Determination of the magnetocaloric effect associated with martensitic transition in Ni 46 Cu 4 Mn 38 Sn 12 and Ni 50 CoMn 34 In 15 Heusler alloys

2011 ◽  
Vol 20 (4) ◽  
pp. 047502 ◽  
Author(s):  
Zhe Li ◽  
Chao Jing ◽  
Hao-Lei Zhang ◽  
Shi-Xun Cao ◽  
Jin-Cang Zhang
2014 ◽  
Vol 584 ◽  
pp. 175-179 ◽  
Author(s):  
S. Esakki Muthu ◽  
M. Kanagaraj ◽  
Sanjay Singh ◽  
P.U. Sastry ◽  
G. Ravikumar ◽  
...  

2008 ◽  
Vol 52 ◽  
pp. 221-228 ◽  
Author(s):  
Antoni Planes ◽  
Lluís Mañosa ◽  
Xavier Moya ◽  
Jordi Marcos ◽  
Mehmet Acet ◽  
...  

In this paper, we discuss the magnetocaloric behavior of Ni-Mn-based Heusler alloys in rela- tion to their shape-memory and superelastic properties. We show that the magnetocaloric effect in these materials originates from two different contributions: (i) the coupling that is related to a strong uniaxial magnetic anisotropy and takes place at the length scale of martensite variants and magnetic domains (extrinsic effect), and (ii) the intrinsic microscopic magnetostructural coupling. The first contribution is intimately related to the magnetically induced rearrange- ment of martensite variants (magnetic shape-memory) and controls the magnetocaloric effect at small applied fields, while the latter is dominant at higher fields and is essentially related to the possibility of magnetically inducing the martensitic transition (magnetic superelasticity). The possibility of inverse magnetocaloric effect associated with these two contributions is also considered.


2019 ◽  
Vol 476 ◽  
pp. 92-99 ◽  
Author(s):  
Arup Ghosh ◽  
Rajeev Rawat ◽  
Arpan Bhattacharyya ◽  
Guruprasad Mandal ◽  
A.K. Nigam ◽  
...  

2007 ◽  
Vol 101 (5) ◽  
pp. 053919 ◽  
Author(s):  
Mahmud Khan ◽  
Naushad Ali ◽  
Shane Stadler

Author(s):  
Michael A. Carpenter ◽  
Christopher J. Howard

In the course of further studies of phase transitions in martensites [Driver, Salje, Howard, Lampronti, Ding & Carpenter (2020), Phys. Rev. B, 102, 014105], errors were uncovered in a few entries in Table 3 of the paper by Carpenter & Howard [(2018), Acta Cryst. B74, 560–573]. The required corrections are given here.


2009 ◽  
Vol 1200 ◽  
Author(s):  
Vasiliy Buchelnikov ◽  
Sergey Taskaev ◽  
Mikhail Drobosyuk ◽  
Vladimir Sokolovskiy ◽  
Viktor Koledov ◽  
...  

AbstractThe positive magnetocaloric effect (MCE) in the vicinity of the Curie point in Ni2+xMn1-xGa (x=0.33, 0.36, 0.39) Heusler alloys and the negative and positive MCE near the metamagnetostructural (MMS) transition and the Curie point, respectively, in Ni45Co5Mn36.5In13.5 Heusler alloy has been measured by a direct method. For the magnetic field change ΔH = 2 T, the maximal adiabatic temperature change ΔTad at the Curie point in Ni2+xMn1-xGa alloys is larger than 0.6 K. For Ni45Co5Mn36.5In13.5 alloy, the maximal value of ΔTad = 1.68 K (for the same magnetic field change, ΔH = 2 T) is observed at the MMS phase transition temperature.


Crystals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 329 ◽  
Author(s):  
Chengfen Xing ◽  
Hu Zhang ◽  
Kewen Long ◽  
Yaning Xiao ◽  
Hanning Zhang ◽  
...  

The effect of different atomic substitutions at Mn sites on the magnetic and magnetocaloric properties in Ni50Mn35Co2Sn13 alloy has been studied in detail. The substitution of Ni or Co for Mn atoms might lower the Mn content at Sn sites, which would reduce the d-d hybridization between Ni 3d eg states and the 3d states of excess Mn atoms at Sn sites, thus leading to the decrease of martensitic transformation temperature TM in Ni51Mn34Co2Sn13 and Ni50Mn34Co3Sn13 alloys. On the other hand, the substitution of Sn for Mn atoms in Ni50Mn34Co2Sn14 would enhance the p-d covalent hybridization between the main group element (Sn) and the transition metal element (Mn or Ni) due to the increase of Sn content, thus also reducing the TM by stabilizing the parent phase. Due to the reduction of TM, a magnetostructural martensitic transition from FM austenite to weak-magnetic martensite is realized in Ni51Mn34Co2Sn13 and Ni50Mn34Co2Sn14, resulting in a large magnetocaloric effect around room temperature. For a low field change of 3 T, the maximum ∆SM reaches as high as 30.9 J/kg K for Ni50Mn34Co2Sn14. A linear dependence of ΔSM upon μ0H has been found in Ni50Mn34Co2Sn14, and the origin of this linear relationship has been discussed by numerical analysis of Maxwell’s relation.


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