Influences of alkanes on the phase behaviors of system of cationic–anionic surfactants

Author(s):  
Hongni Teng ◽  
Na Wang ◽  
Yao Zhang ◽  
Jingjing Wang ◽  
Yong Chen
Author(s):  
E. Naranjo

Equilibrium vesicles, those which are the stable form of aggregation and form spontaneously on mixing surfactant with water, have never been demonstrated in single component bilayers and only rarely in lipid or surfactant mixtures. Designing a simple and general method for producing spontaneous and stable vesicles depends on a better understanding of the thermodynamics of aggregation, the interplay of intermolecular forces in surfactants, and an efficient way of doing structural characterization in dynamic systems.


2007 ◽  
Vol 61 (11-12) ◽  
pp. 2281-2283 ◽  
Author(s):  
Shengyu Jing ◽  
Shuangxi Xing ◽  
Yan Wu ◽  
Yanfei Wang ◽  
Bing Zhao ◽  
...  
Keyword(s):  

2013 ◽  
Vol 17 (4) ◽  
pp. 637-645 ◽  
Author(s):  
Kotte Kamalakar ◽  
Tenneti Satyavani ◽  
Yarra Mohini ◽  
Rachapudi B. N. Prasad ◽  
Mallampalli S. L. Karuna
Keyword(s):  

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3627
Author(s):  
Nikola Sakač ◽  
Dubravka Madunić-Čačić ◽  
Dean Marković ◽  
Lucija Hok ◽  
Robert Vianello ◽  
...  

A 1,3-dihexadecyl-1H-benzo[d]imidazol-3-ium-tetraphenylborate (DHBI-TPB) ion-pair implemented in DHBI-TPB surfactant sensor was used for the potentiometric quantification of anionic surfactants in detergents and commercial household care products. The DHBI-TPB ion-pair was characterized by FTIR spectroscopy and computational analysis which revealed a crucial contribution of the C–H∙∙∙π contacts for the optimal complex formation. The DHBI-TPB sensor potentiometric response showed excellent analytical properties and Nernstian slope for SDS (60.1 mV/decade) with LOD 3.2 × 10−7 M; and DBS (58.4 mV/decade) with LOD 6.1 × 10−7 M was obtained. The sensor possesses exceptional resistance to different organic and inorganic interferences in broad pH (2–10) range. DMIC used as a titrant demonstrated superior analytical performances for potentiometric titrations of SDS, compared to other tested cationic surfactants (DMIC > CTAB > CPC > Hyamine 1622). The combination of DHBI-TPB sensor and DMIC was successfully employed to perform titrations of the highly soluble alkane sulfonate homologues. Nonionic surfactants (increased concentration and number of EO groups) had a negative impact on anionic surfactant titration curves and a signal change. The DHBI-TPB sensor was effectively employed for the determination of technical grade anionic surfactants presenting the recoveries from 99.5 to 101.3%. The sensor was applied on twelve powered samples as well as liquid-gel and handwashing home care detergents containing anionic surfactants. The obtained results showed good agreement compared to the outcomes measured by ISE surfactant sensor and a two-phase titration method. The developed DHBI-TPB surfactant sensor could be used for quality control in industry and has great potential in environmental monitoring.


2019 ◽  
Vol 254 ◽  
pp. 113005 ◽  
Author(s):  
Changjing Li ◽  
Yuan Gao ◽  
Aimin Li ◽  
Lei Zhang ◽  
Guozhao Ji ◽  
...  

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