From Ru nanoparticle-encapsulated metal–organic frameworks to highly catalytically active Cu/Ru nanoparticle-embedded porous carbon

2017 ◽  
Vol 5 (10) ◽  
pp. 4835-4841 ◽  
Author(s):  
Pradip Pachfule ◽  
Xinchun Yang ◽  
Qi-Long Zhu ◽  
Nobuko Tsumori ◽  
Takeyuki Uchida ◽  
...  

High-temperature pyrolysis of Ru nanoparticle-encapsulated MOF (Ru@HKUST-1) afforded ultrafine Cu/Ru nanoparticle-embedded porous carbon composites (Cu/Ru@C), which show high catalytic activity for ammonia borane hydrolysis.

RSC Advances ◽  
2015 ◽  
Vol 5 (11) ◽  
pp. 8228-8235 ◽  
Author(s):  
Cong Zhang ◽  
Fanggui Ye ◽  
Shufen Shen ◽  
Yuhao Xiong ◽  
Linjing Su ◽  
...  

A magnetic nanostructured porous carbon material (γ-Fe2O3/C) was easily synthesized using a microwave-enhanced high-temperature ionothermal method with an iron terephthalate metal–organic framework-MIL-53(Fe), as a template.


2021 ◽  
Author(s):  
Zhanke Wang ◽  
Lei Ge ◽  
Guangxu Zhang ◽  
Rongrong Gao ◽  
Hao Wang ◽  
...  

A novel dissolution-crystallization strategy was developed to synthesize urchin-like superstructure metal-organic frameworks (MOFs) with self-assembled 1D nanorods. The superstructure MOFs not only inherit the high activity of nano-sized MOFs but...


2020 ◽  
Vol 7 (10) ◽  
pp. 2043-2049 ◽  
Author(s):  
Yao Yuan ◽  
Xiaoyu Chen ◽  
Xing Zhang ◽  
Zumin Wang ◽  
Ranbo Yu

A CuCo(O)-embedded nitrogen-enriched porous carbon framework catalyst derived from doped metal–organic frameworks for efficient hydrolysis of ammonia borane.


2014 ◽  
Vol 2 (30) ◽  
pp. 11606-11613 ◽  
Author(s):  
Wei Xia ◽  
Jinghan Zhu ◽  
Wenhan Guo ◽  
Li An ◽  
Dingguo Xia ◽  
...  

Well-defined porous carbon polyhedrons are synthesized directly from MOF nanocrystals and show high oxygen reduction reaction (ORR) catalytic activity in acid media.


2015 ◽  
Vol 5 (1) ◽  
pp. 525-530 ◽  
Author(s):  
Jun Li ◽  
Qi-Long Zhu ◽  
Qiang Xu

Non-noble bimetallic CuCo alloy nanoparticles were successfully encapsulated in the pores of MIL-101 without aggregation on the external surfaces of the host framework, which exhibit excellent catalytic activity for hydrolytic dehydrogenation of ammonia borane.


2017 ◽  
Vol 53 (6) ◽  
pp. 1184-1187 ◽  
Author(s):  
Liyu Chen ◽  
Weihao Huang ◽  
Xiujun Wang ◽  
Zhijie Chen ◽  
Xianfeng Yang ◽  
...  

A series of Pd based bimetallic NPs with unique “crown-jewel” structure and tunable composition have been successfully fabricated inside the MOF pores, exhibiting superior catalytic activity and stability.


2018 ◽  
Vol 6 (15) ◽  
pp. 6130-6154 ◽  
Author(s):  
Haolin Zhu ◽  
Dingxin Liu ◽  
Dianting Zou ◽  
Jianyong Zhang

Since the discovery of metal–organic frameworks (MOFs), covalent–organic frameworks (COFs) and zeolite–imidazole frameworks (ZIFs), many of their outstanding properties have been explored such as their large specific surface area, significant gas adsorption, and high catalytic activity.


RSC Advances ◽  
2016 ◽  
Vol 6 (41) ◽  
pp. 35135-35143 ◽  
Author(s):  
Radoelizo S. Andriamitantsoa ◽  
Jingjing Wang ◽  
Wenjun Dong ◽  
Hongyi Gao ◽  
Ge Wang

The high dispersed –SO3H groups in the framework of MIL-101-Cr–NH–RSO3H ensure high catalytic activity for the condensation of 1,2-diamines with benzil. The catalyst exhibits good stability, general applicability and excellent recycling performance.


2020 ◽  
Vol 49 (20) ◽  
pp. 6548-6552
Author(s):  
Yilin Jiang ◽  
Xu Zhang ◽  
Honghan Fei

We have summarized the recent in situ generation approaches to form metal-free NHC-functionalized MOFs, which are a unique class of CO2-conversion catalysts with high catalytic activity, selectivity and stability.


RSC Advances ◽  
2017 ◽  
Vol 7 (61) ◽  
pp. 38691-38698 ◽  
Author(s):  
Bin Li ◽  
Wubin Wu ◽  
Tianyong Zhang ◽  
Shuang Jiang ◽  
Xingwei Chen ◽  
...  

Ferrocene@UiO-66 exhibited high catalytic activity for phenol hydroxylation with H2O2 at room temperature in water.


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