scholarly journals Lignosulfonate, anionic surfactants and their mixtures influence on water solutions surface tension and zinc concentrate pressure leaching

Author(s):  
E B Kolmachikhina ◽  
E A Ryzhkova ◽  
D V Dmitrieva ◽  
V V Sviridov ◽  
S S Naboichenko
2018 ◽  
Vol 22 (8) ◽  
pp. 143-150
Author(s):  
Elvira Kolmachikhina ◽  
◽  
Ekaterina Ryzhkova ◽  
Darya Dmitrieva ◽  
Kirill Vakula ◽  
...  

2009 ◽  
Vol 209 (1-4) ◽  
pp. 3-13 ◽  
Author(s):  
Kerstin Hagenhoff ◽  
Jingfeng Dong ◽  
Babur Z. Chowdhry ◽  
Stephen Anthony Leharne

2020 ◽  
Vol 207 ◽  
pp. 01022
Author(s):  
Vanya Gandova ◽  
Stanislava Tasheva ◽  
Krasimira Dobreva ◽  
Vanya Prodanova-Stefanova ◽  
Krasimira Marinova ◽  
...  

Some physicochemical, thermodynamic and thermal properties of linalyl acetate - ethanol - water solutions with different ethanol concentrations (70%, 75%, 80%, 85%, 90%, and 95%) in three ratios (1:5, 1:6, and 1:7) were determined. The properties were calculated to describe the stability of the system. Multiply linear regression model was obtained for surface tension prediction. Good correlation was observed between calculated and experimental surface tension values.


2010 ◽  
pp. 607-613 ◽  
Author(s):  
Pavel Kadlec ◽  
Svatopluk Henke ◽  
Zdenek Bubník

This paper deals with the physico-chemical properties of ethanol and ethanol-water solutions. The data of ethanol properties and its water solutions, which were obtained from literature, are presented in the form of Equations and Tables.Extended properties include data for pure ethanol (density, vapor pressure, surface tension, viscosity, molar and specific heat capacity, enthalpy of evaporation, thermal conductivity and static relative permittivity) and tabled data for ethanol-water solutions (0–100% ethanol) as well: concentrative properties, surface tension and thermal conductivity at20 °C, density, viscosity, boiling point and equilibrium liquid-vapor at normal pressure.


1998 ◽  
Vol 76 (2) ◽  
pp. 152-157
Author(s):  
Catherine E Drennan ◽  
Rachelle J Hughes ◽  
Vincent C Reinsborough ◽  
Oladega O Soriyan

Kinetic studies through stopped-flow spectroscopy were undertaken in the dilute solution range of anionic surfactants where pronounced rate enhancement or inhibition of Ni2+-ligand complexations is often observed at surfactant concentrations much below the critical micelle concentration (CMC). The results are interpreted in terms of Ni-surfactant micelles as the agents responsible for the rate changes in dilute surfactant solution. At higher surfactant concentrations these micelles are transformed into mixed micelles (counterion and size changes), eventually becoming normal surfactant micelles close to the CMC. Surface tension, dye solubility, conductivity, and fluorescent probe investigations support this interpretation.Key words: micellar catalysis, sodium dodecyl sulfate, micelles, critical micelle concentration, premicelles, Ni2+-ligand complexations.


2021 ◽  
Vol 22 (15) ◽  
pp. 7953
Author(s):  
Lionel Perrin ◽  
Andrew Akanno ◽  
Eduardo Guzman ◽  
Francisco Ortega ◽  
Ramon G. Rubio

The formation of coffee-ring deposits upon evaporation of sessile droplets containing mixtures of poly(diallyldimethylammonium chloride) (PDADMAC) and two different anionic surfactants were studied. This process is driven by the Marangoni stresses resulting from the formation of surface-active polyelectrolyte–surfactant complexes in solution and the salt arising from the release of counterions. The morphologies of the deposits appear to be dependent on the surfactant concentration, independent of their chemical nature, and consist of a peripheral coffee ring composed of PDADMAC and PDADMAC–surfactant complexes, and a secondary region of dendrite-like structures of pure NaCl at the interior of the residue formed at the end of the evaporation. This is compatible with a hydrodynamic flow associated with the Marangoni stress from the apex of the drop to the three-phase contact line for those cases in which the concentration of the complexes dominates the surface tension, whereas it is reversed when most of the PDADMAC and the complexes have been deposited at the rim and the bulk contains mainly salt.


2020 ◽  
Vol 299 ◽  
pp. 1121-1127
Author(s):  
E.B. Kolmachikhina ◽  
E.A. Ryzhkova ◽  
D.V. Dmitrieva

This paper is describing an investigation of sodium lingo-sulfonate and sodium dodecyl-sulfate mixtures influence on zinc concentrates high temperature oxidative pressure leaching and zinc electro-winning. For this purpose, surfactants concentration at leaching tests was varied from 200 to 800 mg∙l-1. It was established that the maximum zinc extraction (99 %) at leaching was achieved in the presence of mixture containing 800 mg∙l-1 lignosulfonate and 200 mg∙l-1 sodium dodecyl-sulfate. Therefore, this mixture can be recommended for high temperature oxidative pressure leaching of zinc concentrates. Sulfur-sulfide pellets formation also was observed at a low lingo-sulfonate concentration (200 mg∙l-1) in a mixture with sodium dodecyl-sulfate. This phenomenon can lead to emergency shut down of autoclave. It was observed that the mixture usage of 800 mg∙l-1 lignosulfonate and 200 mg∙l-1 sodium dodecyl-sulfate had no significant impact on zinc current efficiency, it was in the rage of 92-93 %. The mixture usage of 200 mg∙l-1 lignosulfonate and 600 mg∙l-1 sodium dodecyl-sulfate allowed to increase current efficiency up to 95 %. Increasing sodium dodecyl-sulfate concentration in mixtures with lignosulfonates leads to decrease of current efficiency, to formation of deep pores and defects on cathode zinc surface.


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