Effects of temperature on the absorption line-shape function for driven two-level atoms: A non-Markovian treatment

1995 ◽  
Vol 52 (4) ◽  
pp. 2804-2810 ◽  
Author(s):  
J. R. Brinati ◽  
S. S. Mizrahi ◽  
G. A. Prataviera
1961 ◽  
Vol 39 (12) ◽  
pp. 1733-1737 ◽  
Author(s):  
Y. Y. Lee

The adequacy of the approximation method used by McMillan and Opechowski in their theoretical study of the temperature dependence of the paramagnetic resonance line shape function is very difficult to ascertain for the case of a typical paramagnetic crystal. For this reason the approximation method has been investigated for the very simple case of the one-dimensional Ising model. Exact expressions for the line shape function of the model are compared with expressions obtained by the approximation method mentioned above. The agreement between the two expressions is found to be very good in general, and extremely good at very low temperatures.


2018 ◽  
Vol 17 (5) ◽  
pp. 552-560 ◽  
Author(s):  
Daniele Loco ◽  
Sandro Jurinovich ◽  
Lorenzo Cupellini ◽  
Maximilian F. S. J. Menger ◽  
Benedetta Mennucci

We present a polarizable QM/MM strategy to simulate the absorption line shape of chromophores embedded in complex matrices, including both homogeneous and inhomogeneous broadening.


2018 ◽  
Vol 7 (3) ◽  
pp. 245-252 ◽  
Author(s):  
Zhongdong Yang ◽  
Yuquan Zhen ◽  
Zenshan Yin ◽  
Chao Lin ◽  
Yanmeng Bi ◽  
...  

Abstract. TanSat is a key satellite mission in the Chinese Earth Observation program and is designed to measure the global atmospheric column-averaged dry-air CO2 mole fraction by measuring the visible and near-infrared solar-reflected spectra. The first Chinese super-high-resolution grating spectrometer for measuring atmospheric CO2 is aboard TanSat. This spectrometer is a suite incorporating three grating spectrometers that make coincident measurements of reflected sunlight in the near-infrared CO2 band near 1.61 and 2.06 µm and in the molecular oxygen (O2) A-band at 0.76 µm. The spectral resolving power (λ∕Δλ) values are ∼19 000, ∼12 800, and ∼12 250 in the O2 A-band, and the weak and strong absorption bands of CO2, respectively. This paper describes the prelaunch spectral calibration of the atmospheric carbon dioxide grating spectrometer aboard TanSat. Several critical aspects of the spectrometer, including the spectral resolution, spectral dispersion, and the instrument line shape function of each channel, which are directly related to producing the Level 1 products are evaluated in this paper. The instrument line shape function of the spectrometer is notably symmetrical and perfectly consistent across all channels in the three bands. The symmetry is better then 99.99 %, and the consistency in the worst case is better then 99.97 %, 99.98 %, and 99.98 % in the O2 A, WCO2, and SCO2 bands, respectively. The resulting variations in the spectral calibrations and the radiometric response errors are negligible. The spectral resolution characterizations meet the mission requirements. The spectral dispersions have excellent consistency in the spatial dimension of each band, and there is good linearity in the spectral dimension of each band. The RMS errors of the fitting residuals are 0.9, 1, and 0.7 pm in the O2 A-band, the WCO2 band, and the SCO2 band, respectively. Taken together, these results suggest that the spectral characterizations of the spectrometer aboard TanSat meet the mission requirements.


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