Low-temperature localized motion of hydrogen and electronic structure transition in hexagonal-close-packed scandium

1989 ◽  
Vol 39 (4) ◽  
pp. 2012-2021 ◽  
Author(s):  
L. R. Lichty ◽  
J-W. Han ◽  
R. Ibanez-Meier ◽  
D. R. Torgeson ◽  
R. G. Barnes ◽  
...  

1978 ◽  
Vol 39 (C6) ◽  
pp. C6-416-C6-417
Author(s):  
B. M. Klein ◽  
L. L. Boyer ◽  
D. A. Papaconstantopoulos


Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 742
Author(s):  
Motomichi Koyama ◽  
Takeaki Gondo ◽  
Kaneaki Tsuzaki

The effects of ausforming in an Fe30Mn10Cr10Co high-entropy alloy on the microstructure, hardness, and plastic anisotropy were investigated. The alloy showed a dual-phase microstructure consisting of face-centered cubic (FCC) austenite and hexagonal close-packed (HCP) martensite in the as-solution-treated condition, and the finish temperature for the reverse transformation was below 200 °C. Therefore, low-temperature ausforming at 200 °C was achieved, which resulted in microstructure refinement and significantly increased the hardness. Furthermore, plasticity anisotropy, a common problem in HCP structures, was suppressed by the ausforming treatment. This, in turn, reduced the scatter of the hardness.



2017 ◽  
Vol 4 (9) ◽  
pp. 094001
Author(s):  
G Krishnamurthy Grandhi ◽  
Renu Tomar ◽  
Ranjani Viswanatha


Author(s):  
Nikolay G. Maksimov ◽  
Victor V. Verpekin ◽  
Dmitry V. Zimonin ◽  
Galina V. Burmakina ◽  
Oleg S. Chudin ◽  
...  

The chemical oxidation of the cluster CpReFePt(μ3-C=CHPh)(CO)5(dppe) (Cp = η5-C5H5, dppe = η2- Ph2P(CH2)2PPh2) resulted in a radical cation [CpReFePt(μ3-C=CHPh)(CO)5(dppe)]+• that is sufficiently stable only at low temperature. An electronic structure of the radical cation was studied by EPR and following parameters were obtained by comparison of the experimental and model spectrum: gx = 2.070 gy = 2.0295 gz = 1.997; Ax(31P) = 17 Ay(31P) = 49 Az(31P) = 35 (Gs);Ax(195Pt) = 62 Ay(195Pt) = 45 Az(195Pt) = 105 (Gs). An unpaired electron is seen to be mainly concentrated on the iron atom (85-90%) and partially on the platinum atom (10-15%). Further transformation of the radical cation led to the formation of the binuclear complex Cp(CO)2RePt(μ-C=CHPh)(dppe) and the Fe-carbonyl fragment





2017 ◽  
Vol 249 ◽  
pp. 54-59 ◽  
Author(s):  
Takamitsu Yamanaka ◽  
Muhtar Ahart ◽  
Ho-kwang Mao ◽  
Takeyuki Suzuki


1984 ◽  
Vol 57 (5-6) ◽  
pp. 629-649 ◽  
Author(s):  
M. Dacorogna ◽  
T. Jarlborg ◽  
A. Junod ◽  
M. Pelizzone ◽  
M. Peter


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