X-ray magnetic scattering study of three-dimensional magnetic order in the quasi-one-dimensional antiferromagnetNd2BaNiO5

Four lithium coordination polymers, [Li3(BTC)(H2O)6] (1), [Li3(BTC)(H2O)5] (2), [Li3(BTC)(μ2-H2O)] (3), and [Li(H2BTC)(H2O)] (4) (H3BTC = 1,3,5-benzenetricarboxylatic acid), have been synthesized and characterized. All the structures have been determined using single crystal X-ray diffraction studies. Complexes 1 and 2 have two-dimensional (2-D) sheets, whereas complex 3 has three-dimensional (3-D) frameworks and complex 4 has one-dimensional (1-D) tubular chains. The crystal-to-crystal transformation was observed in 1–3 upon removal of water molecules, which accompanied the changes in structures and ligand bridging modes. Furthermore, the electrochemical properties of complexes 3 and 4 have been studied to evaluate these compounds as electrode materials in lithium ion batteries with the discharge capacities of 120 and 257 mAhg−1 in the first thirty cycles, respectively.

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Synthesis, Structure, and Properties of a New ErIII Iodate

Australian Journal of Chemistry ◽

10.1071/ch13570 ◽

2014 ◽

Vol 67 (5) ◽

pp. 763 ◽

Cited By ~ 2

Author(s):

Chun-Yang Pan ◽

Hai-Deng Mai ◽

Wu-Zhou Chen ◽

Feng-Hua Zhao ◽

Hong-Mei Yang

Keyword(s):

Three Dimensional ◽

Luminescence Spectroscopy ◽

Supramolecular Network ◽

Structure And Properties ◽

Dsc Analysis ◽

Hydrothermal Conditions ◽

Scanning Calorimetry ◽

One Dimensional ◽

X Ray ◽

Triclinic System

A new iodate Er(IO3)3·2H2O was synthesized under mild hydrothermal conditions. The structure has been confirmed by single-crystal X-ray analysis. It crystallizes in the triclinic system with space group P-1 (No.2), a = 7.338(4) Å, b = 7.506(4) Å, c = 9.409(5) Å, α = 79.698(5)°, β = 85.245(4)°, γ = 71.934(4)°, V = 484.5(5) Å3, Z = 2. Some characterizations were performed such as Fourier transform infrared spectroscopy (FTIR), thermogravimetric–differential scanning calorimetry (TG-DSC) analysis, luminescence spectroscopy, and magnetic property measurements. The overall framework of Er(IO3)3·2H2O is based on one-dimensional chains. The adjacent chains are further linked with each other by hydrogen bonds to form a three-dimensional supramolecular network. The luminescent and magnetic properties of Er(IO3)3·2H2O were studied.

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A one-dimensional coordination polymer with a three-dimensional supramolecular framework:catena-poly[[[(3,4,7,8-tetramethyl-1,10-phenanthroline)cadmium(II)]-μ3-4,4′-sulfonyldibenzoato] trihydrate]

Acta Crystallographica Section C Crystal Structure Communications ◽

10.1107/s0108270113001352 ◽

2013 ◽

Vol 69 (3) ◽

pp. 241-243 ◽

Cited By ~ 2

Author(s):

Jun Wang ◽

Jian-Qing Tao ◽

Xiao-Juan Xu ◽

Chun-Yun Tan

Keyword(s):

Three Dimensional ◽

Water Molecules ◽

X Ray Diffraction ◽

Polymeric Compound ◽

Chain Polymer ◽

One Dimensional ◽

X Ray ◽

Carboxylate Groups ◽

Metal Organic ◽

Coordination Patterns

In the title mixed-ligand metal–organic polymeric compound, {[Cd(C14H8O6S)(C16H16N2)]·3H2O}n, the asymmetric unit contains a crystallographically unique CdIIatom, one doubly deprotonated 4,4′-sulfonyldibenzoic acid (H2SDBA) ligand, one 3,4,7,8-tetramethyl-1,10-phenanthroline (TMPHEN) molecule and three solvent water molecules. Each CdIIcentre is six-coordinated by two O atoms from a chelating carboxylate group of a SDBA2−ligand, two O atoms from monodentate carboxylate groups of two different SDBA2−ligands and two N atoms from a chelating TMPHEN ligand. There are two coordination patterns for the carboxylate groups of the SDBA2−ligand, with one in a μ1-η1:η1chelating mode and the other in a μ2-η1:η1bis-monodentate mode. Single-crystal X-ray diffraction analysis revealed that the title compound is a one-dimensional double-chain polymer containing 28-membered rings based on the [Cd2(CO2)2] rhomboid subunit. More interestingly, a chair-shaped water hexamer cluster is observed in the compound.

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X-ray diffuse scattering study of the organic one-dimensional conductor TMTTF-bromanil

Solid State Communications ◽

10.1016/0038-1098(83)90682-8 ◽

1983 ◽

Vol 46 (7) ◽

pp. 521-525 ◽

Cited By ~ 3

Author(s):

S. Kagoshima ◽

J.P. Pouget ◽

T. Yasunaga ◽

J.B. Torrance

Keyword(s):

Diffuse Scattering ◽

One Dimensional ◽

X Ray ◽

Scattering Study

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A new three-dimensional CdIIsupramolecular framework constructed from the 1-[(1H-tetrazol-5-yl)methyl]-1,4-diazoniabicyclo[2.2.2]octane ligand

Acta Crystallographica Section C Structural Chemistry ◽

10.1107/s2053229614028009 ◽

2015 ◽

Vol 71 (2) ◽

pp. 93-96 ◽

Cited By ~ 3

Author(s):

Qiang Li ◽

Hui-Ting Wang ◽

Lin Zhou

Keyword(s):

Crystal Packing ◽

Three Dimensional ◽

Supramolecular Network ◽

Stacking Interactions ◽

X Ray Diffraction ◽

One Dimensional ◽

X Ray ◽

Distorted Octahedral Coordination Geometry ◽

Distorted Octahedral ◽

Cl Atoms

A new tetrazole–metal supramolecular compound, di-μ-chlorido-bis(trichlorido{1-[(1H-tetrazol-5-yl-κN2)methyl]-1,4-diazoniabicyclo[2.2.2]octane}cadmium(II)), [Cd2(C8H16N6)2Cl8], has been synthesized and structurally characterized by single-crystal X-ray diffraction. In the structure, each CdIIcation is coordinated by five Cl atoms (two bridging and three terminal) and by one N atom from the 1-[(1H-tetrazol-5-yl)methyl]-1,4-diazoniabicyclo[2.2.2]octane ligand, adopting a slightly distorted octahedral coordination geometry. The bridging bicyclo[2.2.2]octane and chloride ligands link the CdIIcations into one-dimensional ribbon-like N—H...Cl hydrogen-bonded chains along thebaxis. An extensive hydrogen-bonding network formed by N—H...Cl and C—H...Cl hydrogen bonds, and interchain π–π stacking interactions between adjacent tetrazole rings, consolidate the crystal packing, linking the poymeric chains into a three-dimensional supramolecular network.

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A one-dimensional coordination polymer based on Cd2O2clusters: poly[aqua(μ3-4,4′-sulfonyldibenzoato)(3,4,7,8-tetramethyl-1,10-phenanthroline-κ2N,N′)cadmium(II)]

Acta Crystallographica Section C Crystal Structure Communications ◽

10.1107/s0108270113001716 ◽

2013 ◽

Vol 69 (3) ◽

pp. 244-246 ◽

Cited By ~ 2

Author(s):

Jian-Qing Tao

Keyword(s):

Water Molecule ◽

Three Dimensional ◽

X Ray Diffraction ◽

Chain Polymer ◽

One Dimensional ◽

X Ray ◽

Acid Ligand ◽

Carboxylate Groups ◽

Metal Organic ◽

Coordinated Water

In the title mixed-ligand metal–organic polymeric complex [Cd(C14H8O6S)(C16H16N2)(H2O)]n, the asymmetric unit contains a crystallographically unique CdIIatom, one doubly deprotonated 4,4′-sulfonyldibenzoic acid ligand (H2SDBA), one 3,4,7,8-tetramethyl-1,10-phenanthroline (TMPHEN) molecule and one water molecule. Each CdIIcentre is coordinated by two N atoms from the chelating TMPHEN ligand, three O atoms from monodentate carboxylate groups of three different SDBA2−ligands and one O atom from a coordinated water molecule, giving a distorted CdN2O4octahedral geometry. Single-crystal X-ray diffraction analysis reveals that the compound is a one-dimensional double-chain polymer containing 28-membered rings based on Cd2O2clusters, with a Cd...Cd separation of 3.6889 (4) Å. These chains are linked by O—H...O and C—H...O hydrogen bonds to form a three-dimensional supramolecular framework. The framework is reinforced by π–π and C—O...π interactions.

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Observation of magnetic order in multiferroicSmMn2O5studied by resonant x-ray magnetic scattering

Physical Review B ◽

10.1103/physrevb.93.064415 ◽

2016 ◽

Vol 93 (6) ◽

Cited By ~ 13

Author(s):

Y. Ishii ◽

S. Horio ◽

M. Mitarashi ◽

T. Sakakura ◽

M. Fukunaga ◽

...

Keyword(s):

Magnetic Order ◽

Magnetic Scattering ◽

X Ray

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Magnetic order of LiCu2O2 studied by resonant soft x-ray magnetic scattering

Solid State Communications ◽

10.1016/j.ssc.2008.04.040 ◽

2008 ◽

Vol 147 (5-6) ◽

pp. 234-237 ◽

Cited By ~ 11

Author(s):

S.W. Huang ◽

D.J. Huang ◽

J. Okamoto ◽

W.B. Wu ◽

C.T. Chen ◽

...

Keyword(s):

Magnetic Order ◽

Magnetic Scattering ◽

X Ray

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X-Ray Scattering Study of a One-Dimensional Ionic Conductor; Hollandite

Journal of the Physical Society of Japan ◽

10.1143/jpsj.53.2311 ◽

1984 ◽

Vol 53 (7) ◽

pp. 2311-2315 ◽

Cited By ~ 9

Author(s):

Hikaru Terauchi ◽

Takafusa Futamura ◽

Tadao Ishii ◽

Yoshinori Fujiki

Keyword(s):

Ionic Conductor ◽

One Dimensional ◽

X Ray ◽

X Ray Scattering ◽

Scattering Study ◽

Ray Scattering

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Structural investigation of one- and three-dimensional lanthanide(III) coordination polymers based on functionalized terpyridine carboxylate and aromatic dicarboxylate ligands

Acta Crystallographica Section C Structural Chemistry ◽

10.1107/s2053229619003437 ◽

2019 ◽

Vol 75 (4) ◽

pp. 422-432 ◽

Cited By ~ 3

Author(s):

Chao Bai ◽

Bin Liu ◽

Huai-Ming Hu ◽

Jin-Dian Li ◽

Xiaofang Wang ◽

...

Keyword(s):

Coordination Polymers ◽

Structural Investigation ◽

Three Dimensional ◽

Topological Type ◽

X Ray Diffraction ◽

Hydrothermal Conditions ◽

One Dimensional ◽

X Ray ◽

Lanthanide Coordination Polymers ◽

3D Networks

Three series of lanthanide coordination polymers, namely catena-poly[[lanthanide(III)-μ2-(benzene-1,2-dicarboxylato)-μ2-[2-(2,2′:6′,2′′-terpyridin-4′-yl)benzoato]] monohydrate], {[Ln(C8H4O4)(C22H14N3O2)]·H2O} n or {[Ln(1,2-bdc)(L)]·H2O} n , with lanthanide (Ln) = dysprosium (Dy, 1), holmium (Ho, 2) and erbium (Er, 3), poly[bis(μ2-benzene-1,3-dicarboxylato)bis[μ2-2-(2,2′:6′,2′′-terpyridin-4′-yl)benzoato]dilanthanide(III)], [Ln2(C8H4O4)2(C22H14N3O2)2] n or [Ln2(1,3-bdc)2(L)2] n , with Ln = gadolinium (Gd, 4), Ho (5) and Er (6), and poly[(μ2-benzene-1,4-dicarboxylato)[μ2-2-(2,2′:6′,2′′-terpyridin-4′-yl)benzoato]lanthanide(III)], [Ln(C8H4O4)(C22H14N3O2)] n or [Ln(1,4-bdc)(L)] n , with Ln = Dy (7), Ho (8), Er (9) and ytterbium (Yb, 10), were synthesized under hydrothermal conditions and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Compounds 1–3 possess one-dimensional loop chains with Ln2(COO)2 units, which are extended into three-dimensional (3D) supramolecular structures by π–π interactions. Isostructural compounds 5 and 6 show 6-connected 3D networks, with pcu topology consisting of Ln2(COO)2 units. Compounds 7–10 display 8-connected 3D frameworks with the topological type rob, consisting of Ln2(COO)2 units. The influence of the coordination orientations of the aromatic dicarboxylate groups on the crystal structures is discussed.

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