Exotic Computational Principles

Author(s):  
John L. Pollock

Exotic computational principles are those not derivable from the theory of proportions constructed in Chapter 2. The most important of these principles are (PFREQ) and (AGREE). The purpose of this chapter is to show that these principles can be derived from a strengthened theory of proportions—what we might call ‘the exotic theory of proportions’. The principles of the theory of proportions constructed in Chapter 2 seem completely unproblematic, and accordingly the derivations of principles of nomic probability can reasonably be regarded as proofs of those principles. That ceases to be the case when we turn to the exotic theory of proportions and the corresponding exotic principles of nomic probability. Although quite intuitive, the exotic axioms for proportions are also very strong and correspondingly riskier. Furthermore, although the exotic axioms are intuitive, intuitions become suspect at this level. The problem is that there are a large number of intuitive candidates for exotic axioms, and although each is intuitive by itself, they are jointly inconsistent. This will be illustrated below. It means that we cannot have unqualified trust in our intuitions. In light of this, (PFREQ) and (AGREE) seem more certain than the exotic principles of proportions from which they can be derived. As such, those derivations cannot reasonably be regarded as justifications for the probability principles. Instead they are best viewed as explanations for why the probability principles are true given the characterization of nomic probabilities in terms of proportions. The derivations play an explanatory role rather than a justificatory role. The exotic principles of proportions concern proportions in relational sets. Recall that we can compare sizes of sets with the relation ┌X ⇆Y┐, which was defined as ┌מ(X/X∪Y) = מ(Y/X∪Y) ┐. Our first exotic principle relates the size of a binary relation (a “two-dimensional set”) to the sizes of its one-dimensional segments. If x is in the domain D(R) of R, let Rx be the Rprojection of x, i.e., {y| Rxy}. Suppose D(R) = D(S), and for each x in their domain, Rx ⇆ Sx. Then their “linear dimensions” are everywhere the same.

2013 ◽  
Vol 19 (S4) ◽  
pp. 143-144
Author(s):  
V. Oliveira ◽  
N.I. Polushkin ◽  
O. Conde ◽  
R. Vilar

Laser ablation using ultrafast femtosecond lasers and holographic schemes has proven to be a powerful and versatile tool for surface and volume structuring. The principle of operation of this technique is simple: when two or more pulses overlap in time and space, an interference pattern is generated that can be used to create periodic surface structures. In addition, due to the extremely short pulse duration, a very high peak power is achieved leading to intense non-linear effects. As a result, almost any type of material can be processed without undesirable collateral thermal effects.In this paper, characterization of two-dimensional (2D) patterns generated in titanium using femtosecond laser radiation has been carried out using scanning electron microscopy (SEM). The laser source is a commercial Yb:KYW laser system providing pulses with a duration of 560 fs at a central wavelength of >= 1030 nm. The surface topography was characterized using a Hitachi S2400 scanning electron microscope operated at an electron acceleration voltage of 25.0 kV. Laser processing was performed in air on polished grade 2 titanium samples, a material typically used in low load bearing medical devices.One-dimensional (1D) gratings were created using a modified Michelson interferometer described in detail elsewhere (Oliveira et al., 2012). To create 2D gratings a double exposure method was used. First, 1D gratings were produced in linear tracks by translating the sample relatively to the stationary interfering laser beams with a fixed scanning velocity of 0.1 mm/s. As an example, Figure 1 depicts SEM pictures of horizontal and vertical 1D gratings with period of about 3.9 m, generated using a pulse energy and pulse repetition rate of 0.35 mJ and 100 Hz, respectively. The peak to valley distance of these patterns can be controlled either by changing the scanning velocity or the pulse repetition rate. By overlapping two linear tracks, different kinds of 2D structures can be created. Figure 2 depicts a square pattern obtained by overlapping two 1D gratings rotated by 90°. The dimensions of the squares depend on the one-dimensional gratings period, which in turn can be easily controlled by varying the distance between the interfering beams. Figure 3 depicts two other possibilities: i) trapezium-like patterns obtained by rotating the 1D gratings by 45°, and ii) rectangular patterns obtained using 1D gratings with different periods and rotated by 90°.The proposed optical setup offers a simple method of texturing the surface of materials and, hence, to control surface properties such as wettability. In the case of titanium, this is particularly important because surface texturing enhances its osseointegration ability. For this purpose, when compared with the columns spontaneously formed on titanium surfaces treated with femtosecond laser radiation, these 2D gratings present the major advantage of being size and shape-controllable.


Author(s):  
Vânia Denise Schwade ◽  
Bárbara Tirloni

Pyrimidine-2-thione (HSpym) reacts with lead(II) thiocyanate and lead(II) bromide in N,N-dimethylformamide (DMF) to form poly[(μ-isothiocyanato-κ2 N:S)(μ4-pyrimidine-2-thiolato-κ6 N 1,S:S:S:S,N 3)lead(II)], [Pb(C4H3N2S)(NCS)] n or [Pb(Spym)(NCS)] n , (I), and the polymeric one-dimensional (1D) compound catena-poly[[μ4-bromido-di-μ-bromido-(μ-pyrimidine-2-thiolato-κ3 N 1,S:S)(μ-pyrimidine-2-thione-κ3 N 1,S:S)dilead(II)] N,N-dimethylformamide monosolvate], {[Pb2Br3(C4H3N2S)(C4H4N2S)]·C3H7NO} n or {[Pb2Br3(Spym)(HSpym)]·DMF} n , (IIa), respectively. Poly[μ4-bromido-di-μ3-bromido-(μ-pyrimidine-2-thiolato-κ3 N 1,S:S)(μ-pyrimidine-2-thione-κ3 N 1,S:S)dilead(II)], [Pb2Br3(C4H3N2S)(C4H4N2S)] n or [Pb2Br3(Spym)(HSpym)] n , (IIb), could be obtained as a mixture with (IIa) when using a lesser amount of solvent. In the crystal structures of the pseudohalide/halide PbII stable compounds, coordination of anionic and neutral HSpym has been observed. Both Spym− (in the thiolate tautomeric form) and NCS− ligands were responsible for the two-dimensional (2D) arrangement in (I). The Br− ligands establish the 1D polymeric arrangement in (IIa). Eight-coordinated metal centres have been observed in both compounds, when considering the Pb...S and Pb...Br interactions. Both compounds were characterized by FT–IR and diffuse reflectance spectroscopies, as well as by powder X-ray diffraction. Compound (IIa) and its desolvated version (IIb) represent the first structurally characterized PbII compounds containing neutral HSpym and anionic Spym− ligands. After a prolonged time in solution, (IIa) is converted to another compound due to complete deprotonation of HSpym. The structural characterization of (I) and (II) suggests HSpym as a good candidate for the removal of PbII ions from solutions containing thiocyanate or bromide ions.


ChemInform ◽  
2015 ◽  
Vol 46 (16) ◽  
pp. no-no
Author(s):  
Laura Torre-Fernandez ◽  
Olena A. Khainakova ◽  
Aranzazu Espina ◽  
Zakariae Amghouz ◽  
Sergei A. Khainakov ◽  
...  

Author(s):  
Chris Waudby ◽  
Tom Frenkiel ◽  
John Christodoulou

Two-dimensional correlation measurements such as COSY, NOESY, HMQC and HSQC experiments are central to small molecule and biomolecular NMR spectroscopy, and commonly form the basis of more complex experiments designed to study chemical exchange occurring during additional mixing periods. However, exchange occurring during chemical shift evolution periods can also influence the appearance of such spectra. While this is often exploited through one-dimensional lineshape analysis ('dynamic NMR'), the analysis of exchange across multiple chemical shift evolution periods has received less attention. Here we report that chemical exchange-induced cross-peaks can arise in even the simplest two-dimensional NMR experiments. These cross-peaks can have highly distorted phases that contain rich information about the underlying exchange process. The quantitative analysis of such peaks, from a single 2D spectrum, can provide a highly accurate characterization of underlying exchange processes.


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