scholarly journals Core formation and core composition from coupled geochemical and geophysical constraints

2015 ◽  
Vol 112 (40) ◽  
pp. 12310-12314 ◽  
Author(s):  
James Badro ◽  
John P. Brodholt ◽  
Hélène Piet ◽  
Julien Siebert ◽  
Frederick J. Ryerson
Keyword(s):  
Experimental Petrology ◽  
Magma Ocean ◽  
Core Formation ◽  
Cobalt Chromium ◽  
Primitive Earth ◽  
Left Behind ◽  
The Core ◽  
Reducing Conditions ◽  
Core Composition ◽  
Seismic Models

The formation of Earth’s core left behind geophysical and geochemical signatures in both the core and mantle that remain to this day. Seismology requires that the core be lighter than pure iron and therefore must contain light elements, and the geochemistry of mantle-derived rocks reveals extensive siderophile element depletion and fractionation. Both features are inherited from metal−silicate differentiation in primitive Earth and depend upon the nature of physiochemical conditions that prevailed during core formation. To date, core formation models have only attempted to address the evolution of core and mantle compositional signatures separately, rather than seeking a joint solution. Here we combine experimental petrology, geochemistry, mineral physics and seismology to constrain a range of core formation conditions that satisfy both constraints. We find that core formation occurred in a hot (liquidus) yet moderately deep magma ocean not exceeding 1,800 km depth, under redox conditions more oxidized than present-day Earth. This new scenario, at odds with the current belief that core formation occurred under reducing conditions, proposes that Earth’s magma ocean started oxidized and has become reduced through time, by oxygen incorporation into the core. This core formation model produces a core that contains 2.7–5% oxygen along with 2–3.6% silicon, with densities and velocities in accord with radial seismic models, and leaves behind a silicate mantle that matches the observed mantle abundances of nickel, cobalt, chromium, and vanadium.

scholarly journals The niobium and tantalum concentration in the mantle constrains the composition of Earth’s primordial magma ocean

2020 ◽  
Vol 117 (45) ◽  
pp. 27893-27898
Author(s):  
Dongyang Huang ◽  
James Badro ◽  
Julien Siebert
Keyword(s):  
Diamond Anvil Cell ◽  
Magma Ocean ◽  
Core Formation ◽  
The Core ◽  
Bulk Silicate Earth ◽  
Reducing Conditions ◽  
Metal Silicate ◽  
Diamond Anvil ◽  
Laser Heated ◽  
Tantalum Concentration

The bulk silicate Earth (BSE), and all its sampleable reservoirs, have a subchondritic niobium-to-tantalum ratio (Nb/Ta). Because both elements are refractory, and Nb/Ta is fairly constant across chondrite groups, this can only be explained by a preferential sequestration of Nb relative to Ta in a hidden (unsampled) reservoir. Experiments have shown that Nb becomes more siderophile than Ta under very reducing conditions, leading the way for the accepted hypothesis that Earth’s core could have stripped sufficient amounts of Nb during its formation to account for the subchondritic signature of the BSE. Consequently, this suggestion has been used as an argument that Earth accreted and differentiated, for most of its history, under very reducing conditions. Here, we present a series of metal–silicate partitioning experiments of Nb and Ta in a laser-heated diamond anvil cell, at pressure and temperature conditions directly comparable to those of core formation; we find that Nb is more siderophile than Ta under any conditions relevant to a deep magma ocean, confirming that BSE’s missing Nb is in the core. However, multistage core formation modeling only allows for moderately reducing or oxidizing accretionary conditions, ruling out the need for very reducing conditions, which lead to an overdepletion of Nb from the mantle (and a low Nb/Ta ratio) that is incompatible with geochemical observations. Earth’s primordial magma ocean cannot have contained less than 2% or more than 18% FeO since the onset of core formation.

Experiments on metal–silicate plumes and core formation

2008 ◽  
Vol 366 (1883) ◽  
pp. 4253-4271 ◽  
Author(s):  
Peter Olson ◽  
Dayanthie Weeraratne
Keyword(s):  
Lower Layer ◽  
High Viscosity ◽  
Primitive Mantle ◽  
Liquid Gallium ◽  
Magma Ocean ◽  
Core Formation ◽  
Thermal Plumes ◽  
The Core ◽  
Metal Silicate ◽  
Sucrose Solutions

Short-lived isotope systematics, mantle siderophile abundances and the power requirements of the geodynamo favour an early and high-temperature core-formation process, in which metals concentrate and partially equilibrate with silicates in a deep magma ocean before descending to the core. We report results of laboratory experiments on liquid metal dynamics in a two-layer stratified viscous fluid, using sucrose solutions to represent the magma ocean and the crystalline, more primitive mantle and liquid gallium to represent the core-forming metals. Single gallium drop experiments and experiments on Rayleigh–Taylor instabilities with gallium layers and gallium mixtures produce metal diapirs that entrain the less viscous upper layer fluid and produce trailing plume conduits in the high-viscosity lower layer. Calculations indicate that viscous dissipation in metal–silicate plumes in the early Earth would result in a large initial core superheat. Our experiments suggest that metal–silicate mantle plumes facilitate high-pressure metal–silicate interaction and may later evolve into buoyant thermal plumes, connecting core formation to ancient hotspot activity on the Earth and possibly on other terrestrial planets.

Accretion and core formation: constraints from metal–silicate partitioning

2008 ◽  
Vol 366 (1883) ◽  
pp. 4339-4355 ◽  
Author(s):  
Bernard J Wood
Keyword(s):  
Oxidation State ◽  
Maximum Pressure ◽  
Magma Ocean ◽  
Core Formation ◽  
The Core ◽  
Refractory Elements ◽  
The Earth ◽  
Metal Silicate ◽  
Restricted Volume ◽  
Si Content

Experimental metal–silicate partitioning data for Ni, Co, V, Cr, Nb, Mn, Si and W were used to investigate the geochemical consequences of a range of models for accretion and core formation on Earth. The starting assumptions were chondritic ratios of refractory elements in the Earth and the segregation of metal at the bottom of a magma ocean, which deepened as the planet grew and which had, at its base, a temperature close to the liquidus of the silicate. The models examined were as follows. (i) Continuous segregation from a mantle which is chemically homogeneous and which has a fixed oxidation state, corresponding to 6.26 per cent oxidized Fe. Although Ni, Co and W partitioning is consistent with chondritic ratios, the current V content of the silicate Earth cannot be reconciled with core segregation under these conditions of fixed oxidation state. (ii) Continuous segregation from a mantle which is chemically homogeneous but in which the Earth became more oxidized as it grew. In this case, the Ni, Co, W, V, Cr and Nb contents of core and mantle are easily matched to those calculated from the chondritic ratios of refractory elements. The magma ocean is calculated to maintain a thickness approximately 35 per cent of the depth to the core–mantle boundary in the accreting Earth, yielding a maximum pressure of 44 GPa. This model yields a Si content of the core of 5.7 per cent, in good agreement with cosmochemical estimates and with recent isotopic data. (iii) Continuous segregation from a mantle which is not homogeneous and in which the core equilibrates with a restricted volume of mantle at the base of the magma ocean. This is found to increase depth of the magma ocean by approximately 50 per cent. All of the other elements (except Mn) have partitioning consistent with chondritic abundances in the Earth, provided the Earth became, as before, progressively oxidized during accretion. (iv) Continuous segregation of metal from a crystal-melt mush. In this case, pressures decrease to a maximum of 31 GPa and it is extremely difficult to match the calculated mantle contents of the highly incompatible elements Nb and W to those observed. Progressive oxidation is required to fit the observed mantle contents of vanadium. All of the scenarios discussed above point to progressive oxidation having occurred as the Earth grew. The Earth appears to be depleted in Mn relative to the chondritic reference.

Leaving Agent-Relative Value Behind

Utilitas ◽  
2020 ◽  
pp. 1-15
Author(s):  
Christa M. Johnson
Keyword(s):  
Left Behind ◽  
The Core ◽  
Relative Value ◽  
Long Time ◽  
Commonsense Morality

Abstract Commonsense morality seems to feature both agent-neutral and agent-relative elements. For a long time, the core debate between consequentialists and deontologists was which of these features should take centerstage. With the introduction of the consequentializing project and agent-relative value, however, agent-neutrality has been left behind. While I likewise favor an agent-relative view, agent-neutral views capture important features of commonsense morality. This article investigates whether an agent-relative view can maintain what is attractive about typical agent-neutral views. In particular, I argue that the agent-relative reasons-wielding deontologist is ultimately able to capture those features ordinarily associated with agent-neutral views, while the agent-relative value wielding consequentialist is left with a dilemma. The consequentializer either succumbs to the concerns of her agent-neutral opponents or else abandons the distinctive and attractive features of her view. Either way, I conclude that agent-relative value is best left behind.

scholarly journals White Dwarf Seismology at the Université de Montréal

1993 ◽  
Vol 139 ◽  
pp. 120-120
Author(s):  
G. Fontaine ◽  
P. Brassard ◽  
P. Bergeron ◽  
F. Wesemael
Keyword(s):  
Specific Heat ◽  
Cooling Rate ◽  
Internal Structure ◽  
White Dwarf ◽  
White Dwarfs ◽  
Period Change ◽  
Core Material ◽  
The Core ◽  
Core Composition ◽  
Chemical Stratification

Over the last several years, we have developed a comprehensive program aimed at better understanding the properties of pulsating DA white dwarfs (or ZZ Ceti stars). These stars are nonradial pulsators of the g-type, and their study can lead to inferences about their internal structure. For instance, the period spectrum of a white dwarf is most sensitive to its vertical chemical stratification, and one of the major goals of white dwarf seismology is to determine the thickness of the hydrogen layer that sits on top of a star. This can be done, in principle, by comparing in detail theoretical period spectra with the periods of the observed excited modes. Likewise, because the cooling rate of a white dwarf is very sensitive to the specific heat of its core material (and hence to its composition), it is possible to infer the core composition through measurements and interpretations of rates of period change in a pulsator.

scholarly journals Hydrogen in an early magma ocean: Implications for Earth’s core composition

2021 ◽  
Author(s):  
Ali Bouhifd ◽  
Rémi Delon ◽  
Nathalie Bolfan-Casanova ◽  
Geeth Manthilake ◽  
Federica Schiavi ◽  
...  
Keyword(s):  
Magma Ocean ◽  
Earth’S Core ◽  
Earth's Core ◽  
Core Composition

scholarly journals The internal structure of ZZ Cet stars using quantitative asteroseismology: The case of R548

2013 ◽  
Vol 9 (S301) ◽  
pp. 285-288
Author(s):  
N. Giammichele ◽  
G. Fontaine ◽  
P. Brassard ◽  
S. Charpinet
Keyword(s):  
Internal Structure ◽  
White Dwarf ◽  
White Dwarfs ◽  
Optimization Technique ◽  
Seismic Model ◽  
The Core ◽  
Spectroscopic Analyses ◽  
Core Composition ◽  
Oscillation Modes ◽  
Chemical Stratification

AbstractWe explore quantitatively the low but sufficient sensitivity of oscillation modes to probe both the core composition and the details of the chemical stratification of pulsating white dwarfs. Until recently, applications of asteroseismic methods to pulsating white dwarfs have been far and few, and have generally suffered from an insufficient exploration of parameter space. To remedy this situation, we apply to white dwarfs the same double-optimization technique that has been used quite successfully in the context of pulsating hot B subdwarfs. Based on the frequency spectrum of the pulsating white dwarf R548, we are able to unravel in a robust way the unique onion-like stratification and the chemical composition of the star. Independent confirmations from both spectroscopic analyses and detailed evolutionary calculations including diffusion provide crucial consistency checks and add to the credibility of the inferred seismic model. More importantly, these results boost our confidence in the reliability of the forward method for sounding white dwarf internal structure with asteroseismology.

Smart Blockchain

2020 ◽  
pp. 43-62
Author(s):  
Gutha Jaya Krishna ◽  
Vadlamani Ravi ◽  
Bheemidi Vikram Reddy ◽  
Mohammad Zaheeruddin
Keyword(s):  
Visual Analytics ◽  
New Technology ◽  
Big Data Analytics ◽  
Left Behind ◽  
The Core ◽  
Diverse Field ◽  
Comprehensive Survey ◽  
Overall Performance ◽  
Core Idea ◽  
Analytical Approaches

A blockchain is a digitized, decentralized, open system of records. Of late, there is a phenomenal spurt in the research and application activities of the catch-all phrase analytics, which subsumes machine learning, text mining, classical optimization, artificial intelligence, evolutionary computing, visual analytics, big data analytics, etc. in many a diverse field. Consequently, even new technology like blockchain is not left behind. This chapter presents a comprehensive survey of 33 papers that appeared between 2016 and 2018 under the theme, ‘Analytics and Blockchain', which focuses on how analytical approaches and blockchain implementation are symbiotically related to improve their overall performance in solving various real-world problems. The core idea behind the survey is to facilitate the reader to appreciate the utility of analytical methods to the design, implementation, and application of blockchain and suggesting future directions for further research.

Constraints on core composition from shock-waves data

1982 ◽  
Vol 306 (1492) ◽  
pp. 37-47 ◽  
Keyword(s):  
Equations Of State ◽  
Liquid Core ◽  
Light Element ◽  
Outer Core ◽  
Atomic Ratio ◽  
Core Material ◽  
Solar Photosphere ◽  
The Core ◽  
The Earth ◽  
Core Composition

Seismic data demonstrate that the density of the liquid core is some 8-10 % less than pure iron. Equations of state of Fe-Si, C, FeS 2 , FeS, KFeS 2 and FeO, over the pressure interval 133-364 GPa and a range of possible core temperatures (3500- 5000 K), can be used to place constraints on the cosmochemically plausible light element constituents of the core (Si, C, S, K and O ). The seismically derived density profile allows from 14 to 20 % Si (by mass) in the outer core. The inclusion of Si, or possibly G (up to 11 %), in the core is possible if the Earth accreted inhomogeneously within a region of the solar nebulae in which a C :0 (atomic) ratio of about 1 existed, compared with a G : O ratio of 0.6 for the present solar photosphere. In contrast, homogeneous accretion permits Si, but not C, to enter the core by means of reduction of silicates to metallic Fe-Si core material during the late stages of the accumulation of the Earth. The data from the equation of state for the iron sulphides allow up to 9-13 % S in the core. This composition would provide the entire Earth with a S:Si ratio in the range 0.14-0.3, comparable with meteoritic and cosmic abundances. Shock-wave data for KFeS 2 give little evidence for an electronic phase change from 4s to 3d orbitals, which has been suggested to occur in K, and allow the Earth to store a cosmic abundance of K in the metallic core.

Solubility of carbon and nitrogen in a sulfur-bearing iron melt: Constraints for siderophile behavior at upper mantle conditions

2019 ◽  
Vol 104 (12) ◽  
pp. 1857-1865 ◽  
Author(s):  
Alexander G. Sokol ◽  
Alexander F. Khokhryakov ◽  
Yuri M. Borzdov ◽  
Igor N. Kupriyanov ◽  
Yuri N. Palyanov
Keyword(s):  
Liquid Iron ◽  
Upper Mantle ◽  
Carbon Budget ◽  
Iron Alloy ◽  
Stability Field ◽  
Magma Ocean ◽  
Carbon Solubility ◽  
Carbon And Nitrogen ◽  
Liquid Iron Alloy ◽  
The Core

Abstract Carbon solubility in a liquid iron alloy containing nitrogen and sulfur has been studied experimentally in a carbon-saturated Fe-C-N-S-B system at pressures of 5.5 and 7.8 GPa, temperatures of 1450 to 1800 °C, and oxygen fugacities from the IW buffer to log fO2 ΔIW-6 (ΔIW is the logarithmic difference between experimental fO2 and that imposed by the coexistence of iron and wüstite). Carbon saturation of Fe-rich melts at 5.5 and 7.8 GPa maintains crystallization of flaky graphite and diamond. Diamond containing 2100–2600 ppm N and 130–150 ppm B crystallizes in equilibrium with BN within the diamond stability field at 7.8 GPa and 1600 to 1800 °C, while graphite forms at other conditions. The solubility of carbon in the C-saturated metal melt free from nitrogen and sulfur is 6.2 wt% C at 7.8 GPa and 1600 °C and decreases markedly with increasing nitrogen. A 1450–1600 °C graphite-saturated iron melt with 6.2–8.8 wt% N can dissolve: 3.6–3.9 and 1.4–2.5 wt% C at 5.5 and 7.8 GPa, respectively. However, the melt equilibrated with boron nitride and containing 1–1.7 wt% sulfur and 500–780 ppm boron dissolves twice less nitrogen while the solubility of carbon remains relatively high (3.8–5.2 wt%). According to our estimates, nitrogen partitions between diamond and the iron melt rich in volatiles at DNDm/Met=0.013−0.024. The pressure increase in the Fe-C-N system affects iron affinity of N and C: it increases in nitrogen but decreases in carbon. The reduction of C solubility in a Fe-rich melt containing nitrogen and sulfur may have had important consequences in the case of imperfect equilibration between the core and the mantle during their separation in the early Earth history. The reduction of C solubility allowed C supersaturation of the liquid iron alloy and crystallization of graphite and diamond. The carbon phases could float in the segregated core liquid and contribute to the carbon budget of the overlying silicate magma ocean. Therefore, the process led to the formation of graphite and diamond, which were the oldest carbon phases in silicate mantle.

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