Kinetics of phase separation by spinodal decomposition in a liquid-crystalline polymer solution

1988 ◽  
Vol 3 (5) ◽  
pp. 631-644 ◽  
Author(s):  
Thein Kyu ◽  
Partha Mukherjee
1995 ◽  
Vol 60 (11) ◽  
pp. 1869-1874 ◽  
Author(s):  
Anatoly E. Nesterov ◽  
Yuri S. Lipatov ◽  
Vitaly V. Horichko

The phase separation in the blends of poly(methyl methacrylate) and liquid-crystalline polymer (copolymer of ethylene terephthalate and p-hydroxybenzoic acid) has been studied by the light scattering method and the cloud point curves have been obtained. Simultaneously some morphological features of the blends have been observed. It was found that the initial blends are in the state of forced compatibility and that thermally induced phase separation occurs by the mechanism of spinodal decomposition but presumably in the non-linear regime.


2008 ◽  
Vol 130 (8) ◽  
Author(s):  
Takatsune Narumi ◽  
Jun Fukada ◽  
Satoru Kiryu ◽  
Shinji Toga ◽  
Tomiichi Hasegawa

An experimental study has been conducted on unstable structures induced in two-dimensional slit flows of liquid crystalline polymer solution. 50wt% aqueous solution of hydroxyl-propylcellulose (HPC) was utilized as a test fluid and its flow behavior in L-shaped slit channels with a cross section of 1mm height and 16mm width was measured optically. The inner corner of the L-shaped channel was rounded off in order to clarify the influence of the radius of curvature on the unstable behavior. A conversing curved channel was also tested. The flow patterns of the HPC solution in the channels were visualized with two crossed polarizers and we observed that typical wavy textures generated in the upstream of the corner almost disappeared after the corner flow. However, an unstable texture was developed again only from the inner corner in downstream flow. The fluctuation of the orientation angle and dichroism were also measured with a laser opto-rheometric system and it was found that the unstable behaviors of the HPC solution have periodic oscillatory characteristics at a typical frequency. In the inner side flow after the corner, the periodic motion became larger toward the downstream and then higher harmonic oscillations were superimposed. Larger rounding off of the inner corner suppressed the redevelopment of unstable behavior, and it is considered that the rapid regrowth of unstable behavior was caused by rapid deceleration at the corner flow. Moreover, the unstable structure was stabilized with an accelerated (elongated) region in the corner flow and the converging channel was helpful to obtain a stable structure in the downstream region.


1999 ◽  
Vol 38 (5-6) ◽  
pp. 549-562 ◽  
Author(s):  
Antje Gottwald ◽  
Dieter Jehnichen ◽  
Doris Pospiech ◽  
Peter Friedel ◽  
Andreas Janke

2002 ◽  
Vol 2002.77 (0) ◽  
pp. _13-49_-_13-50_
Author(s):  
Masatada SHINDOU ◽  
Noriyasu MORI ◽  
Tsutomu TAKAHASHI ◽  
Kiyoji NAKAMURA

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