Hyperfine structure, pressure shift and pressure broadening in the 648 nm transition of atomic bismuth by Faraday spectroscopy

1994 ◽  
Vol 27 (22) ◽  
pp. 5497-5506 ◽  
Author(s):  
D M Lucas ◽  
R B Warrington ◽  
C D Thompson ◽  
D N Stacey
2007 ◽  
Vol 85 (2) ◽  
pp. 199-218 ◽  
Author(s):  
A Predoi-Cross ◽  
S Brawley-Tremblay ◽  
C Povey ◽  
M A Smith

In this study, we report the first experimental measurements of air-broadening and air-induced pressure-shift coefficients for approximately 378 transitions in the ν2 fundamental band of CH3D. These results were obtained from analysis of 17 room-temperature laboratory absorption spectra recorded at 0.0056 cm–1 resolution using the McMath–Pierce Fourier transform spectrometer located on Kitt Peak, Ariz. Three absorption cells with path lengths of 10.2, 25, and 150 cm were used to record the spectra. The total sample pressures ranged from 0.129 × 10–2 to 52.855 × 10–2 atm with CH3D volume mixing ratios of approximately 0.0109 in air. The spectra were analyzed using a multispectrum nonlinear least-squares fitting technique. We report measurements for air pressure-broadening coefficients for transitions with quantum numbers as high as J′′ = 20 and K = 15, where K′′ = K′ ≡ K (for a parallel band). The measured air-broadening coefficients range from 0.0205 to 0.0835 cm–1atm–1 at 296 K. All the measured pressure-shift coefficients are negative and are found to vary from about –0.0005 to –0.0080 cm–1 atm–1 at the temperature of the spectra. We have examined the dependence of the measured broadening and shift parameters on the J′′, and K quantum numbers and also developed empirical expressions to describe the broadening coefficients in terms of m (m = –J′′, J′′, and J′′ + 1 in the QP-, QQ-, and QR-branch, respectively) and K. On average, the empirical expressions reproduce the measured broadening coefficients to within 4.4%.PACS Nos.: 33.20.Ea, 39.30+w


2003 ◽  
Vol 76 (3-4) ◽  
pp. 411-434 ◽  
Author(s):  
V. Malathy Devi ◽  
D. Chris Benner ◽  
Mary Ann H. Smith ◽  
Linda R. Brown ◽  
Michael Dulick

2011 ◽  
Vol 112 (18) ◽  
pp. 2750-2761 ◽  
Author(s):  
S. Galalou ◽  
K. Ben Mabrouk ◽  
H. Aroui ◽  
F. Kwabia Tchana ◽  
F. Willaert ◽  
...  

2000 ◽  
Vol 78 (11) ◽  
pp. 989-995 ◽  
Author(s):  
Y Liu ◽  
J Lin ◽  
Y Guo

This paper presents a method for the determination of the pressure-broadening coefficient of 15N16O by 14N16O. The hyperfine-structure-resolved spectral lines of NO were obtained with an intracavity laser magnetic resonance spectrometer via Lamb dips. From the spectra, the self-broadening coefficient of the P2(5/2) transition of the 15N16O fundamental band due to its collision with 14N16O at 293 K is determined to be 0.092(7) cm–1/atm. PACS No.: 32.40


1963 ◽  
Vol 28 (5) ◽  
pp. 1093-1095 ◽  
Author(s):  
F. A. Franz ◽  
E. Lüscher ◽  
D. W. Smith

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