scholarly journals Alan Herbert Cowley. 29 January 1934—2 August 2020

Author(s):  
Richard A. Jones ◽  
Richard A. Kemp ◽  
Jonathan G. Lasch ◽  
Michael Lattman ◽  
Nicholas C. Norman

Alan Cowley was one of the most creative main group chemists of his generation, and had a central role in what was often described as the renaissance of main group chemistry. Throughout his career Alan always had an eye for what was new. In his early years as an independent researcher, Alan made many fundamental contributions to the chemistry of phosphorus, not only in terms of the synthesis of new compounds but also in their study by employing novel analytical and computational methods. Starting in the 1980s he was at the forefront of emerging research into low-coordinate phosphorus chemistry and made seminal contributions in the areas of multiply bonded species, such as phosphenium ions and diphosphenes, as well as in the transition metal coordination chemistry of phosphinidenes. In the second half of his career, Alan also turned his attention to the study of single source precursors for important solid-state electronic materials, many of which were far superior to known examples. In all of the many areas in which Alan worked, he was a great collaborator with colleagues and researchers across the world, both in chemistry and in other disciplines. This was made all the easier by Alan's charm and easy-going nature, which was also manifest in the interactions he had with his many group members over a period of almost half a century. Alan was a gentleman in every sense and is much missed by friends, colleagues, collaborators and family.

2001 ◽  
Vol 79 (12) ◽  
pp. 1841-1850 ◽  
Author(s):  
Tristram Chivers

The imido group (NR) is a versatile ligand in main group chemistry. The high reactivity of multiply bonded (terminal) imido derivatives of p-block elements is used, for example, in the aza-Wittig reaction, allylic aminations, and in peptide synthesis. As a bridging ligand, the imido group provides a cornerstone for a wide variety of binary cluster structures. This review is primarily concerned with the synthesis, structures, reactions, and ligand behaviour of imido derivatives of the heavy chalcogens (selenium and tellurium) as exemplified by the tellurium diimide dimer t-BuNTe(µ-N-t-Bu)2TeN-t-Bu and the homoleptic trisimido-tellurite dianion [Te(N-t-Bu)3]2–. The synthesis and cluster structures of alkali metal and alkaline earth metal derivatives of heteroleptic imido-oxo anions of sulfur, e.g., [OxS(NR)3 – x]2– (x = 1, 2) and [O2S(µ-NPh)SO2]2–, are also discussed.Key words: main group chemistry, imido ligand, chalcogens.


1992 ◽  
Vol 11 (1) ◽  
pp. 192-195 ◽  
Author(s):  
Sally Brooker ◽  
Norbert Bertel ◽  
Dietmar Stalke ◽  
Mathias Noltemeyer ◽  
Herbert W. Roesky ◽  
...  

Author(s):  
R.M. Minyaev ◽  
T.N. Gribanova ◽  
V.I. Minkin

2018 ◽  
Vol 47 (31) ◽  
pp. 10377-10381 ◽  
Author(s):  
Adam J. Ruddy ◽  
Darren M. C. Ould ◽  
Paul D. Newman ◽  
Rebecca L. Melen

Recent developments in main group chemistry towards the activation and conversion of N2 have lead to the revelation that boron can greatly affect these processes.


Sign in / Sign up

Export Citation Format

Share Document