Acid-base properties and catalytic activity of metal-organic frameworks: A view from spectroscopic and semiempirical methods

2016 ◽  
Vol 58 (2) ◽  
pp. 209-307 ◽  
Author(s):  
Valentina N. Panchenko ◽  
Maria N. Timofeeva ◽  
Sung Hwa Jhung
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Frameworks ◽  
Semiempirical Methods ◽  
Acid Base ◽  
Metal Organic ◽  
Base Properties

From Ru nanoparticle-encapsulated metal–organic frameworks to highly catalytically active Cu/Ru nanoparticle-embedded porous carbon

2017 ◽  
Vol 5 (10) ◽  
pp. 4835-4841 ◽  
Author(s):  
Pradip Pachfule ◽  
Xinchun Yang ◽  
Qi-Long Zhu ◽  
Nobuko Tsumori ◽  
Takeyuki Uchida ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Temperature ◽  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Carbon Composites ◽  
High Catalytic Activity ◽  
Catalytically Active ◽  
Metal Organic

High-temperature pyrolysis of Ru nanoparticle-encapsulated MOF (Ru@HKUST-1) afforded ultrafine Cu/Ru nanoparticle-embedded porous carbon composites (Cu/Ru@C), which show high catalytic activity for ammonia borane hydrolysis.

Controllable synthesis of urchin-like hierarchical superstructure MOFs with high catalytic activity and stability

2021 ◽  
Author(s):  
Zhanke Wang ◽  
Lei Ge ◽  
Guangxu Zhang ◽  
Rongrong Gao ◽  
Hao Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Activity ◽  
Metal Organic Frameworks ◽  
High Catalytic Activity ◽  
Controllable Synthesis ◽  
Metal Organic ◽  
Self Assembled

A novel dissolution-crystallization strategy was developed to synthesize urchin-like superstructure metal-organic frameworks (MOFs) with self-assembled 1D nanorods. The superstructure MOFs not only inherit the high activity of nano-sized MOFs but...

Enzyme encapsulation in metal–organic frameworks for applications in catalysis

CrystEngComm ◽  
2017 ◽  
Vol 19 (29) ◽  
pp. 4082-4091 ◽  
Author(s):  
Marek B. Majewski ◽  
Ashlee J. Howarth ◽  
Peng Li ◽  
Michael R. Wasielewski ◽  
Joseph T. Hupp ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Frameworks ◽  
Enzyme Encapsulation ◽  
Metal Organic

Various methods for encapsulating enzymes in metal–organic frameworks are discussed and the catalytic activity of biocomposites prepared using these methods is highlighted.

scholarly journals Hf-based metal–organic frameworks as acid–base catalysts for the transformation of biomass-derived furanic compounds into chemicals

2018 ◽  
Vol 20 (13) ◽  
pp. 3081-3091 ◽  
Author(s):  
Sergio Rojas-Buzo ◽  
Pilar García-García ◽  
Avelino Corma
Keyword(s):  
Aldol Condensation ◽  
Condensation Reaction ◽  
Metal Organic Frameworks ◽  
Acid Base ◽  
Base Catalysts ◽  
Metal Organic ◽  
Furanic Compounds

Hafnium-based metal–organic frameworks are promising catalysts for upgrading biomass derivatives via an aldol condensation reaction.

Metal-Organic Frameworks Conjugated Lipase with Enhanced Bio-catalytic Activity and Stability

2020 ◽  
Vol 192 (1) ◽  
pp. 132-145
Author(s):  
Bin Zou ◽  
Liming Zhang ◽  
Jiaojiao Xia ◽  
Pengyun Wang ◽  
Yan Yan ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Frameworks ◽  
Metal Organic

Colloidal-sized zirconium porphyrin metal–organic frameworks with improved peroxidase-mimicking catalytic activity, stability and dispersity

The Analyst ◽  
2020 ◽  
Vol 145 (8) ◽  
pp. 3002-3008 ◽  
Author(s):  
Junning Wang ◽  
Tianxiang Wei ◽  
Yichen Liu ◽  
Mengyuan Bao ◽  
Rui Feng ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Organic Framework

A new and facile method was developed to synthesize a sub-100 nm zirconium porphyrin metal–organic framework with improved peroxidase-mimicking catalytic activity, stability and dispersity.

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