Comparative Study on Reactive Extraction of Nicotinic Acid with Amberlite LA‐2 and D2EHPA

2007 ◽  
Vol 42 (2) ◽  
pp. 389-401 ◽  
Author(s):  
Dan Caşcaval ◽  
Alexandra‐Cristina Blaga ◽  
Maria Cămăruţ ◽  
Anca‐Irina Galaction
2013 ◽  
Vol 120 ◽  
pp. 296-303 ◽  
Author(s):  
Mangesh D. Waghmare ◽  
Kailas L. Wasewar ◽  
Shriram S. Sonawane ◽  
Diwakar Z. Shende

2014 ◽  
Vol 13 (6) ◽  
pp. 1473-1482 ◽  
Author(s):  
Dan Cascaval ◽  
Madalina Postaru ◽  
Lenuta Kloetzer ◽  
Anca-Irina Galaction ◽  
Alexandra Cristina Blaga

2013 ◽  
Vol 52 (38) ◽  
pp. 13785-13794 ◽  
Author(s):  
Lenuţa Kloetzer ◽  
Mădălina Poştaru ◽  
Anca-Irina Galaction ◽  
Alexandra Cristina Blaga ◽  
Dan Caşcaval

2008 ◽  
Vol 14 (3) ◽  
pp. 159-165 ◽  
Author(s):  
Anca-Irina Galaction ◽  
Maria Camarut ◽  
Dan Cascaval

The comparative study on the reactive extraction of p-aminobenzoic acid with Amberlite LA-2 and D2EHPA in two solvents with different polarity (n-heptane and dichloromethane) indicated that the extractant type and solvent polarity control the extraction mechanism. Thus, the reactive extraction with Amberlite LA-2 occurs by means of the interfacial formation of an aminic adduct with three extractant molecules in low-polar solvent, or of an salt with one extractant molecule in higher polar solvent. Similarly, the extraction with D2EHPA is based on the formation of an acidic adduct with two extractant molecules in n-heptane, or of a salt with one extractant molecule in dichloromethane. The most efficient extraction has been reached for the combination Amberlite LA-2-dichloromethane.


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