non-existent soil cover at particular sites remains unresolved. We suggest that, in general, soil production from saprolite declines exponentially with increasing depth, while production from bedrock follows a humped function. Estimates of the role of flora, fauna and processes such as freeze–thaw that mix soil mantles to depth, have been limited prior to optically stimulated luminescence (OSL) dating techniques. Recently derived OSL mixing rates extend the magnitude of previous partial, short-term bioturbation rates. In fact, bioturbation appears to be the most active pedogenic process operating in many soils, with freeze–thaw environments a noted exception. Although bioturbation far outweighs soil production, it does not always lead to homogenisation as is often reported. We maintain that the above-ground component of bioturbation, i.e. mounding, may alone, or particularly when combined with particle sorting via rainwash processes, lead to horizonisation and texture contrast soils in those materials that can be sorted such as mixtures of sand and clay. Together, TCN- and OSL-based estimates of hillslope soil transport and bioturbation, suggest significant rates of downslope soil mantle movement coupled with rapid mixing, contrary to in situ soil development models.


2020 ◽  
Vol 24 (18) ◽  
pp. 2181-2191
Author(s):  
Li Wang ◽  
Ziyi Li ◽  
Jiang Liu ◽  
Jianlin Han ◽  
Hiroki Moriwaki ◽  
...  

The development of an efficient and mild synthetic methodology for the construction of bioactive fluorine-containing molecules represents one of the hot research topics in general synthetic organic chemistry. In this review, some recent progresses achieved in the development of detrifluoroacetylatively generated mono-fluorinated enolates via CC bond cleavage and their asymmetric nucleophilic reactions for assembly of chiral quaternary C-F center containing compounds.



Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 536
Author(s):  
Mosab Kaseem ◽  
Karna Ramachandraiah ◽  
Shakhawat Hossain ◽  
Burak Dikici

This review presents an overview of the recent developments in the synthesis of layered double hydroxide (LDH) on the anodized films of Mg alloys prepared by either conventional anodizing or plasma electrolytic oxidation (PEO) and the applications of the formed composite ceramics as smart chloride traps in corrosive environments. In this work, the main fabrication approaches including co-precipitation, in situ hydrothermal, and an anion exchange reaction are outlined. The unique structure of LDH nanocontainers enables them to intercalate several corrosion inhibitors and release them when required under the action of corrosion-relevant triggers. The influences of different variables, such as type of cations, the concentration of salts, pH, and temperature, immersion time during the formation of LDH/anodic film composites, on the electrochemical response are also highlighted. The correlation between the dissolution rate of PEO coating and the growth rate of the LDH film was discussed. The challenges and future development strategies of LDH/anodic films are also highlighted in terms of industrial applications of these materials.



2009 ◽  
Vol 4 (6) ◽  
pp. 441-461 ◽  
Author(s):  
Irene Schimmelpfennig ◽  
Lucilla Benedetti ◽  
Robert Finkel ◽  
Raphaël Pik ◽  
Pierre-Henri Blard ◽  
...  


Water ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 1174 ◽  
Author(s):  
Honglin Zhu ◽  
Tingxi Liu ◽  
Baolin Xue ◽  
Yinglan A. ◽  
Guoqiang Wang

Soil moisture distribution plays a significant role in soil erosion, evapotranspiration, and overland flow. Infiltration is a main component of the hydrological cycle, and simulations of soil moisture can improve infiltration process modeling. Different environmental factors affect soil moisture distribution in different soil layers. Soil moisture distribution is influenced mainly by soil properties (e.g., porosity) in the upper layer (10 cm), but by gravity-related factors (e.g., slope) in the deeper layer (50 cm). Richards’ equation is a widely used infiltration equation in hydrological models, but its homogeneous assumptions simplify the pattern of soil moisture distribution, leading to overestimates. Here, we present a modified Richards’ equation to predict soil moisture distribution in different layers along vertical infiltration. Two formulae considering different controlling factors were used to estimate soil moisture distribution at a given time and depth. Data for factors including slope, soil depth, porosity, and hydraulic conductivity were obtained from the literature and in situ measurements and used as prior information. Simulations were compared between the modified and the original Richards’ equations and with measurements taken at different times and depths. Comparisons with soil moisture data measured in situ indicated that the modified Richards’ equation still had limitations in terms of reproducing soil moisture in different slope positions and rainfall periods. However, compared with the original Richards’ equation, the modified equation estimated soil moisture with spatial diversity in the infiltration process more accurately. The equation may benefit from further solutions that consider various controlling factors in layers. Our results show that the proposed modified Richards’ equation provides a more effective approach to predict soil moisture in the vertical infiltration process.



2017 ◽  
Vol 5 (3) ◽  
pp. 479-492 ◽  
Author(s):  
Jon D. Pelletier

Abstract. The potential soil production rate, i.e., the upper limit at which bedrock can be converted into transportable material, limits how fast erosion can occur in mountain ranges in the absence of widespread landsliding in bedrock or intact regolith. Traditionally, the potential soil production rate has been considered to be solely dependent on climate and rock characteristics. Data from the San Gabriel Mountains of California, however, suggest that topographic steepness may also influence potential soil production rates. In this paper I test the hypothesis that topographically induced stress opening of preexisting fractures in the bedrock or intact regolith beneath hillslopes of the San Gabriel Mountains increases potential soil production rates in steep portions of the range. A mathematical model for this process predicts a relationship between potential soil production rates and average slope consistent with published data. Once the effects of average slope are accounted for, a small subset of the data suggests that cold temperatures may limit soil production rates at the highest elevations of the range due to the influence of temperature on vegetation growth. These results suggest that climate and rock characteristics may be the sole controls on potential soil production rates as traditionally assumed but that the porosity of bedrock or intact regolith may evolve with topographic steepness in a way that enhances the persistence of soil cover in compressive-stress environments. I develop an empirical equation that relates potential soil production rates in the San Gabriel Mountains to the average slope and a climatic index that accounts for temperature limitations on soil production rates at high elevations. Assuming a balance between soil production and erosion rates on the hillslope scale, I illustrate the interrelationships among potential soil production rates, soil thickness, erosion rates, and topographic steepness that result from the feedbacks among geomorphic, geophysical, and pedogenic processes in the San Gabriel Mountains.



2021 ◽  
Author(s):  
Shaojie Sun ◽  
Xinyu Wang ◽  
Junjie Zhou ◽  
Siqi Zhang ◽  
Kongyu Ge ◽  
...  

Abstract The application of ceramic materials is limited due to the complicated preparation process and intrinsic brittleness. In this work, a pressureless manufacturing route that enables the formation of barium aluminosilicate (BAS) glass-ceramic consisting of internal β-Sialon fibers with enhanced thermal conductivity is developed. By adjusting the carbon source content, composites with different Sialon contents can be easily fabricated. The thermal conductivity of the sample with 3.5 wt.% is improved to 5.845 W/m ∙ K with the Sialon content of 26 wt.% in the composite, which is 112.64 % higher than that of the pure BAS matrix. The theoretical models suggest that the enhanced thermal conductivity is mainly ascribed to the thermal conduction network constructed by Sialon fibers. This work provides a method with industrial application prosperity to fabricate the high temperature ceramic matrix composite of different sizes and complex shapes.



2021 ◽  
Author(s):  
Emma Harrison ◽  
Jane Willenbring ◽  
Gilles Brocard
Keyword(s):  


2021 ◽  
Vol 9 (4B) ◽  
Author(s):  
Abiola Ayopo Abiodun ◽  
◽  
Zalihe Nalbantoglu ◽  

Electrokinetic (EK) treatment is an innovative, cost-effective in situ ground modification technology. The EK treatment uses a combination of low-voltage direct-current, electrodes, and ionic solutions across problematic soil to improve the ground conditions. This study aims to model the effect of changing electrode length (le) on the performance of the EK treatment on the engineering properties of fine-grained problematic soils. The consideration of the changing electrode lengths (le), varying soil depths (ds), and lengthwise anode to cathode distances (dA↔E), in the soil block samples, is in the form of the laboratory model test tank. The significant performance of the experimental tests was with changing electrode lengths of 0.25le (7.5 cm), 0.50le (15.0 cm), 0.75le (22.5 cm), and 1.0le (30.0 cm). The study analyzed the test data obtained from the Atterberg limit and one-dimensional swelling tests at different extraction points of the EK treated soils in the test tanks. Furthermore, the study carefully analyzed the effect of changing electrode length (le) on the performance of the EK treatment. The results of the Design of Experiment (DOE) model analysis revealed that the effect of changing electrode length (le) on the plasticity index (PI), and swelling potential (SP) of the EK treated soils, was significant. For a specific soil depth (ds), the electrode lengths (le) of 0.50le and 0.75le were significantly effective in reducing the PI, and the SP of the EK treated soils. Unlike other studies in the literature, the use of DOE analysis in the present study enabled the detection of the significant input factors and their interactive effects on the PI and the SP, thus, enabling the practicing engineers to navigate accurate design models for large in situ applications.



Sign in / Sign up

Export Citation Format

Share Document