On the one-dimensional recovery and microstructural evaluation of shocked alumina

2006 ◽  
Vol 462 (2074) ◽  
pp. 3197-3212 ◽  
Author(s):  
N.K Bourne ◽  
W.H Green ◽  
D.P Dandekar
Keyword(s):  
Elastic Limit ◽  
Three Dimensional ◽  
Dislocation Interaction ◽  
One Dimensional ◽  
X Ray ◽  
Interaction Mechanisms ◽  
Microstructural Evaluation ◽  
The One

A technique has been developed in the previous work for determining dislocation interaction mechanisms in metals by shocking, unloading, then decelerating and catching part of the target for subsequent examination. This proceeds by using a system of partial momentum traps around the sample. This technique is further refined here, and is then applied to recover brittle targets that, in three-dimensional loading, would fail into a series of fragments. A number of hydrocode design simulations are presented to illustrate the technique, and the results of the experiments are presented. Sectioned targets indicate fracture, and X-ray tomography gives an overview of the volumetric damage. The response of the alumina above and below the elastic limit is highlighted.

A one-dimensional silver(I) coordination polymer based on 5-methyl-1,3,4-thiadiazol-2-amine and pyridine-2,3-dicarboxylate

2017 ◽  
Vol 73 (6) ◽  
pp. 498-502
Author(s):  
Wei-Wei Fu ◽  
Juan Li ◽  
Shu-Ting Liu ◽  
Dan Zhao ◽  
Xue Zhou ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Binding Modes ◽  
Supramolecular Framework ◽  
X Ray Diffraction ◽  
Tetrahedral Geometry ◽  
One Dimensional ◽  
X Ray ◽  
The One

The bifunctional pyridine-2,3-dicarboxylic acid (H2pdc) ligand has one N atom and four O atoms, which could bind more than one AgI centre with diverse binding modes. A novel infinite one-dimensional AgI coordination polymer, namely catena-poly[[silver(I)-(μ2-pyridine-2,3-dicarboxylato-κ2 N:O 3)-silver(I)-tris(μ2-5-methyl-1,3,4-thiodiazol-2-amine-κ2 N:N′)] monohydrate ethanol monosolvate], {[Ag2(C7H3NO4)(C3H5N3S)3]·H2O·C2H5OH} n , has been synthesized using H2pdc and 5-methyl-1,3,4-thiadiazol-2-amine (tda), and characterized by single-crystal X-ray diffraction. One AgI atom is located in a four-coordinated AgN4 tetrahedral geometry and the other AgI atom is in a tetrahedral AgN3O geometry. A dinuclear AgI cluster formed by three tda ligands with a paddelwheel configuration is bridged by the dianionic pdc2− ligand into a one-dimensional coordination polymer. Interchain N—H...O hydrogen bonds extend the one-dimensional chains into an undulating two-dimensional sheet. The sheets are further packed into a three-dimensional supramolecular framework by interchain N—H...O hydrogen bonds.

The lattice distortion and possible causes of the lazurite incommensurate and commensurate modulation structure

1993 ◽  
Vol 8 (4) ◽  
pp. 202-205
Author(s):  
A. N. Sapozhnikov ◽  
E. K. Vasil'ev
Keyword(s):  
Lattice Distortion ◽  
Three Dimensional ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
Mineral Structure ◽  
Incommensurate Modulation ◽  
Density Modulation ◽  
Cubic Structure ◽  
The One

By methods of X-ray structure analysis commensurate (one dimensional) and incommensurate (three-dimensional) modulations of the lazurite structure from Baikal deposits are considered. The analysis of the X-ray diffraction powder and single crystal data showed that the one-dimensional (anisotropic) modulation deforms the lazurite cubic structure and is manifested in a broadening and splitting of sublattice lines on the powder diffraction pattern of the mineral. At a three-dimensional modulation, the cubic structure is maintained. It is concluded that a density modulation is a cause of the incommensurate modulation of the lazurite structure. Due to this arrangement, a crystallographic equivalency of subcells is maintained. The cause of the commensurate modulation is an ordered distribution of intraframework units and the displacement modulation where all atoms of the mineral structure participate.

A one-dimensional coordination polymer createdvia in situligand synthesis involving C—N bond formation

2013 ◽  
Vol 69 (11) ◽  
pp. 1307-1310 ◽  
Author(s):  
Hua Cai ◽  
Ying Guo ◽  
Jian-Gang Li
Keyword(s):  
Addition Reaction ◽  
Bond Formation ◽  
Three Dimensional ◽  
Cadmium Complex ◽  
Stacking Interactions ◽  
The Novel ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
The One

The novel cadmium complexcatena-poly[cadmium(II)-μ3-{2-[3-(pyridin-2-yl)-1H-pyrazol-1-yl]butanedioato}], [Cd(C12H9N3O4)]n, has been prepared by the conjugate addition reaction of 2-(1H-pyrazol-3-yl)pyridine to fumaric acid in the presence of Cd(OAc)2·3H2O (OAc is acetate) at 413 K. Single-crystal X-ray diffraction analysis reveals that the complex consists of one-dimensional ladders constructed from [Cd2(COO)2] dimeric subunits. A combination of hydrogen bonding and π–π stacking interactions extend the one-dimensional ladders into a three-dimensional supramolecular architecture.

Exploring the Multidimensional Facets of Authoritarianism: Authoritarian Aggression and Social Dominance Orientation

2008 ◽  
Vol 67 (1) ◽  
pp. 51-60 ◽  
Author(s):  
Stefano Passini
Keyword(s):  
Social Dominance ◽  
Factor Model ◽  
Three Dimensional ◽  
Social Dominance Orientation ◽  
Model Fit ◽  
Regression Analyses ◽  
One Dimensional ◽  
Confirmatory Factor ◽  
The One ◽  
Better Than

The relation between authoritarianism and social dominance orientation was analyzed, with authoritarianism measured using a three-dimensional scale. The implicit multidimensional structure (authoritarian submission, conventionalism, authoritarian aggression) of Altemeyer’s (1981, 1988) conceptualization of authoritarianism is inconsistent with its one-dimensional methodological operationalization. The dimensionality of authoritarianism was investigated using confirmatory factor analysis in a sample of 713 university students. As hypothesized, the three-factor model fit the data significantly better than the one-factor model. Regression analyses revealed that only authoritarian aggression was related to social dominance orientation. That is, only intolerance of deviance was related to high social dominance, whereas submissiveness was not.

On the numerical study of thermohydrodynamics and biochemistry of inland water bodies

2021 ◽  
Author(s):  
Daria Gladskikh ◽  
Evgeny Mortikov ◽  
Victor Stepanenko
Keyword(s):  
Mixed Layer ◽  
Numerical Study ◽  
Three Dimensional ◽  
Water Bodies ◽  
Dimensional Model ◽  
Three Dimensional Model ◽  
One Dimensional ◽  
Lake Model ◽  
Upper Mixed Layer ◽  
The One

<p>The study of thermodynamic and biochemical processes of inland water objects using one- and three-dimensional RANS numerical models was carried out both for idealized water bodies and using measurements data. The need to take into account seiche oscillations to correctly reproduce the deepening of the upper mixed layer in one-dimensional (vertical) models is demonstrated. We considered the one-dimensional LAKE model [1] and the three-dimensional model [2, 3, 4] developed at the Research Computing Center of Moscow State University on the basis of a hydrodynamic code combining DNS/LES/RANS approaches for calculating geophysical turbulent flows. The three-dimensional model was supplemented by the equations for calculating biochemical substances by analogy with the one-dimensional biochemistry equations used in the LAKE model. The effect of mixing processes on the distribution of concentration of greenhouse gases, in particular, methane and oxygen, was studied.</p><p>The work was supported by grants of the RF President’s Grant for Young Scientists (MK-1867.2020.5, MD-1850.2020.5) and by the RFBR (19-05-00249, 20-05-00776). </p><p>1. Stepanenko V., Mammarella I., Ojala A., Miettinen H., Lykosov V., Timo V. LAKE 2.0: a model for temperature, methane, carbon dioxide and oxygen dynamics in lakes // Geoscientific Model Development. 2016. V. 9(5). P. 1977–2006.<br>2. Mortikov E.V., Glazunov A.V., Lykosov V.N. Numerical study of plane Couette flow: turbulence statistics and the structure of pressure-strain correlations // Russian Journal of Numerical Analysis and Mathematical Modelling. 2019. 34(2). P. 119-132.<br>3. Mortikov, E.V. Numerical simulation of the motion of an ice keel in stratified flow // Izv. Atmos. Ocean. Phys. 2016. V. 52. P. 108-115.<br>4. Gladskikh D.S., Stepanenko V.M., Mortikov E.V. On the influence of the horizontal dimensions of inland waters on the thickness of the upper mixed layer // Water Resourses. 2021.V. 45, 9 pages. (in press) </p>

scholarly journals The three dimensional stabilization of superconductivity at 12 K in the one dimensional organic superconductor (TMTSF)2PF6 under 11 kbar

1981 ◽  
Vol 42 (19) ◽  
pp. 445-449 ◽  
Author(s):  
A. Fournel ◽  
C. More ◽  
G. Roger ◽  
J.P. Sorbier ◽  
J.M. Delrieu ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Organic Superconductor ◽  
One Dimensional ◽  
The One

Polysulfonylamine, CXXV [1]. Neue Komplexe von Disulfonylaminen mit Kronenethern - im voraus entworfen oder zufällig entdeckt / Polysulfonylamines, CXXV [1]. New Complexes of Disulfonylam ines with Crown Ethers - Preconceived or Discovered by Serendipity

2000 ◽  
Vol 55 (3-4) ◽  
pp. 299-316 ◽  
Author(s):  
Dagmar Henschel ◽  
Karna Wijaya ◽  
Oliver Moers ◽  
Armand Blaschette ◽  
Peter G. Jones
Keyword(s):  
Hydrogen Bonds ◽  
X Ray Diffraction ◽  
Ladder Structure ◽  
Triclinic Space Group ◽  
One Dimensional ◽  
X Ray ◽  
Bonding System ◽  
Supramolecular Aggregate ◽  
Guest Species ◽  
The One

Abstract In a study aim ed at the „deconstruction“ of the supramolecular aggregate 3(18C6) · 2HN( SO2Me)2 (1,18C6 = 18-crown-6), which is known to display a ladder structure with two isotactic [18C6 - Me SO2N(H)SO2Me···)∞ polymers forming the uprights and symmetrically N - H···O bonded 18C6 rings providing the rungs, the following crystalline complexes were isolated and (except for 2b) characterized by low-temperature X-ray diffraction: 18C6-ClN (SO2Me)2 (2a, triclinic, space group P1̅, Z = 2), 18C6-PhN (SO2Me)2 (2b), 18C6 -MeN(SO2Me)2 (3, monoclinic, P21/c, Z = 8), Bz18C6-HN(SO2Me)2 (4, Bz18C6 = benzo-18-crown-6, monoclinic, P21/n, Z = 4), 18C6-2 MeN (SO2Me)2 (5, triclinic, P1̅, Z = 1), 18C6-Me2SO- HN( SO2Me) (SO2Ph) (13, triclinic, P1̅, Z = 2), and 18C6-H2OMe2SO·2HN(SO2Me)2 (14, triclinic, P1̅, Z = 2). Each of the one-dimensional polymers 2a (syndiotactic), 3 (disyndiotactic) and 4 (isotactic) mimics a single upright of 1; in contrast to 1 and 2a, where the intra-catemer connectivity solely relies on S - Me ··· crow n and crown ··· O = S hydrogen bonds, this bonding system is reinforced in 3 by N -Me ··· crown and in 4 by N - H ··· crown hydrogen bonds. Complex 5 is monomeric and matches a fragment formally extruded from the catemer 3; moreover, 3 and 5 represent a rare case of two structurally characterized 18C6 complexes containing the same uncharged guest species in distinct molecular ratios. The surprising structure of the quaternary adduct 14 exhibits an [18C6 ··· MeSO2N(H)SO2Me ··· ]∞ chain, which can be regarded both as an isolated, though unmodified upright from the ladder 1 and, being syndiotactic, as a stereochemical analogue of 2a; the potentially rung-forming *NH functions in the chain are blocked by hydrogenbonded side chains of the type * N - H ··· water ··· sulfoxide ··· H - N (SO2Me)2. The ternary complex 13 consists of chains [18C6 ··· Me2SO ··· H - N (SO2Ph)SO2Me···]∞ and is not closely related to the other structures

scholarly journals Hydraulic modeling of combined sewers overflow integrating the results of the SWMM and CFX models.

2021 ◽  
Vol 37 (1) ◽  
Author(s):  
D. Pulgarín ◽  
J. Plaza ◽  
J. Ruge ◽  
J. Rojas
Keyword(s):  
Three Dimensional ◽  
Hydraulic Modeling ◽  
Dimensional Model ◽  
Three Dimensional Model ◽  
One Dimensional ◽  
Ansys Cfx ◽  
Combined Sewer ◽  
The One ◽  
Swmm Model

This study proposes a methodology for the calibration of combined sewer overflow (CSO), incorporating the results of the three-dimensional ANSYS CFX model in the SWMM one-dimensional model. The procedure consists of constructing calibration curves in ANSYS CFX that relate the input flow to the CSO with the overflow, to then incorporate them into the SWMM model. The results obtained show that the behavior of the flow over the crest of the overflow weir varies in space and time. Therefore, the flow of entry to the CSO and the flow of excesses maintain a non-linear relationship, contrary to the results obtained in the one-dimensional model. However, the uncertainty associated with the idealization of flow methodologies in one dimension is reduced under the SWMM model with kinematic wave conditions and simulating CSO from curves obtained in ANSYS CFX. The result obtained facilitates the calibration of combined sewer networks for permanent or non-permanent flow conditions, by means of the construction of curves in a three-dimensional model, especially when the information collected in situ is limited.

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